MSDS Name:Tripropylamine 99+%
Synonym:

EMERGENCY OVERVIEW
Flammable. Harmful by inhalation and in contact with skin. Toxic if swallowed. Causes burns.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns. Causes redness and pain.
Skin:
Harmful if absorbed through the skin. Causes skin burns. Exposure may cause irritation characterized by redness, dryness, and inflammation. Substance is readily absorbed through the skin.
Ingestion:
Poison by ingestion. Causes gastrointestinal tract burns.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
May cause asthma and shortness of breath.
Chronic:
Not available.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.

Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Take precautionary measures against static discharges. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Flammables-area.

Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 102-69-2: Russia: 2 mg/m3 TWA Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Physical State: Clear liquid
Color: colorless
Odor: amine-like
pH: 11.4(2.69g/laq.sol.)
Vapor Pressure: 3 mbar @ 20 deg C
Viscosity: 0.627 mPa.s
Boiling Point: 156 deg C @ 760 mmHg
Freezing/Melting Point: -93 deg C
Autoignition Temperature: 180 deg C ( 356.00 deg F)
Flash Point: 32.5 deg C ( 90.50 deg F)
Explosion Limits, lower: 0.6 vol %
Explosion Limits, upper: 5.5 vol %
Decomposition Temperature:
Solubility in water: 2.6 g/l water (20C)
Specific Gravity/Density: 0.76 g/cm3
Molecular Formula: C9H21N
Molecular Weight: 143.27

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

RTECS#:
CAS# 102-69-2: TX1575000 LD50/LC50:
CAS# 102-69-2: Inhalation, mouse: LC50 = 3800 mg/m3/2H; Inhalation, rat: LC50 = 5100 mg/m3/4H; Oral, rat: LD50 = 96 mg/kg; Skin, rabbit: LD50 = 570 uL/kg.
Carcinogenicity:
Tripropylamine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Other No information available.

Dispose of in a manner consistent with federal, state, and local regulations.

IATA
Shipping Name: TRIPROPYLAMINE
Hazard Class: 3 (8)
UN Number: 2260
Packing Group: III
IMO
Shipping Name: TRIPROPYLAMINE
Hazard Class: 3 (8)
UN Number: 2260
Packing Group: III
RID/ADR
Shipping Name: TRIPROPYLAMINE
Hazard Class: 3
UN Number: 2260
Packing group: III

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 10 Flammable.
R 20/21 Harmful by inhalation and in contact with
skin.
R 25 Toxic if swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 102-69-2: 2
Canada
CAS# 102-69-2 is listed on Canadas NDSL List.
CAS# 102-69-2 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 102-69-2 is listed on the TSCA inventory.