氯化双(5-茂二甲基铝-甲基钛)

氯化双(5-茂二甲基铝-甲基钛)

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tebbe

Chlorobishetacyclopentadienyldimethylammoniummumethyle; MU-Chlorobis(Eta5-cyclopentadienyl)(dimethylaluminum)-MU-methylene-titanium (ca. 0.5mol/l Toluene Soln.); mu-Chlorobis(((heta)^5)-cyclopentadienyl)(dimethylammonium)-mu-methylene-titanium; Bis(cyclopentadienyl-micron-chloro(dimethylaluminum-micron-methylenetitanium; Tebbe reagent

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C₁₃H₁₈AlClTi

284.5836

InChI=1/2C5H5.2CH3.CH2.Al.ClH.Ti/c2*1-2-4-5-3-1;;;;;;/h2*1-5H;2*1H3;1H2;;1H;/rC13H19AlClTi/c1-14(2)11-16(15-14,12-7-3-4-8-12)13-9-5-6-10-13/h3-10,12-13,15H,11H2,1-2H3

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R11:Highly flammable.;
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 吸入、皮肤接触及吞食有毒。Toxic by inhalation, in contact with skin and if swallowed.;
R34:Causes burns.;

S16:Keep away from sources of ignition - No smoking.;
S25:Avoid contact with eyes.;
S29:Do not empty into drains.;
S33:Take precautionary measures against static discharges.;
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.;