Name:
tert-Butyl peroxyacetate 50% solution in aromatic free mineral
Synonym:
CAS:
107-71-1
Section 1 - Chemical Product
MSDS Name:tert-Butyl peroxyacetate 50% solution in aromatic free mineral
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 107-71-1 | tert-Butyl peroxyacetate | 50% | 203-514-5 |
| Hazard Symbols: XI O Risk Phrases: 10 36 7 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Irritating to eyes. May cause fire.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the flow of tears).
Skin:
Non-irritating to the skin. May be harmful if absorbed through the skin.
Ingestion:
Aspiration hazard. May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
Flammable. Irritating to eyes. May cause fire.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the flow of tears).
Skin:
Non-irritating to the skin. May be harmful if absorbed through the skin.
Ingestion:
Aspiration hazard. May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Strong oxidizer. Contact with other material may cause fire.
Will burn if involved in a fire. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Strong oxidizer. Contact with other material may cause fire.
Will burn if involved in a fire. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
Section 7 - HANDLING and STORAGE
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid mechanical shock and friction.
Storage:
Keep away from sources of ignition. Do not store near combustible materials. Store in a tightly closed container. Store in a dry area.
Refrigerator/flammables. Keep away from reducing agents.
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid mechanical shock and friction.
Storage:
Keep away from sources of ignition. Do not store near combustible materials. Store in a tightly closed container. Store in a dry area.
Refrigerator/flammables. Keep away from reducing agents.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 107-71-1: Russia: 0.1 mg/m3 TWA CAS# 31807-55-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 107-71-1: Russia: 0.1 mg/m3 TWA CAS# 31807-55-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: Not available.
Odor: pungent odor
pH: Not available.
Vapor Pressure: 6.6726 kPa
Viscosity: 1.9 mPa.s 0 deg C
Boiling Point: Not available.
Freezing/Melting Point: -20 deg C
Autoignition Temperature: > 400 deg C (> 752.00 deg F)
Flash Point: 43 deg C ( 109.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Immiscible.
Specific Gravity/Density: 0.820
Molecular Formula: C6H12O3
Molecular Weight: 132.16
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by direct contact with incompatible substances or by thermal decomposition at and above the SADT (see Section 16).
Conditions to Avoid:
Incompatible materials, ignition sources, combustible materials.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, acids, bases, metal oxides, rust, heavy metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acetic acid, acetone, methane.
Hazardous Polymerization: Will not occur.
A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by direct contact with incompatible substances or by thermal decomposition at and above the SADT (see Section 16).
Conditions to Avoid:
Incompatible materials, ignition sources, combustible materials.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, acids, bases, metal oxides, rust, heavy metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acetic acid, acetone, methane.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 107-71-1: SD8925000 CAS# 31807-55-3 unlisted.
LD50/LC50:
CAS# 107-71-1: Oral, mouse: LD50 = 632 mg/kg; Oral, rat: LD50 = 675 mg/kg.
CAS# 31807-55-3.
Carcinogenicity:
tert-Butyl peroxyacetate - Not listed by ACGIH, IARC, or NTP.
Isododecane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 107-71-1: SD8925000 CAS# 31807-55-3 unlisted.
LD50/LC50:
CAS# 107-71-1: Oral, mouse: LD50 = 632 mg/kg; Oral, rat: LD50 = 675 mg/kg.
CAS# 31807-55-3.
Carcinogenicity:
tert-Butyl peroxyacetate - Not listed by ACGIH, IARC, or NTP.
Isododecane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 10 Flammable.
R 36 Irritating to eyes.
R 7 May cause fire.
Safety Phrases:
S 3/7 Keep container tightly closed in a cool,
well-ventilated place.
S 14A Keep away from acids, reducing agents and
polymerisation catalysts.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 107-71-1: No information available.
CAS# 31807-55-3: 1
Canada
CAS# 107-71-1 is listed on Canadas DSL List.
CAS# 31807-55-3 is listed on Canadas NDSL List.
CAS# 107-71-1 is listed on Canadas Ingredient Disclosure List.
CAS# 31807-55-3 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 107-71-1 is listed on the TSCA inventory.
CAS# 31807-55-3 is listed on the TSCA inventory.
