Name:
Thallium(iii) oxide 99+%
Synonym:
Dithallium Trioxide; Thallium Oxide; Thallium Peroxide; Thallium Sesquioxid
CAS:
1314-32-5
Section 1 - Chemical Product
MSDS Name:Thallium(iii) oxide 99+%
Synonym:Dithallium Trioxide; Thallium Oxide; Thallium Peroxide; Thallium Sesquioxid
Synonym:Dithallium Trioxide; Thallium Oxide; Thallium Peroxide; Thallium Sesquioxid
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 1314-32-5 | Thallic oxide | >99 | 215-229-3 |
| Hazard Symbols: T+ Risk Phrases: 28 33 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Very toxic if swallowed. Danger of cumulative effects.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be absorbed through the skin. Chronic inhalation can cause hair loss, fatigue, weight loss, and pain in the extremities. Chronic skin exposure may cause effects similar to those of chronic inhalation.
Ingestion:
May be fatal if swallowed.
Inhalation:
Dust is irritating to the respiratory tract.
Chronic:
Chronic inhalation can cause hair loss, fatigue, weight loss, and pain in the extremities. Chronic skin exposure may cause effects similar to those of chronic inhalation.
Very toxic if swallowed. Danger of cumulative effects.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be absorbed through the skin. Chronic inhalation can cause hair loss, fatigue, weight loss, and pain in the extremities. Chronic skin exposure may cause effects similar to those of chronic inhalation.
Ingestion:
May be fatal if swallowed.
Inhalation:
Dust is irritating to the respiratory tract.
Chronic:
Chronic inhalation can cause hair loss, fatigue, weight loss, and pain in the extremities. Chronic skin exposure may cause effects similar to those of chronic inhalation.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. Get medical aid immediately. SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. Get medical aid immediately. SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible. Decomposes at high temperatures releasing oxygen which may cause an existing fire to burn more vigorously.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible. Decomposes at high temperatures releasing oxygen which may cause an existing fire to burn more vigorously.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Isolate area and deny entry.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Isolate area and deny entry.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Do not ingest or inhale.
Storage:
Store in a tightly closed container. Keep away from food and drinking water. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Do not ingest or inhale.
Storage:
Store in a tightly closed container. Keep away from food and drinking water. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Use substance with extreme caution and designate regulated areas for use.
Exposure Limits CAS# 1314-32-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Use adequate ventilation to keep airborne concentrations low. Use substance with extreme caution and designate regulated areas for use.
Exposure Limits CAS# 1314-32-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: very dark brown
Odor: Odorless.
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 717 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: O3Tl2
Molecular Weight: 456.73
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Forms explosive mixtures with sulfur and sulfur compounds.
Hazardous Decomposition Products:
Thallium fumes.
Hazardous Polymerization: Will not occur.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Forms explosive mixtures with sulfur and sulfur compounds.
Hazardous Decomposition Products:
Thallium fumes.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1314-32-5: XG2975000 LD50/LC50:
CAS# 1314-32-5: Oral, rat: LD50 = 44 mg/kg.
Oral, rat/mice: LD50 = 25 Carcinogenicity:
Thallic oxide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 1314-32-5: XG2975000 LD50/LC50:
CAS# 1314-32-5: Oral, rat: LD50 = 44 mg/kg.
Oral, rat/mice: LD50 = 25 Carcinogenicity:
Thallic oxide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing Group: II
IMO
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing Group: II
RID/ADR
Shipping Name: THALLIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1707
Packing group: II
USA RQ: CAS# 1314-32-5: 100 lb final RQ; 45.4 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 28 Very toxic if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding
stuffs.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1314-32-5: No information available.
Canada
CAS# 1314-32-5 is listed on Canadas NDSL List.
CAS# 1314-32-5 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1314-32-5 is listed on the TSCA inventory.
