Name:
Titanium (III) Sulfate Solution
Synonym:
Non
CAS:
7664-93-9
Section 1 - Chemical Product
MSDS Name:Titanium (III) Sulfate Solution
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7664-93-9 | Sulfuric acid | 35 | 231-639-5 |
| Hazard Symbols: C Risk Phrases: 34 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May cause circulatory system failure. May cause perforation of the digestive tract.
Inhalation:
Causes chemical burns to the respiratory tract. May cause pulmonary edema and severe respiratory disturbances.
Chronic:
No information found.
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May cause circulatory system failure. May cause perforation of the digestive tract.
Inhalation:
Causes chemical burns to the respiratory tract. May cause pulmonary edema and severe respiratory disturbances.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get on skin or in eyes. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get on skin or in eyes. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 7664-93-9: United States OSHA: 1 mg/m3 TWA Belgium - TWA: 1 mg/m3 VLE Belgium - STEL: 3 mg/m3 VLE France - VME: 1 mg/m3 VME France - VLE: 3 mg/m3 VLE Germany: 0.5 mg/m3 TWA (inhalable fraction, battery manufacture, metal working in a close Japan: 1 mg/m3 Ceiling Malaysia: 1 mg/m3 TWA Netherlands: 1 mg/m3 MAC Russia: 1 mg/m3 TWA Spain: 1 mg/m3 VLA-ED Spain: 3 mg/m3 VLA-EC CAS# 10343-61-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 7664-93-9: United States OSHA: 1 mg/m3 TWA Belgium - TWA: 1 mg/m3 VLE Belgium - STEL: 3 mg/m3 VLE France - VME: 1 mg/m3 VME France - VLE: 3 mg/m3 VLE Germany: 0.5 mg/m3 TWA (inhalable fraction, battery manufacture, metal working in a close Japan: 1 mg/m3 Ceiling Malaysia: 1 mg/m3 TWA Netherlands: 1 mg/m3 MAC Russia: 1 mg/m3 TWA Spain: 1 mg/m3 VLA-ED Spain: 3 mg/m3 VLA-EC CAS# 10343-61-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: purple
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible with water
Specific Gravity/Density: 1.28
Molecular Formula: Mixture
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, oxides of sulfur, titanium/titanium oxides, hydrogen gas.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, oxides of sulfur, titanium/titanium oxides, hydrogen gas.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7664-93-9: WS5600000 CAS# 10343-61-0 unlisted.
LD50/LC50:
CAS# 7664-93-9: Draize test, rabbit, eye: 250 ug Severe; Inhalation, mouse: LC50 = 320 mg/m3/2H; Inhalation, mouse: LC50 = 320 mg/m3; Inhalation, rat: LC50 = 510 mg/m3/2H; Inhalation, rat: LC50 = 510 mg/m3; Oral, rat: LD50 = 2140 mg/kg.
CAS# 10343-61-0.
Carcinogenicity:
Sulfuric acid - ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorg California: carcinogen, initial date 3/14/03 (listed as Strong inorgan NTP: Known carcinogen (listed as Strong inorganic acid mists co IARC: Group 1 carcinogen Titanium (III) Sulfate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7664-93-9: WS5600000 CAS# 10343-61-0 unlisted.
LD50/LC50:
CAS# 7664-93-9: Draize test, rabbit, eye: 250 ug Severe; Inhalation, mouse: LC50 = 320 mg/m3/2H; Inhalation, mouse: LC50 = 320 mg/m3; Inhalation, rat: LC50 = 510 mg/m3/2H; Inhalation, rat: LC50 = 510 mg/m3; Oral, rat: LD50 = 2140 mg/kg.
CAS# 10343-61-0.
Carcinogenicity:
Sulfuric acid - ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorg California: carcinogen, initial date 3/14/03 (listed as Strong inorgan NTP: Known carcinogen (listed as Strong inorganic acid mists co IARC: Group 1 carcinogen Titanium (III) Sulfate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: CORROSIVE LIQUID, NOS
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, NOS
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, NOS
Hazard Class: 8
UN Number: 1760
Packing group: III
USA RQ: CAS# 7664-93-9: 1000 lb final RQ; 454 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
WGK (Water Danger/Protection)
CAS# 7664-93-9: 2
CAS# 10343-61-0: No information available.
Canada
CAS# 7664-93-9 is listed on Canadas DSL List.
CAS# 10343-61-0 is listed on Canadas NDSL List.
CAS# 7664-93-9 is listed on Canadas Ingredient Disclosure List.
CAS# 10343-61-0 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
CAS# 10343-61-0 is listed on the TSCA inventory.
