Name:
trans-4 4-Dimethyl-2-pentene
Synonym:
Non
CAS:
102-71-6
Section 1 - Chemical Product
MSDS Name:trans-4 4-Dimethyl-2-pentene
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 102-71-6 | Triethanolamine | 31.0 | 203-049-8 |
| Hazard Symbols: XI Risk Phrases: 36/37/38 20 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Harmful by inhalation.Corrosive.
Potential Health Effects
Eye:
Causes severe eye irritation. Causes eye burns.
Skin:
May be absorbed through the skin in harmful amounts. Exposure may cause irritation and possible burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation.
Chronic:
Not available.
Irritating to eyes, respiratory system and skin. Harmful by inhalation.Corrosive.
Potential Health Effects
Eye:
Causes severe eye irritation. Causes eye burns.
Skin:
May be absorbed through the skin in harmful amounts. Exposure may cause irritation and possible burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors mixed with air can explode when ignited.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors mixed with air can explode when ignited.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
Autoignition Temperature: Not available.
Flash Point: Not available.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: Not available.
Odor: Slight odor.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Decomposition Temperature: Not available.
Solubility: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: Not available.
Molecular Weight: Not available.
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, acids, excess heat, strong acids, strong oxidants, nitrites.
Incompatibilities with Other Materials:
Ethanolamine is incompatible with strong oxidizing agents, acids, and bases. It attacks some forms of plastics, rubber and coatings. Avoid contact with strong acids and nitrites.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, acids, excess heat, strong acids, strong oxidants, nitrites.
Incompatibilities with Other Materials:
Ethanolamine is incompatible with strong oxidizing agents, acids, and bases. It attacks some forms of plastics, rubber and coatings. Avoid contact with strong acids and nitrites.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# unlisted.
CAS# 102-71-6: KL9275000 CAS# 141-43-5: KJ5775000 CAS# 12069-69-1: GL6910000 CAS# 31075-24-8 unlisted.
LD50/LC50:
Not available.
CAS# 102-71-6: Oral, mouse: LD50 = 5846 mg/kg; Oral, rabbit: LD50 = 2200 mg/kg; Oral, rat: LD50 = 8 gm/kg; Skin, rabbit: LD50 = >20 gm/kg.
CAS# 141-43-5: Oral, mouse: LD50 = 700 mg/kg; Oral, rabbit: LD50 = 1 gm/kg; Oral, rat: LD50 = 1720 mg/kg; Skin, rabbit: LD50 = 1 gm/kg.
CAS# 12069-69-1: Oral, rabbit: LD50 = 159 mg/kg; Oral, rat: LD50 = 1350 mg/kg.
CAS# 31075-24-8.
Carcinogenicity:
TRANS-4,4-DIMETHYL-2-PENTENE - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Triethanolamine - IARC: Group 3 carcinogen Ethanolamine - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Copper(II) carbonate hydroxide - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Polyoxyethylen(dimethylimino)ethylene(dimethylimino)ethylene dichloride - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
CAS# unlisted.
CAS# 102-71-6: KL9275000 CAS# 141-43-5: KJ5775000 CAS# 12069-69-1: GL6910000 CAS# 31075-24-8 unlisted.
LD50/LC50:
Not available.
CAS# 102-71-6: Oral, mouse: LD50 = 5846 mg/kg; Oral, rabbit: LD50 = 2200 mg/kg; Oral, rat: LD50 = 8 gm/kg; Skin, rabbit: LD50 = >20 gm/kg.
CAS# 141-43-5: Oral, mouse: LD50 = 700 mg/kg; Oral, rabbit: LD50 = 1 gm/kg; Oral, rat: LD50 = 1720 mg/kg; Skin, rabbit: LD50 = 1 gm/kg.
CAS# 12069-69-1: Oral, rabbit: LD50 = 159 mg/kg; Oral, rat: LD50 = 1350 mg/kg.
CAS# 31075-24-8.
Carcinogenicity:
TRANS-4,4-DIMETHYL-2-PENTENE - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Triethanolamine - IARC: Group 3 carcinogen Ethanolamine - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Copper(II) carbonate hydroxide - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Polyoxyethylen(dimethylimino)ethylene(dimethylimino)ethylene dichloride - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
For further information, contact Fisher Scientific.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
CDG/CPL
IMO
Not regulated as a hazardous material.
IATA
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Canadian TDG
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 20 Harmful by inhalation.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# :
CAS# 102-71-6: 1
CAS# 141-43-5: 1
CAS# 12069-69-1:
CAS# 31075-24-8: 2
Canada
CAS# 102-71-6 is listed on Canadas DSL/NDSL List.
CAS# 141-43-5 is listed on Canadas DSL/NDSL List.
CAS# 12069-69-1 is listed on Canadas DSL/NDSL List.
