Name:
Vanadyl Sulfate Solution
Synonym:
Non
CAS:
7664-93-9
Section 1 - Chemical Product
MSDS Name:Vanadyl Sulfate Solution
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7664-93-9 | Sulfuric acid | 10 | 231-639-5 |
| Hazard Symbols: XN Risk Phrases: 22 36/38 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause eye burns.
Skin:
Causes skin irritation. May cause skin burns.
Ingestion:
Harmful if swallowed. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause allergic reaction characterized by a rash. May cause unconsciousness.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual industrial handling. May cause effects similar to those described for ingestion.
Chronic:
No information found.
Harmful if swallowed. Irritating to eyes and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause eye burns.
Skin:
Causes skin irritation. May cause skin burns.
Ingestion:
Harmful if swallowed. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause allergic reaction characterized by a rash. May cause unconsciousness.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual industrial handling. May cause effects similar to those described for ingestion.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.
Flush down the spill with a large amount of water. Absorb spill with an alkaline material such as soda ash or lime.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.
Flush down the spill with a large amount of water. Absorb spill with an alkaline material such as soda ash or lime.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Avoid contact with skin and eyes.
Avoid ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Avoid contact with skin and eyes.
Avoid ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 7664-93-9: United States OSHA: 1 mg/m3 TWA Belgium - TWA: 1 mg/m3 VLE Belgium - STEL: 3 mg/m3 VLE France - VME: 1 mg/m3 VME France - VLE: 3 mg/m3 VLE Germany: 0.5 mg/m3 TWA (inhalable fraction, battery manufacture, metal working in a close Japan: 1 mg/m3 Ceiling Malaysia: 1 mg/m3 TWA Netherlands: 1 mg/m3 MAC Russia: 1 mg/m3 TWA Spain: 1 mg/m3 VLA-ED Spain: 3 mg/m3 VLA-EC CAS# 7732-18-5: CAS# 27774-13-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 7664-93-9: United States OSHA: 1 mg/m3 TWA Belgium - TWA: 1 mg/m3 VLE Belgium - STEL: 3 mg/m3 VLE France - VME: 1 mg/m3 VME France - VLE: 3 mg/m3 VLE Germany: 0.5 mg/m3 TWA (inhalable fraction, battery manufacture, metal working in a close Japan: 1 mg/m3 Ceiling Malaysia: 1 mg/m3 TWA Netherlands: 1 mg/m3 MAC Russia: 1 mg/m3 TWA Spain: 1 mg/m3 VLA-ED Spain: 3 mg/m3 VLA-EC CAS# 7732-18-5: CAS# 27774-13-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: dark blue
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Not available.
Hazardous Polymerization:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Not available.
Hazardous Polymerization:
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7664-93-9: WS5600000 CAS# 7732-18-5: ZC0110000 CAS# 27774-13-6: YW1925000 LD50/LC50:
CAS# 7664-93-9: Draize test, rabbit, eye: 250 ug Severe; Inhalation, mouse: LC50 = 320 mg/m3/2H; Inhalation, mouse: LC50 = 320 mg/m3; Inhalation, rat: LC50 = 510 mg/m3/2H; Inhalation, rat: LC50 = 510 mg/m3; Oral, rat: LD50 = 2140 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 27774-13-6: Skin, rabbit: LD50 = 4450 mg/kg.
Carcinogenicity:
Sulfuric acid - ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorg California: carcinogen, initial date 3/14/03 (listed as Strong inorgan NTP: Known carcinogen (listed as Strong inorganic acid mists co IARC: Group 1 carcinogen Water - Not listed by ACGIH, IARC, or NTP.
Vanadyl sulfate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7664-93-9: WS5600000 CAS# 7732-18-5: ZC0110000 CAS# 27774-13-6: YW1925000 LD50/LC50:
CAS# 7664-93-9: Draize test, rabbit, eye: 250 ug Severe; Inhalation, mouse: LC50 = 320 mg/m3/2H; Inhalation, mouse: LC50 = 320 mg/m3; Inhalation, rat: LC50 = 510 mg/m3/2H; Inhalation, rat: LC50 = 510 mg/m3; Oral, rat: LD50 = 2140 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 27774-13-6: Skin, rabbit: LD50 = 4450 mg/kg.
Carcinogenicity:
Sulfuric acid - ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorg California: carcinogen, initial date 3/14/03 (listed as Strong inorgan NTP: Known carcinogen (listed as Strong inorganic acid mists co IARC: Group 1 carcinogen Water - Not listed by ACGIH, IARC, or NTP.
Vanadyl sulfate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: VANADYL SULPHATE
Hazard Class: 6.1
UN Number: 2931
Packing Group: II
IMO
Shipping Name: VANADYL SULPHATE
Hazard Class: 6.1
UN Number: 2931
Packing Group: II
RID/ADR
Shipping Name: VANADYL SULPHATE
Hazard Class: 6.1
UN Number: 2931
Packing group: II
USA RQ: CAS# 7664-93-9: 1000 lb final RQ; 454 kg final RQ
USA RQ: CAS# 27774-13-6: 1000 lb final RQ; 454 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 7664-93-9: 2
CAS# 7732-18-5: No information available.
CAS# 27774-13-6: No information available.
Canada
CAS# 7664-93-9 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 27774-13-6 is listed on Canadas DSL List.
CAS# 7664-93-9 is listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
CAS# 27774-13-6 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 27774-13-6 is listed on the TSCA inventory.
