Name:
tert-Butylperoxy allyl carbonate 70 wt.% solution in odourless
Synonym:
CAS:
31807-55-3
Section 1 - Chemical Product
MSDS Name:tert-Butylperoxy allyl carbonate 70 wt.% solution in odourless
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 31807-55-3 | Isododecane | 30 | 250-816-8 |
| Hazard Symbols: XI O Risk Phrases: 10 36/38 7 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Irritating to eyes and skin. May cause fire.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
Flammable. Irritating to eyes and skin. May cause fire.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Exposure to heat may promote violent decomposition.
Strong oxidizer. Contact with other material may cause fire. Will burn if involved in a fire. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Do NOT use halogenated agents.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Exposure to heat may promote violent decomposition.
Strong oxidizer. Contact with other material may cause fire. Will burn if involved in a fire. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Do NOT use halogenated agents.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Vacuum or sweep up material and place into a suitable disposal container. Remove all sources of ignition. Use a spark-proof tool.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Vacuum or sweep up material and place into a suitable disposal container. Remove all sources of ignition. Use a spark-proof tool.
Section 7 - HANDLING and STORAGE
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Do not store near combustible materials. Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Flammables-area.
Store at temperatures below the decomposition temperature. Store at room temperature or below.
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Do not store near combustible materials. Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Flammables-area.
Store at temperatures below the decomposition temperature. Store at room temperature or below.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 31807-55-3: CAS# 65700-08-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 31807-55-3: CAS# 65700-08-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: light yellow
Odor: mild odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: <= -50 deg C
Autoignition Temperature: Not available.
Flash Point: 50 deg C ( 122.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 55 deg C
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C8H14O4
Molecular Weight: 174.2
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Light sensitive. Material is heat sensitive and may decompose at elevated temperatures.
Conditions to Avoid:
Incompatible materials, temperatures above 50C (122F), direct sunlight..
Incompatibilities with Other Materials:
Rust, iron, steel, copper, acids, alkalies, heavy metals, reducing agents, ignition or explosion may occur with readily oxidizable, organic, or flammable materials or chemical accelerants.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, peroxides, various hydrocarbons.
Hazardous Polymerization: Has not been reported
Light sensitive. Material is heat sensitive and may decompose at elevated temperatures.
Conditions to Avoid:
Incompatible materials, temperatures above 50C (122F), direct sunlight..
Incompatibilities with Other Materials:
Rust, iron, steel, copper, acids, alkalies, heavy metals, reducing agents, ignition or explosion may occur with readily oxidizable, organic, or flammable materials or chemical accelerants.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, peroxides, various hydrocarbons.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 31807-55-3 unlisted.
CAS# 65700-08-5 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Isododecane - Not listed by ACGIH, IARC, or NTP.
Allyl tert-butyl peroxycarbonate - Not listed by ACGIH, IARC, or NTP.
CAS# 31807-55-3 unlisted.
CAS# 65700-08-5 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Isododecane - Not listed by ACGIH, IARC, or NTP.
Allyl tert-butyl peroxycarbonate - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: ORGANIC PEROXIDE TYPE C, LIQUID (Organic peroxide,
liquid, sample) (forbidden to ship via cargo or passen
Hazard Class: 5.2
UN Number: 3103
Packing Group:
IMO
Shipping Name: ORGANIC PEROXIDE TYPE C, LIQUID (ORGANIC PEROXIDE,
LIQUID, SAMPLE)
Hazard Class: 5.2
UN Number: 3103
Packing Group:
RID/ADR
Shipping Name: ORGANIC PEROXIDE TYPE C, LIQUID (ORGANIC PEROXIDE,
LIQUID, SAMPLE)
Hazard Class: 5.2
UN Number: 3103
Packing group:
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 10 Flammable.
R 36/38 Irritating to eyes and skin.
R 7 May cause fire.
Safety Phrases:
S 3/7 Keep container tightly closed in a cool,
well-ventilated place.
S 14 Keep away from ... (incompatible materials to
be indicated by the manufacturer).
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 50 Do not mix with ... (to be specified by the
manufacturer).
WGK (Water Danger/Protection)
CAS# 31807-55-3: 1
CAS# 65700-08-5: No information available.
Canada
CAS# 31807-55-3 is listed on Canadas NDSL List.
CAS# 31807-55-3 is not listed on Canadas Ingredient Disclosure List.
CAS# 65700-08-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 31807-55-3 is listed on the TSCA inventory.
CAS# 65700-08-5 is not listed on the TSCA inventory.
It is for research and development use only.
