Name:
Terbium Atomic Absorption Standard Solution 1 mg/ml Tb in 2% HCl
Synonym:
None Known
CAS:
7440-27-9
Section 1 - Chemical Product
MSDS Name:Terbium Atomic Absorption Standard Solution 1 mg/ml Tb in 2% HCl
Synonym:None Known
Synonym:None Known
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7440-27-9 | Terbium | <1.0% | 231-137-6 |
| Hazard Symbols: T C Risk Phrases: 23 35 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation. Causes severe burns.Corrosive.
Potential Health Effects
Eye:
May cause irreversible eye injury. Vapor or mist may cause irritation and severe burns. Contact with liquid is corrosive to the eyes and causes severe burns. May cause painful sensitization to light.
Skin:
May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with liquid is corrosive and causes severe burns and ulceration.
Ingestion:
May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. May be harmful if swallowed.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Exposure to the mist and vapor may erode exposed teeth. Causes corrosive action on the mucous membranes.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth. May cause fetal effects.
Laboratory experiments have resulted in mutagenic effects. Prolonged exposure may cause conjunctivitis, photosensitization, and possible blindness.
Toxic by inhalation. Causes severe burns.Corrosive.
Potential Health Effects
Eye:
May cause irreversible eye injury. Vapor or mist may cause irritation and severe burns. Contact with liquid is corrosive to the eyes and causes severe burns. May cause painful sensitization to light.
Skin:
May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with liquid is corrosive and causes severe burns and ulceration.
Ingestion:
May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. May be harmful if swallowed.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Exposure to the mist and vapor may erode exposed teeth. Causes corrosive action on the mucous membranes.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth. May cause fetal effects.
Laboratory experiments have resulted in mutagenic effects. Prolonged exposure may cause conjunctivitis, photosensitization, and possible blindness.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). SPEEDY ACTION IS CRITICAL! Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Give milk of magnesia.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Do NOT use sodium bicarbonate in an attempt to neutralize the acid.
Antidote: Do NOT use oils or ointments in eye.
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Give milk of magnesia.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Do NOT use sodium bicarbonate in an attempt to neutralize the acid.
Antidote: Do NOT use oils or ointments in eye.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Not flammable, but reacts with most metals to form flammable hydrogen gas. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Containers may explode when heated.
Extinguishing Media:
For large fires, use water spray, fog, or alcohol-resistant foam.
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Do NOT use straight streams of water. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out. For small fires, use carbon dioxide (except for cyanides), dry chemical, dry sand, and alcohol-resistant foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Not flammable, but reacts with most metals to form flammable hydrogen gas. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Containers may explode when heated.
Extinguishing Media:
For large fires, use water spray, fog, or alcohol-resistant foam.
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Do NOT use straight streams of water. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out. For small fires, use carbon dioxide (except for cyanides), dry chemical, dry sand, and alcohol-resistant foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Large spills may be neutralized with dilute alkaline solutions of soda ash (sodium carbonate, Na2CO3), or lime (calcium oxide, CaO).
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water.
Spills/Leaks:
Large spills may be neutralized with dilute alkaline solutions of soda ash (sodium carbonate, Na2CO3), or lime (calcium oxide, CaO).
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors. Cover with dry earth, dry sand, or other non-combustible material followed with plastic sheet to minimize spreading and contact with water.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. emsdss may develop pressure upon prolonged storage. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use caution when opening. Keep from contact with moist air and steam.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not store in metal containers. Do not store near flammable or oxidizing substances (especially nitric acid or chlorates).
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. emsdss may develop pressure upon prolonged storage. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use caution when opening. Keep from contact with moist air and steam.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not store in metal containers. Do not store near flammable or oxidizing substances (especially nitric acid or chlorates).
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 7440-27-9: CAS# 7647-01-0: United Kingdom, WEL - TWA: 1 ppm TWA (aerosol mist and gas); 2 mg TWA (aerosol mist and gas) United Kingdom, WEL - STEL: 5 ppm STEL (aerosol mist and gas); 8 mg/m3 STEL (aerosol mist and gas) United States OSHA: ; 5 ppm Ceiling; 7 mg/m3 Ceiling Belgium - TWA: 5 ppm VLE; 8 mg/m3 VLE Belgium - STEL: 10 ppm VLE; 15 mg/m3 VLE France - VLE: 5 ppm VLE; 7.5 mg/m3 VLE Germany: 8 mg/m3 TWA Japan: 5 ppm Ceiling; 7.5 mg/m3 Ceiling Malaysia: 5 ppm Ceiling; 7.5 mg/m3 Ceiling Netherlands: 10 ppm STEL; 15 mg/m3 STEL Netherlands: 5 ppm MAC; 8 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 5 ppm VLA-ED; 7.6 mg/m3 VLA-ED Spain: 10 ppm VLA-EC; 15 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear neoprene or polyvinyl chloride gloves to prevent exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 7440-27-9: CAS# 7647-01-0: United Kingdom, WEL - TWA: 1 ppm TWA (aerosol mist and gas); 2 mg TWA (aerosol mist and gas) United Kingdom, WEL - STEL: 5 ppm STEL (aerosol mist and gas); 8 mg/m3 STEL (aerosol mist and gas) United States OSHA: ; 5 ppm Ceiling; 7 mg/m3 Ceiling Belgium - TWA: 5 ppm VLE; 8 mg/m3 VLE Belgium - STEL: 10 ppm VLE; 15 mg/m3 VLE France - VLE: 5 ppm VLE; 7.5 mg/m3 VLE Germany: 8 mg/m3 TWA Japan: 5 ppm Ceiling; 7.5 mg/m3 Ceiling Malaysia: 5 ppm Ceiling; 7.5 mg/m3 Ceiling Netherlands: 10 ppm STEL; 15 mg/m3 STEL Netherlands: 5 ppm MAC; 8 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 5 ppm VLA-ED; 7.6 mg/m3 VLA-ED Spain: 10 ppm VLA-EC; 15 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear neoprene or polyvinyl chloride gloves to prevent exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: not available
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Mechanical shock, incompatible materials, metals, excess heat, exposure to moist air or water, bases.