CAS# 31075-24-8 is listed on Canadas DSL/NDSL List.
This product has a WHMIS classification of D2B.
CAS# is not listed on Canadas Ingredient Disclosure List.
CAS# 102-71-6 is listed on Canadas Ingredient Disclosure List.
CAS# 141-43-5 is listed on Canadas Ingredient Disclosure List.
CAS# 12069-69-1 is listed on Canadas Ingredient Disclosure List.
CAS# 31075-24-8 is not listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 102-71-6:. OEL-SWEDEN:TWA 5 mg/m3;STEL 10 mg/m3
CAS# 141-43-5:. OEL-ARAB Republic of Egypt:TWA 3 ppm (6 mg/m3). OEL-A
USTRALIA:TWA 3 ppm (8 mg/m3);STEL 6 ppm (15 mg/m3). OEL-BELGIUM:TWA 3
ppm (7.5 mg/m3);STEL 6 ppm (15 mg/m3). OEL-DENMARK:TWA 6 ppm (6 mg/m3)
. OEL-FINLAND:TWA 3 ppm (7.5 mg/m3);STEL 6 ppm (15 mg/m3). OEL-FRANCE:
TWA 3 ppm (8 mg/m3). OEL-GERMANY:TWA 3 ppm (8 mg/m3). OEL-JAPAN:TWA 3
ppm (7.5 mg/m3). OEL-THE NETHERLANDS:TWA 3 ppm (8 mg/m3). OEL-THE PHIL
IPPINES:TWA 3 ppm (6 mg/m3). OEL-RUSSIA:TWA 3 ppm;STEL 0.5 mg/m3;Skin
OEL-SWITZERLAND:TWA 3 ppm (7.5 mg/m3);STEL 15 ppm (37.5 mg/m3). OEL-U
NITED KINGDOM:TWA 3 ppm (8 mg/m3);STEL 6 ppm (15 mg/m3). OEL IN BULGAR
IA, COLOMBIA, JORDAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SINGA
PORE, VIETNAM check ACGI TLV
CAS# 12069-69-1:. OEL-ARAB Republic of Egypt:TWA 0.1 mg(Cu)/m3 (fume)
. OEL-AUSTRALIA:TWA 0.2 mg(Cu)/m3 (fume). OEL-AUSTRALIA:TWA 1 mg(Cu)/m
3 (dust). OEL-BELGIUM:TWA 0.2 mg(Cu)/m3 (fume). OEL-BELGIUM:TWA 1 mg(C
u)/m3 (dust). OEL-DENMARK:TWA 0.1 mg(Cu)/m3 (fume). OEL-DENMARK:TWA 1
mg(Cu)/m3 (dust). OEL-FINLAND:TWA 0.2 mg(Cu)/m3 (fume). OEL-FINLAND:TW
A 1 mg(Cu)/m3. OEL-FINLAND:TWA 1 mg(Cu)/m3 (dust). OEL-FRANCE:TWA 0.2
mg(Cu)/m3 (fume). OEL-FRANCE:TWA 1 mg(Cu)/m3;STEL 2 mg(Cu)/m3 (dust. O
EL-GERMANY:TWA 0.1 mg(Cu)/m3 (fume). OEL-GERMANY:TWA 1 mg(Cu)/m3. OEL-
GERMANY:TWA 1 mg(Cu)/m3 (dust). OEL-HUNGARY:TWA 0.2 mg(Cu)/m3;STEL 0.4
mg(Cu)/m3 (dust). OEL-INDIA:TWA 0.2 mg(Cu)/m3 (fume). OEL-THE NETHERL
ANDS:TWA 02 mg(Cu)/m3 (fume). OEL-THE NETHERLANDS:TWA 1 mg(Cu)/m3 (dus
t). OEL-THE PHILIPPINES:TWA 1.0 mg(Cu)/m3 (fume) JAN9. OEL-POLAND:TWA
0.1 mg(Cu)/m3 (fume). OEL-RUSSIA:STEL 0.5 ppm (1 mg(Cu)/m3) (dust) JAN
9. OEL-SWEDEN:TWA 0.2 mg(Cu)/m3 (resp. dust). OEL-SWEDEN:TWA 0.2 mg(Cu
)/m3 (fume). OEL-SWEDEN:TWA 1 mg(Cu)/m3 (total dust). OEL-SWITZERLAND:
TWA 0.1 mg(Cu)/m3;STEL 0.2 mg(Cu)/m3 (fume)
Cu)/m3;STEL 1 mg(Cu)/m3
AILAND:TWA 1 mg(Cu)/m3
US FEDERAL
TSCA
CAS# is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 102-71-6 is listed on the TSCA inventory.
CAS# 141-43-5 is listed on the TSCA inventory.
CAS# 12069-69-1 is listed on the TSCA inventory.
CAS# 31075-24-8 is listed on the TSCA inventory.
