Name:
4-Vinyl-1-cyclohexene 99% stabilized with 50-200 ppm bht
Synonym:
Butadine dimer; Cyclohexene, 4-ethenyl-; Cyclohexenylethylene; 4-Ethenyl-1-cyclohexene; 1,2,3,4-Tetrahydrostyrene; 1-Vinylcyclohexene-3; 1-Vinylcyclohex-3-ene; 4-Vinylcyclohexene; 4-Vinylcyclohexene; 4-Vinylcyclohexene-
CAS:
100-40-3
Section 1 - Chemical Product
MSDS Name:4-Vinyl-1-cyclohexene 99% stabilized with 50-200 ppm bht
Synonym:Butadine dimer; Cyclohexene, 4-ethenyl-; Cyclohexenylethylene; 4-Ethenyl-1-cyclohexene; 1,2,3,4-Tetrahydrostyrene; 1-Vinylcyclohexene-3; 1-Vinylcyclohex-3-ene; 4-Vinylcyclohexene; 4-Vinylcyclohexene; 4-Vinylcyclohexene-
Synonym:Butadine dimer; Cyclohexene, 4-ethenyl-; Cyclohexenylethylene; 4-Ethenyl-1-cyclohexene; 1,2,3,4-Tetrahydrostyrene; 1-Vinylcyclohexene-3; 1-Vinylcyclohex-3-ene; 4-Vinylcyclohexene; 4-Vinylcyclohexene; 4-Vinylcyclohexene-
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 100-40-3 | 4-Vinyl-1-cyclohexene, stab. with 50-2 | 99 | 202-848-9 |
| Hazard Symbols: XI F Risk Phrases: 11 38 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Irritating to skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis and corneal inflammation.
Skin:
Causes skin irritation.
Ingestion:
Ingestion of large amounts may cause CNS depression. Causes gastrointestinal tract irritation. Causes digestive tract irritation.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or suffocation. Exposure may cause headache and rhinitis (inflammation of the mucous membrane of the nose).
Chronic:
May cause cancer according to animal studies. Potential cancer hazard.
Highly flammable. Irritating to skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis and corneal inflammation.
Skin:
Causes skin irritation.
Ingestion:
Ingestion of large amounts may cause CNS depression. Causes gastrointestinal tract irritation. Causes digestive tract irritation.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or suffocation. Exposure may cause headache and rhinitis (inflammation of the mucous membrane of the nose).
Chronic:
May cause cancer according to animal studies. Potential cancer hazard.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Water may be ineffective. Use dry chemical, carbon dioxide, or appropriate foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Water may be ineffective. Use dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Wash area with soap and water. Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool.
Provide ventilation.
Spills/Leaks:
Wash area with soap and water. Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool.
Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Keep away from heat, sparks and flame. Use with adequate ventilation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapor.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator/flammables. Do not expose to air.
Wash thoroughly after handling. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Keep away from heat, sparks and flame. Use with adequate ventilation. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapor.
Storage:
Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigerator/flammables. Do not expose to air.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 100-40-3: Belgium - TWA: 0.1 ppm VLE; 0.45 mg/m3 VLE Malaysia: 0.1 ppm TWA; 0.4 mg/m3 TWA Netherlands: 0.1 ppm MAC; 0.4 mg/m3 MAC Spain: 0.1 ppm VLA-ED; 0.45 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 100-40-3: Belgium - TWA: 0.1 ppm VLE; 0.45 mg/m3 VLE Malaysia: 0.1 ppm TWA; 0.4 mg/m3 TWA Netherlands: 0.1 ppm MAC; 0.4 mg/m3 MAC Spain: 0.1 ppm VLA-ED; 0.45 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 25.8 mm Hg @ 38 C
Viscosity: 0.7 mPas 20 deg C
Boiling Point: 128 deg C @ 760.00mm Hg
Freezing/Melting Point: -109 deg C
Autoignition Temperature: 280 deg C ( 536.00 deg F)
Flash Point: 14 deg C ( 57.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: .8320g/cm3
Molecular Formula: C8H12
Molecular Weight: 108.18
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Oxidizes when exposed to air. May decompose on exposure to moist air or water. May discolor on exposure to air.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, alcohols, amines.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Oxidizes when exposed to air. May decompose on exposure to moist air or water. May discolor on exposure to air.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, alcohols, amines.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 100-40-3: GW6650000 LD50/LC50:
CAS# 100-40-3: Inhalation, mouse: LC50 = 27 gm/m3; Oral, rat: LD50 = 3080 uL/kg; Skin, rabbit: LD50 = 20 mL/kg.
Inhalation, rat: LC50 = 8000 Carcinogenicity:
4-Vinyl-1-cyclohexene, stab. with 50-200 ppm BHT - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 5/1/96 IARC: Group 2B carcinogen Other:
See actual entry in RTECS for complete information.
CAS# 100-40-3: GW6650000 LD50/LC50:
CAS# 100-40-3: Inhalation, mouse: LC50 = 27 gm/m3; Oral, rat: LD50 = 3080 uL/kg; Skin, rabbit: LD50 = 20 mL/kg.
Inhalation, rat: LC50 = 8000 Carcinogenicity:
4-Vinyl-1-cyclohexene, stab. with 50-200 ppm BHT - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 5/1/96 IARC: Group 2B carcinogen Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 38 Irritating to skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 100-40-3: 1
Canada
CAS# 100-40-3 is listed on Canadas DSL List.
CAS# 100-40-3 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-40-3 is listed on the TSCA inventory.
