Name:
Tin(IV) Chloride 99.999%
Synonym:
Stannic chloride; Tin tetrachloride; fuming spirit of Libavius; tin perchloride
CAS:
7646-78-8
Section 1 - Chemical Product
MSDS Name:Tin(IV) Chloride 99.999%
Synonym:Stannic chloride; Tin tetrachloride; fuming spirit of Libavius; tin perchloride
Synonym:Stannic chloride; Tin tetrachloride; fuming spirit of Libavius; tin perchloride
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7646-78-8 | Tin(IV) chloride | 99.999 | 231-588-9 |
| Hazard Symbols: C Risk Phrases: 34 52/53 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May cause severe skin irritation with possible burns, especially if skin is wet or moist.
Ingestion:
May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema. May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic exposure to tin oxide dusts and fumes may result in stannosis (benign pneumoconiosis).
Causes burns. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May cause severe skin irritation with possible burns, especially if skin is wet or moist.
Ingestion:
May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.
Inhalation:
Irritation may lead to chemical pneumonitis and pulmonary edema. May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic exposure to tin oxide dusts and fumes may result in stannosis (benign pneumoconiosis).
Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Not combustible, but if involved in a fire, decomposes to produce hydrogen chloride.
Extinguishing Media:
Do NOT use water directly on fire. Use extinguishing media most appropriate for the surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Not combustible, but if involved in a fire, decomposes to produce hydrogen chloride.
Extinguishing Media:
Do NOT use water directly on fire. Use extinguishing media most appropriate for the surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Use water spray to cool and disperse vapors and protect personnel.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Use water spray to cool and disperse vapors and protect personnel.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from metals. Corrosives area. Storage under a nitrogen blanket has been recommended. Do not get water inside containers.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only with adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from metals. Corrosives area. Storage under a nitrogen blanket has been recommended. Do not get water inside containers.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 7646-78-8: United Kingdom, WEL - TWA: (listed as tin inorganic compounds): 2 mg/m3 TWA (except SnH4, as Sn) United Kingdom, WEL - STEL: (listed as tin inorganic compounds): mg/m3 STEL (except SnH4, as Sn) United States OSHA: 2 mg/m3 TWA (as Sn) (listed under Tin inorga compounds).
Belgium - TWA: (listed as tin inorganic compounds): 2 mg/m3 VLE ( Sn) Malaysia: (listed as tin inorganic compounds): 2 mg/m3 TWA (as Sn except tin hydride) Netherlands: (listed as tin inorganic compounds): 2 mg/m3 MAC (as Spain: (listed as tin inorganic compounds): 2 mg/m3 VLA-ED (as Sn Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 7646-78-8: United Kingdom, WEL - TWA: (listed as tin inorganic compounds): 2 mg/m3 TWA (except SnH4, as Sn) United Kingdom, WEL - STEL: (listed as tin inorganic compounds): mg/m3 STEL (except SnH4, as Sn) United States OSHA: 2 mg/m3 TWA (as Sn) (listed under Tin inorga compounds).
Belgium - TWA: (listed as tin inorganic compounds): 2 mg/m3 VLE ( Sn) Malaysia: (listed as tin inorganic compounds): 2 mg/m3 TWA (as Sn except tin hydride) Netherlands: (listed as tin inorganic compounds): 2 mg/m3 MAC (as Spain: (listed as tin inorganic compounds): 2 mg/m3 VLA-ED (as Sn Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: slightly yellow
Odor: Strong acrid odor.
pH: Not available.
Vapor Pressure: 20 mm Hg @ 22 deg C
Viscosity: Not available.
Boiling Point: 114 deg C @ 760 mm Hg
Freezing/Melting Point: -33 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water with much heat
Specific Gravity/Density: 2.23 (water=1)
Molecular Formula: Cl4Sn
Molecular Weight: 260.50
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on exposure to moist air or water. Liberates heat and hydrochloric acid on contact with water. Fumes in moist air.
Conditions to Avoid:
High temperatures, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong bases, alcohols, amines, ethylene oxide, potassium, sodium, alkyl nitrates, turpentine.
Hazardous Decomposition Products:
Hydrogen chloride, tin/tin oxides.
Hazardous Polymerization: Will not occur.
Stable under normal temperatures and pressures. May decompose on exposure to moist air or water. Liberates heat and hydrochloric acid on contact with water. Fumes in moist air.
Conditions to Avoid:
High temperatures, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong bases, alcohols, amines, ethylene oxide, potassium, sodium, alkyl nitrates, turpentine.
Hazardous Decomposition Products:
Hydrogen chloride, tin/tin oxides.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7646-78-8: XP8750000 LD50/LC50:
CAS# 7646-78-8: Inhalation, rat: LC50 = 2300 mg/m3/10M.
Carcinogenicity:
Tin(IV) chloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7646-78-8: XP8750000 LD50/LC50:
CAS# 7646-78-8: Inhalation, rat: LC50 = 2300 mg/m3/10M.
Carcinogenicity:
Tin(IV) chloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: STANNIC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1827
Packing Group: II
IMO
Shipping Name: STANNIC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1827
Packing Group: II
RID/ADR
Shipping Name: STANNIC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1827
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7646-78-8: 1
Canada
CAS# 7646-78-8 is listed on Canadas DSL List.
CAS# 7646-78-8 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7646-78-8 is listed on the TSCA inventory.
