Name:
Tin (II) Sulfate 99%
Synonym:
Stannous Sulfate; Tin (2+) Sulfate
CAS:
7488-55-3
Section 1 - Chemical Product
MSDS Name:Tin (II) Sulfate 99%
Synonym:Stannous Sulfate; Tin (2+) Sulfate
Synonym:Stannous Sulfate; Tin (2+) Sulfate
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7488-55-3 | TIN(II) SULFATE | 99 | 231-302-2 |
| Hazard Symbols: XI Risk Phrases: 36/37 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes and respiratory system.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingested inorganic tin exhibits only moderate toxicity due to poor absorption and rapid tissue turnover. Ingestion of large amounts may cause gastrointestinal irritation, nausea, cramps, vomiting and diarrhea. May interfere with various enzyme systems.
Inorganic tin salts may cause systemic effects on the central nervous system, heart and liver.
Inhalation:
May cause respiratory tract irritation. Irritation may lead to chemical pneumonitis and pulmonary edema. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. May cause chemical bronchitis with coughing and difficulty in breathing. When inhaled as a dust or fume, may cause benign pneumoconiosis.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Adverse reproductive effects have been reported in animals. Chronic exposure to tin oxide dusts and fumes may result in stannosis (benign pneumoconiosis).
Irritating to eyes and respiratory system.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingested inorganic tin exhibits only moderate toxicity due to poor absorption and rapid tissue turnover. Ingestion of large amounts may cause gastrointestinal irritation, nausea, cramps, vomiting and diarrhea. May interfere with various enzyme systems.
Inorganic tin salts may cause systemic effects on the central nervous system, heart and liver.
Inhalation:
May cause respiratory tract irritation. Irritation may lead to chemical pneumonitis and pulmonary edema. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. May cause chemical bronchitis with coughing and difficulty in breathing. When inhaled as a dust or fume, may cause benign pneumoconiosis.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Adverse reproductive effects have been reported in animals. Chronic exposure to tin oxide dusts and fumes may result in stannosis (benign pneumoconiosis).
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or chemical foam. Do NOT get water inside containers.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or chemical foam. Do NOT get water inside containers.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Store protected from moisture.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Store protected from moisture.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7488-55-3: United Kingdom, WEL - TWA: (listed as tin inorganic compounds): 2 mg/m3 TWA (except SnH4, as Sn) United Kingdom, WEL - STEL: (listed as tin inorganic compounds): mg/m3 STEL (except SnH4, as Sn) United States OSHA: 2 mg/m3 TWA (as Sn) (listed under Tin inorga compounds).
Belgium - TWA: (listed as tin inorganic compounds): 2 mg/m3 VLE ( Sn) Malaysia: (listed as tin inorganic compounds): 2 mg/m3 TWA (as Sn except tin hydride) Netherlands: (listed as tin inorganic compounds): 2 mg/m3 MAC (as Spain: (listed as tin inorganic compounds): 2 mg/m3 VLA-ED (as Sn Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7488-55-3: United Kingdom, WEL - TWA: (listed as tin inorganic compounds): 2 mg/m3 TWA (except SnH4, as Sn) United Kingdom, WEL - STEL: (listed as tin inorganic compounds): mg/m3 STEL (except SnH4, as Sn) United States OSHA: 2 mg/m3 TWA (as Sn) (listed under Tin inorga compounds).
Belgium - TWA: (listed as tin inorganic compounds): 2 mg/m3 VLE ( Sn) Malaysia: (listed as tin inorganic compounds): 2 mg/m3 TWA (as Sn except tin hydride) Netherlands: (listed as tin inorganic compounds): 2 mg/m3 MAC (as Spain: (listed as tin inorganic compounds): 2 mg/m3 VLA-ED (as Sn Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white to yellow
Odor: none reported
pH: acidic (in solution)
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point: 712 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 712 deg F
Solubility in water: soluble in water
Specific Gravity/Density: 3.95 @ 20C
Molecular Formula: O4SSn
Molecular Weight: 214.7476
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on exposure to moist air or water.
Conditions to Avoid:
High temperatures, incompatible materials, moisture.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases, tin/tin oxides.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures. May decompose on exposure to moist air or water.
Conditions to Avoid:
High temperatures, incompatible materials, moisture.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases, tin/tin oxides.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7488-55-3: WT1255000 LD50/LC50:
CAS# 7488-55-3: Oral, mouse: LD50 = 2152 mg/kg; Oral, rat: LD50 = 2207 mg/kg.
Carcinogenicity:
TIN(II) SULFATE - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7488-55-3: WT1255000 LD50/LC50:
CAS# 7488-55-3: Oral, mouse: LD50 = 2152 mg/kg; Oral, rat: LD50 = 2207 mg/kg.
Carcinogenicity:
TIN(II) SULFATE - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37 Irritating to eyes and respiratory system.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7488-55-3: No information available.
Canada
CAS# 7488-55-3 is listed on Canadas DSL List.
CAS# 7488-55-3 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7488-55-3 is listed on the TSCA inventory.
