Name:
Z-1 3-Dichloropropene
Synonym:
cis-1,3-Dichloropropene
CAS:
542-75-6
Section 1 - Chemical Product
MSDS Name:Z-1 3-Dichloropropene
Synonym:cis-1,3-Dichloropropene
Synonym:cis-1,3-Dichloropropene
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 542-75-6 | Z-1,3-Dichloropropene | 100 | 233-195-8 |
| Hazard Symbols: T N Risk Phrases: 10 20/21 25 36/37/38 43 50/53 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation and in contact with skin. Toxic if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Vapors cause eye irritation. Lachrymator (substance which increases the flow of tears). May cause severe eye irritation and possible injury. May cause temporary corneal clouding and ulceration.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Prolonged or widespread skin contact may result in the material being absorbed in harmful amounts.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
Inhalation:
Causes respiratory tract irritation. Causes narcotic effects including headache, dizziness, weakness, unconsciousness, and possible death. Effects of inhalation may be delayed. Easily attainable vapor concentrations may cause serious adverse effects, even death.
Chronic:
Possible cancer hazard based on tests with laboratory animals. May cause liver and kidney damage.
Flammable. Harmful by inhalation and in contact with skin. Toxic if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Vapors cause eye irritation. Lachrymator (substance which increases the flow of tears). May cause severe eye irritation and possible injury. May cause temporary corneal clouding and ulceration.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Prolonged or widespread skin contact may result in the material being absorbed in harmful amounts.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
Inhalation:
Causes respiratory tract irritation. Causes narcotic effects including headache, dizziness, weakness, unconsciousness, and possible death. Effects of inhalation may be delayed. Easily attainable vapor concentrations may cause serious adverse effects, even death.
Chronic:
Possible cancer hazard based on tests with laboratory animals. May cause liver and kidney damage.
Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
POISON material. If inhaled, get medical aid immediately. Remove victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
POISON material. If inhaled, get medical aid immediately. Remove victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. May accumulate static electrical charges, and may cause ignition of its own vapors. Fire or excessive heat may result in violent rupture of the container due to bulk polymerization. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. May accumulate static electrical charges, and may cause ignition of its own vapors. Fire or excessive heat may result in violent rupture of the container due to bulk polymerization. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Evacuate unnecessary personnel. Approach spill from upwind.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Evacuate unnecessary personnel. Approach spill from upwind.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapor or mist. Use only with adequate ventilation or respiratory protection. This product is corrosive to some metals. Do not use containers or equipment containing aluminum, magnesium, zinc, cadmium, or other alloys.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not store in aluminum containers.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapor or mist. Use only with adequate ventilation or respiratory protection. This product is corrosive to some metals. Do not use containers or equipment containing aluminum, magnesium, zinc, cadmium, or other alloys.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not store in aluminum containers.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Ventilation fans and other electrical service must be non-sparking and have an explosion-proof design.
Exposure Limits CAS# 542-75-6: Belgium - TWA: 1 ppm VLE; 4.6 mg/m3 VLE Germany: 0.11 ppm TWA; 0.5 mg/m3 TWA Germany: Skin absorber Malaysia: 1 ppm TWA; 4.5 mg/m3 TWA Netherlands: 1 ppm MAC; 5 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 1 ppm VLA-ED; 4.6 mg/m3 VLA-ED CAS# 10061-01-5: Belgium - TWA: (listed as 1,3-dichloropropene): 1 ppm VLE; 4.6 mg VLE Germany: (listed as 1,3-dichloropropene): Skin absorber Malaysia: (listed as 1,3-dichloropropene): 1 ppm TWA; 4.5 mg/m3 T Netherlands: (listed as 1,3-dichloropropene): 1 ppm MAC; 5 mg/m3 Russia: (listed as 1,3-dichloropropene): 5 mg/m3 TWA Spain: (listed as 1,3-dichloropropene): 1 ppm VLA-ED; 4.6 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin exposure. Use polyvinyl alcohol or fluorocarbon rubber (viton) gloves.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Ventilation fans and other electrical service must be non-sparking and have an explosion-proof design.
Exposure Limits CAS# 542-75-6: Belgium - TWA: 1 ppm VLE; 4.6 mg/m3 VLE Germany: 0.11 ppm TWA; 0.5 mg/m3 TWA Germany: Skin absorber Malaysia: 1 ppm TWA; 4.5 mg/m3 TWA Netherlands: 1 ppm MAC; 5 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 1 ppm VLA-ED; 4.6 mg/m3 VLA-ED CAS# 10061-01-5: Belgium - TWA: (listed as 1,3-dichloropropene): 1 ppm VLE; 4.6 mg VLE Germany: (listed as 1,3-dichloropropene): Skin absorber Malaysia: (listed as 1,3-dichloropropene): 1 ppm TWA; 4.5 mg/m3 T Netherlands: (listed as 1,3-dichloropropene): 1 ppm MAC; 5 mg/m3 Russia: (listed as 1,3-dichloropropene): 5 mg/m3 TWA Spain: (listed as 1,3-dichloropropene): 1 ppm VLA-ED; 4.6 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin exposure. Use polyvinyl alcohol or fluorocarbon rubber (viton) gloves.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear straw colored
Odor: sweetish odor - pungent odor - penetrating odor
pH: Not applicable.