Incompatibilities with Other Materials:
Bases, acetic anhydride, alkali metals, aluminum, amines, copper, copper alloys, fluorine, iron, sodium hydroxide, steel, sulfuric acid, vinyl acetate, zinc, potassium permanganate, cesium acetylene carbide, rubidium acetylene carbide, rubidium carbide, sodium, chlorosulfonic acid, oleum, carbonates, perchloric acid, calcium phosphide, metal oxides, acetates, cesium carbide, beta-propiolactone, ethyleneimine, propylene oxide, lithium silicides, alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide, calcium carbide, 1,1-difluoroethylene, ethylene diamine, magnesium boride, mercuric sulfate, silver perchlorate + carbon tetrachloride, uranium phosphide.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen gas.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Mechanical shock, incompatible materials, metals, excess heat, exposure to moist air or water, bases.
Incompatibilities with Other Materials:
Bases, acetic anhydride, alkali metals, aluminum, amines, copper, copper alloys, fluorine, iron, sodium hydroxide, steel, sulfuric acid, vinyl acetate, zinc, potassium permanganate, cesium acetylene carbide, rubidium acetylene carbide, rubidium carbide, sodium, chlorosulfonic acid, oleum, carbonates, perchloric acid, calcium phosphide, metal oxides, acetates, cesium carbide, beta-propiolactone, ethyleneimine, propylene oxide, lithium silicides, alcohols + hydrogen cyanide, 2-aminoethanol, ammonium hydroxide, calcium carbide, 1,1-difluoroethylene, ethylene diamine, magnesium boride, mercuric sulfate, silver perchlorate + carbon tetrachloride, uranium phosphide.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, hydrogen gas.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7440-27-9 unlisted.
CAS# 7647-01-0: MW4025000 MW4031000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
Not available.
CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation, mouse: LC50 = 20487 mg/m3/5M; Inhalation, mouse: LC50 = 3940 mg/m3/30M; Inhalation, mouse: LC50 = 8300 mg/m3/30M; Inhalation, rat: LC50 = 3124 ppm/1H; Inhalation, rat: LC50 = 60938 mg/m3/5M; Inhalation, rat: LC50 = 7004 mg/m3/30M; Inhalation, rat: LC50 = 45000 mg/m3/5M; Inhalation, rat: LC50 = 8300 mg/m3/30M; Oral, rabbit: LD50 = 900 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Terbium - Not listed by ACGIH, IARC, or NTP.
Hydrogen Chloride - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7440-27-9 unlisted.
CAS# 7647-01-0: MW4025000 MW4031000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
Not available.
CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation, mouse: LC50 = 20487 mg/m3/5M; Inhalation, mouse: LC50 = 3940 mg/m3/30M; Inhalation, mouse: LC50 = 8300 mg/m3/30M; Inhalation, rat: LC50 = 3124 ppm/1H; Inhalation, rat: LC50 = 60938 mg/m3/5M; Inhalation, rat: LC50 = 7004 mg/m3/30M; Inhalation, rat: LC50 = 45000 mg/m3/5M; Inhalation, rat: LC50 = 8300 mg/m3/30M; Oral, rabbit: LD50 = 900 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Terbium - Not listed by ACGIH, IARC, or NTP.
Hydrogen Chloride - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Bluegill/Sunfish: 3.6 mg/L; 48Hr; Lethal (unspecified)Fish: Bluegill/Sunfish: LC50; 96 Hr; pH 3.0-3.5
Fish: Bluegill/Sunfish: 3.6 mg/L; 48Hr; Lethal (unspecified)Fish: Bluegill/Sunfish: LC50; 96 Hr; pH 3.0-3.5
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: HYDROCHLORIC ACID
Hazard Class: 8
UN Number: 1789
Packing Group: II
IMO
Shipping Name: HYDROCHLORIC ACID
Hazard Class: 8
UN Number: 1789
Packing Group: II
RID/ADR
Shipping Name: HYDROCHLORIC ACID
Hazard Class: 8
UN Number: 1789
Packing group: II
USA RQ: CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T C
Risk Phrases:
R 23 Toxic by inhalation.
R 35 Causes severe burns.
Safety Phrases:
S 1/2 Keep locked up and out of reach of children.
S 9 Keep container in a well-ventilated place.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7440-27-9: No information available.
CAS# 7647-01-0: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 7440-27-9 is listed on Canadas NDSL List.
CAS# 7647-01-0 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 7440-27-9 is not listed on Canadas Ingredient Disclosure List.
CAS# 7647-01-0 is listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7440-27-9 is listed on the TSCA inventory.
CAS# 7647-01-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
