Name:
Tris Glycine SDS 1X to 10X Solution
Synonym:
Tris-Glycine-Sodium Lauryl Sulfate Solution
CAS:
56-40-6
Section 1 - Chemical Product
MSDS Name:Tris Glycine SDS 1X to 10X Solution
Synonym:Tris-Glycine-Sodium Lauryl Sulfate Solution
Synonym:Tris-Glycine-Sodium Lauryl Sulfate Solution
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 56-40-6 | Glycine | 1.0-14.4 | 200-272-2 |
| Hazard Symbols: None Listed. Risk Phrases: None Listed. |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation. Low hazard for normal industrial handling.
Skin:
May cause skin irritation. Low hazard for usual industrial handling.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Low hazard for usual industrial handling.
Inhalation:
Low hazard for usual industrial handling. Inhalation of a mist of this material may cause respiratory tract irritation.
Chronic:
No information found.
Not available.
Potential Health Effects
Eye:
May cause eye irritation. Low hazard for normal industrial handling.
Skin:
May cause skin irritation. Low hazard for usual industrial handling.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Low hazard for usual industrial handling.
Inhalation:
Low hazard for usual industrial handling. Inhalation of a mist of this material may cause respiratory tract irritation.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Wash mouth out with water. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Wash mouth out with water. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation.
Storage:
Store in a cool, dry place. No special precautions indicated. Keep containers tightly closed.
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation.
Storage:
Store in a cool, dry place. No special precautions indicated. Keep containers tightly closed.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 56-40-6: Russia: 5 mg/m3 TWA CAS# 77-86-1: CAS# 151-21-3: CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 56-40-6: Russia: 5 mg/m3 TWA CAS# 77-86-1: CAS# 151-21-3: CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: Clear
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: Mixture
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong acids, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong acids, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 56-40-6: MB7600000 CAS# 77-86-1: TY2900000 CAS# 151-21-3: WT1050000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 56-40-6: Oral, mouse: LD50 = 4920 mg/kg; Oral, rat: LD50 = 7930 mg/kg.
CAS# 77-86-1: Oral, rat: LD50 = 5900 mg/kg.
CAS# 151-21-3: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, eye: 250 ug Mild; Draize test, rabbit, eye: 2 mg; Draize test, rabbit, eye: 10 mg Moderate; Draize test, rabbit, skin: 50 mg/24H Severe; Draize test, rabbit, skin: 25 mg/24H Moderate; Draize test, rabbit, skin: 250 mg/24H Moderate; Draize test, rabbit, skin: 10 mg/24H; Draize test, rabbit, skin: 50 mg/24H Mild; Inhalation, rat: LC50 = >3900 mg/m3/1H; Oral, rat: LD50 = 1288 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Glycine - Not listed by ACGIH, IARC, or NTP.
Tris (Hydroxymethyl) Aminomethane - Not listed by ACGIH, IARC, or NTP.
Sodium lauryl sulfate - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 56-40-6: MB7600000 CAS# 77-86-1: TY2900000 CAS# 151-21-3: WT1050000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 56-40-6: Oral, mouse: LD50 = 4920 mg/kg; Oral, rat: LD50 = 7930 mg/kg.
CAS# 77-86-1: Oral, rat: LD50 = 5900 mg/kg.
CAS# 151-21-3: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, eye: 250 ug Mild; Draize test, rabbit, eye: 2 mg; Draize test, rabbit, eye: 10 mg Moderate; Draize test, rabbit, skin: 50 mg/24H Severe; Draize test, rabbit, skin: 25 mg/24H Moderate; Draize test, rabbit, skin: 250 mg/24H Moderate; Draize test, rabbit, skin: 10 mg/24H; Draize test, rabbit, skin: 50 mg/24H Mild; Inhalation, rat: LC50 = >3900 mg/m3/1H; Oral, rat: LD50 = 1288 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Glycine - Not listed by ACGIH, IARC, or NTP.
Tris (Hydroxymethyl) Aminomethane - Not listed by ACGIH, IARC, or NTP.
Sodium lauryl sulfate - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 56-40-6: 0
CAS# 77-86-1: 1
CAS# 151-21-3: 2
CAS# 7732-18-5: No information available.
Canada
CAS# 56-40-6 is listed on Canadas DSL List.
CAS# 77-86-1 is listed on Canadas DSL List.
CAS# 151-21-3 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 56-40-6 is not listed on Canadas Ingredient Disclosure List.
CAS# 77-86-1 is not listed on Canadas Ingredient Disclosure List.
CAS# 151-21-3 is listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 56-40-6 is listed on the TSCA inventory.
CAS# 77-86-1 is listed on the TSCA inventory.
CAS# 151-21-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