Vapor Pressure: 30 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 108 deg C @ 760 mmHg
Freezing/Melting Point: -60 deg C
Autoignition Temperature: Not available.
Flash Point: 27 deg C ( 80.60 deg F)
Explosion Limits, lower: 5.50 vol %
Explosion Limits, upper: 14.50 vol %
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 1.2000g/cm3
Molecular Formula: C3H4Cl2
Molecular Weight: 110.97
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
May polymerize.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, aluminum, magnesium.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: May occur.
May polymerize.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, aluminum, magnesium.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: May occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 542-75-6: UC8310000 CAS# 10061-01-5: UC8325000 LD50/LC50:
CAS# 542-75-6: Inhalation, mouse: LC50 = 3220 mg/m3/2H; Oral, mouse: LD50 = 640 mg/kg; Oral, rat: LD50 = 470 mg/kg; Skin, rabbit: LD50 = 333 mg/kg; Skin, rat: LD50 = 775 mg/kg.
CAS# 10061-01-5.
Toxicity data from Dow AgroSciences: (rat) is 300 mg/kg (male), and 224 mg/kg (female).
Vapor LC50 (rat) (male) is 855 to 1035 ppm for 4 hours; Vapor LC50 (rat) (female) is 904 ppm for 4 hours.
Carcinogenicity:
1,3-Dichloropropene, mixed isomers - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 1/1/89 NTP: Suspect carcinogen IARC: Group 2B carcinogen Z-1,3-Dichloropropene - California: carcinogen, initial date 1/1/89 (listed as 1,3-Dichloropro NTP: Suspect carcinogen (listed as 1,3-Dichloropropene).
IARC: Group 2B carcinogen (listed as 1,3-Dichloropropene).
Other:
See actual entry in RTECS for complete information.
CAS# 542-75-6: UC8310000 CAS# 10061-01-5: UC8325000 LD50/LC50:
CAS# 542-75-6: Inhalation, mouse: LC50 = 3220 mg/m3/2H; Oral, mouse: LD50 = 640 mg/kg; Oral, rat: LD50 = 470 mg/kg; Skin, rabbit: LD50 = 333 mg/kg; Skin, rat: LD50 = 775 mg/kg.
CAS# 10061-01-5.
Toxicity data from Dow AgroSciences: (rat) is 300 mg/kg (male), and 224 mg/kg (female).
Vapor LC50 (rat) (male) is 855 to 1035 ppm for 4 hours; Vapor LC50 (rat) (female) is 904 ppm for 4 hours.
Carcinogenicity:
1,3-Dichloropropene, mixed isomers - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 1/1/89 NTP: Suspect carcinogen IARC: Group 2B carcinogen Z-1,3-Dichloropropene - California: carcinogen, initial date 1/1/89 (listed as 1,3-Dichloropro NTP: Suspect carcinogen (listed as 1,3-Dichloropropene).
IARC: Group 2B carcinogen (listed as 1,3-Dichloropropene).
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 4.1 mg/L; 96 Hr.; Static Conditions; 18 degrees CFish: Rainbow trout: LC50 = 5.9 mg/L; 96 Hr.; Static Conditions; 11-13 degrees CFish: Bluegill/Sunfish: LC50 = 6.1 mg/L; 96 Hr.; Static Conditions; 21-23 degrees CWater flea Daphnia: EC50 = 6.15 mg/L; 48 Hr.; Static Conditions; 21-23 degrees CBacteria: Phytobacterium phosphoreum: EC50 = 5.1 mg/L; 30 minutes; Microtox testAlgae: EC50 = 4.95 mg/L; 96 Hr.; None
Fish: Fathead Minnow: LC50 = 4.1 mg/L; 96 Hr.; Static Conditions; 18 degrees CFish: Rainbow trout: LC50 = 5.9 mg/L; 96 Hr.; Static Conditions; 11-13 degrees CFish: Bluegill/Sunfish: LC50 = 6.1 mg/L; 96 Hr.; Static Conditions; 21-23 degrees CWater flea Daphnia: EC50 = 6.15 mg/L; 48 Hr.; Static Conditions; 21-23 degrees CBacteria: Phytobacterium phosphoreum: EC50 = 5.1 mg/L; 30 minutes; Microtox testAlgae: EC50 = 4.95 mg/L; 96 Hr.; None
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Toxic Liquid, Flammable, Organic, N.O.S.
Hazard Class: 6.1 (3)
UN Number: 2929
Packing Group: II
IMO
Shipping Name: Toxic Liquid, Flammable, Organic, N.O.S.
Hazard Class: 6.1 (3)
UN Number: 2929
Packing Group: II
RID/ADR
Shipping Name: Toxic Liquid, Flammable, Organic, N.O.S.
Hazard Class: 6.1 (3)
UN Number: 2929
Packing group: II
USA RQ: CAS# 542-75-6: 100 lb final RQ; 45.4 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 10 Flammable.
R 20/21 Harmful by inhalation and in contact with
skin.
R 25 Toxic if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 542-75-6: 3
CAS# 10061-01-5: No information available.
Canada
CAS# 542-75-6 is listed on Canadas NDSL List.
CAS# 542-75-6 is listed on Canadas Ingredient Disclosure List.
CAS# 10061-01-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 542-75-6 is listed on the TSCA inventory.
CAS# 10061-01-5 is not listed on the TSCA inventory.
It is for research and development use only.
