Name:
Titanium (IV) Oxide 98.0 - 100.5% TiO2
Synonym:
Titanium Dioxide, Titanium Peroxide
CAS:
13463-40-6
Section 1 - Chemical Product
MSDS Name:Titanium (IV) Oxide 98.0 - 100.5% TiO2
Synonym:Titanium Dioxide, Titanium Peroxide
Synonym:Titanium Dioxide, Titanium Peroxide
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 13463-40-6 | Iron pentacarbonyl | 236-670-8 |
| Hazard Symbols: XI Risk Phrases: 37 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to respiratory system.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
The toxicological properties of this substance have not been fully investigated. Causes digestive tract irritation.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Inhalation of dusts cause severe irritation of the upper respiratory tract, gastrointestinal disturbances, albuminuria, gradual loss of weight, and increasing weakness.
Chronic:
Possible cancer hazard based on tests with laboratory animals. May cause cancer according to animal studies.
Irritating to respiratory system.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
The toxicological properties of this substance have not been fully investigated. Causes digestive tract irritation.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Inhalation of dusts cause severe irritation of the upper respiratory tract, gastrointestinal disturbances, albuminuria, gradual loss of weight, and increasing weakness.
Chronic:
Possible cancer hazard based on tests with laboratory animals. May cause cancer according to animal studies.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Substance is noncombustible. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Substance is noncombustible. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Powder
Appearance: white
Odor: odorless
pH: Neutral
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 2500 deg C
Freezing/Melting Point: 1830 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Insoluble in water.
Specific Gravity/Density: 4.1700
Molecular Formula: TiO2
Molecular Weight: 79.8788
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, titanium/titanium oxides.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, titanium/titanium oxides.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13463-40-6: NO4900000 LD50/LC50:
CAS# 13463-40-6: Inhalation, mouse: LC50 = 2190 mg/m3/30M; Inhalation, rat: LC50 = 10 ppm/4H; Oral, mouse: LD50 = 62 mg/kg; Oral, rabbit: LD50 = 12 mg/kg; Oral, rat: LD50 = 25 mg/kg; Skin, rabbit: LD50 = 56 mg/kg.
Carcinogenicity:
Iron pentacarbonyl - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
CAS# 13463-40-6: NO4900000 LD50/LC50:
CAS# 13463-40-6: Inhalation, mouse: LC50 = 2190 mg/m3/30M; Inhalation, rat: LC50 = 10 ppm/4H; Oral, mouse: LD50 = 62 mg/kg; Oral, rabbit: LD50 = 12 mg/kg; Oral, rat: LD50 = 25 mg/kg; Skin, rabbit: LD50 = 56 mg/kg.
Carcinogenicity:
Iron pentacarbonyl - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 37 Irritating to respiratory system.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13463-40-6: No information available.
United Kingdom Occupational Exposure Limits
CAS# 13463-40-6: OES-United Kingdom, TWA as Fe: 0.01 ppm TWA; 0.08
mg/m3 TWA
CAS# 13463-40-6: OES-United Kingdom, STEL (listed as ** undefined
**): as Fe: 2 mg/m3 STEL
Canada
CAS# 13463-40-6 is listed on Canadas DSL List.
CAS# 13463-40-6 is listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 13463-40-6: OEL-AUSTRALIA:TWA 0.1 ppm (0.8 mg/m3);STEL 0.2 ppm (1
.6 mg/m3)
OEL-BELGIUM:TWA 0.1 ppm (0.23 mg/m3);STEL 0.2 ppm (0.45 mg/m3)
OEL-DENMARK:TWA 0.1 ppm (0.8 mg/m3)
OEL-FINLAND:STEL 0.01 ppm (0.08 mg/m3)
OEL-FRANCE:TWA 0.1 ppm (0.8 mg/m3)
OEL-GERMANY:TWA 0.1 ppm (0.8 mg/m3)
OEL-THE NETHERLANDS:TWA 0.01 ppm (0.08 mg/m3)
OEL-RUSSIA:STEL 0.1 mg/m3;Skin
OEL-SWITZERLAND:TWA 0.1 ppm (0.8 mg/m3);STEL 0.2 ppm (1.6 mg/m3)
OEL-UNITED KINGDOM:TWA 0.01 ppm (0.08 mg/m3) JAN9
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 13463-40-6 is listed on the TSCA inventory.
