Name:
50 wt% Nickel on alumina catalyst reduced and stabilized 15-25 M2 Ni
Synonym:
None
CAS:
1313-99-1
Section 1 - Chemical Product
MSDS Name:50 wt% Nickel on alumina catalyst reduced and stabilized 15-25 M2 Ni
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 1313-99-1 | Nickel monoxide | 18-22 | 215-215-7 |
| Hazard Symbols: T F Risk Phrases: 17 40 43 49 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Spontaneously flammable in air. Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. May cause cancer by inhalation.Cancer suspect agent.Air sensitive.Possible risks of irreversible effects.
Potential Health Effects
Eye:
May cause eye irritation. May cause redness, pain, blurred vision and possible eye damage.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Causes "nickel itch" which is a dermatitis resulting from sensitization to nickel, which is characterized by skin eruptions, followed by discrete ulcers that may discharge and become crusted, or by eczema.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage. May cause cardiac disturbances. May cause central nervous system effects. Ingestion of large amounts may cause gastroenteritis. Ingestion of large amounts may cause convulsions, tremors, muscular contractions or spasticity, diarrhea, or fever.
Inhalation:
May cause liver and kidney damage. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. May cause anosmia (loss of smell). May cause cardiac abnormalities. Inhalation at high concentrations may cause CNS depression and asphixiation.
Chronic:
May cause liver and kidney damage. May cause cancer according to animal studies. Symptoms of overexposure to nickel can cause sensitization, dermatitis, allergic asthma and pneumonitis.
Spontaneously flammable in air. Limited evidence of a carcinogenic effect. May cause sensitization by skin contact. May cause cancer by inhalation.Cancer suspect agent.Air sensitive.Possible risks of irreversible effects.
Potential Health Effects
Eye:
May cause eye irritation. May cause redness, pain, blurred vision and possible eye damage.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Causes "nickel itch" which is a dermatitis resulting from sensitization to nickel, which is characterized by skin eruptions, followed by discrete ulcers that may discharge and become crusted, or by eczema.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage. May cause cardiac disturbances. May cause central nervous system effects. Ingestion of large amounts may cause gastroenteritis. Ingestion of large amounts may cause convulsions, tremors, muscular contractions or spasticity, diarrhea, or fever.
Inhalation:
May cause liver and kidney damage. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. May cause anosmia (loss of smell). May cause cardiac abnormalities. Inhalation at high concentrations may cause CNS depression and asphixiation.
Chronic:
May cause liver and kidney damage. May cause cancer according to animal studies. Symptoms of overexposure to nickel can cause sensitization, dermatitis, allergic asthma and pneumonitis.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. Material can spontaneously ignite (pyrophoric) when exposed to air at normal or slightly elevated temperatures. Combustion generates toxic fumes. Use water spray to keep fire-exposed containers cool. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. May re-ignite after fire is extinguished. Containers may explode when heated. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use dry sand, Met-L-X powder, or G-1 graphite powder. Do NOT use water, carbon dioxide, or foam. Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. Material can spontaneously ignite (pyrophoric) when exposed to air at normal or slightly elevated temperatures. Combustion generates toxic fumes. Use water spray to keep fire-exposed containers cool. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. May re-ignite after fire is extinguished. Containers may explode when heated. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use dry sand, Met-L-X powder, or G-1 graphite powder. Do NOT use water, carbon dioxide, or foam. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Avoid generating dusty conditions. Remove all sources of ignition. Isolate area and deny entry. Provide ventilation.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Avoid generating dusty conditions. Remove all sources of ignition. Isolate area and deny entry. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Flammables-area.
Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Use only under a chemical fume hood.
Exposure Limits CAS# 1313-99-1: United Kingdom, WEL - TWA: (listed as nickel, inorganic compounds insoluble): 0.5 mg/m3 TWA (except nickel tetracarbonyl, as Ni) United Kingdom, WEL - STEL: (listed as nickel, inorganic compound insoluble): 1.5 mg/m3 STEL (except nickel tetracarbonyl, as Ni) United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel insoluble compounds).1 mg/m3 TWA (as Ni) (listed under Nickel soluble compounds).
Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL (as Ni) France - VME: 1 mg/m3 VME (as Ni) Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA (inhalable fraction, as Ni) Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC Ni) Spain: 0.1 mg/m3 VLA-ED (as Ni) CAS# 1344-28-1: United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 10 mg/m3 VLE (as Al) France - VME: 10 mg/m3 VME Japan: 0.5 mg/m3 OEL (respirable dust); 2 mg/m3 OEL (total dust) Malaysia: 10 mg/m3 TWA (particulate matter containing no asbestos <1% crystalline sili Netherlands: 10 mg/m3 MAC Spain: 10 mg/m3 VLA-ED CAS# 7440-02-0: United Kingdom, WEL - TWA: 0.5 mg/m3 TWA United Kingdom, WEL - STEL: 1.5 mg/m3 STEL United States OSHA: 1 mg/m3 TWA Belgium - TWA: 1 mg/m3 VLE France - VME: 1 mg/m3 VME; 1 mg/m3 VME (metal gratings) Germany: 0.5 mg/m3 TWA (inhalable fraction) Japan: 1 mg/m3 OEL Malaysia: 1.5 mg/m3 TWA (inhalable fraction) Netherlands: 1 mg/m3 MAC Russia: 0.05 mg/m3 TWA Spain: 1 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Use only under a chemical fume hood.
Exposure Limits CAS# 1313-99-1: United Kingdom, WEL - TWA: (listed as nickel, inorganic compounds insoluble): 0.5 mg/m3 TWA (except nickel tetracarbonyl, as Ni) United Kingdom, WEL - STEL: (listed as nickel, inorganic compound insoluble): 1.5 mg/m3 STEL (except nickel tetracarbonyl, as Ni) United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel insoluble compounds).1 mg/m3 TWA (as Ni) (listed under Nickel soluble compounds).
Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL (as Ni) France - VME: 1 mg/m3 VME (as Ni) Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA (inhalable fraction, as Ni) Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC Ni) Spain: 0.1 mg/m3 VLA-ED (as Ni) CAS# 1344-28-1: United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 10 mg/m3 VLE (as Al) France - VME: 10 mg/m3 VME Japan: 0.5 mg/m3 OEL (respirable dust); 2 mg/m3 OEL (total dust) Malaysia: 10 mg/m3 TWA (particulate matter containing no asbestos <1% crystalline sili Netherlands: 10 mg/m3 MAC Spain: 10 mg/m3 VLA-ED CAS# 7440-02-0: United Kingdom, WEL - TWA: 0.5 mg/m3 TWA United Kingdom, WEL - STEL: 1.5 mg/m3 STEL United States OSHA: 1 mg/m3 TWA Belgium - TWA: 1 mg/m3 VLE France - VME: 1 mg/m3 VME; 1 mg/m3 VME (metal gratings) Germany: 0.5 mg/m3 TWA (inhalable fraction) Japan: 1 mg/m3 OEL Malaysia: 1.5 mg/m3 TWA (inhalable fraction) Netherlands: 1 mg/m3 MAC Russia: 0.05 mg/m3 TWA Spain: 1 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: grey
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble in water.
Specific Gravity/Density:
Molecular Formula: Mixture
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, moisture, exposure to air, temperatures above 50C (122F).
Incompatibilities with Other Materials:
Acids; acid chlorides; oxidizing agents; sulfur; halogens; titanium; ammonium nitrate; potassium perchlorate; hydrazoic acid.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, aluminum oxide, nickel oxide.
Hazardous Polymerization: Has not been reported
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, moisture, exposure to air, temperatures above 50C (122F).
Incompatibilities with Other Materials:
Acids; acid chlorides; oxidizing agents; sulfur; halogens; titanium; ammonium nitrate; potassium perchlorate; hydrazoic acid.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, aluminum oxide, nickel oxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1313-99-1: QR8400000 QR8430000 CAS# 1344-28-1: BD1200000 CAS# 7440-02-0: QR5950000 QR6126100 QR6555000 QR7120000 LD50/LC50:
Not available.
Not available.
Not available.
Carcinogenicity:
Nickel monoxide - California: carcinogen, initial date 10/1/89 NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
Aluminum Oxide - Not listed by ACGIH, IARC, or NTP.
Nickel powder - California: carcinogen, initial date 10/1/89 NTP: Suspect carcinogen IARC: Group 1 carcinogen (listed as Nickel compounds).
Other:
See actual entry in RTECS for complete information.
CAS# 1313-99-1: QR8400000 QR8430000 CAS# 1344-28-1: BD1200000 CAS# 7440-02-0: QR5950000 QR6126100 QR6555000 QR7120000 LD50/LC50:
Not available.
Not available.
Not available.
Carcinogenicity:
Nickel monoxide - California: carcinogen, initial date 10/1/89 NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
Aluminum Oxide - Not listed by ACGIH, IARC, or NTP.
Nickel powder - California: carcinogen, initial date 10/1/89 NTP: Suspect carcinogen IARC: Group 1 carcinogen (listed as Nickel compounds).
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: METAL CATALYST, DRY
Hazard Class: 4.2
UN Number: 2881
Packing Group: II
IMO
Shipping Name: METAL CATALYST, DRY
Hazard Class: 4.2
UN Number: 2881
Packing Group: II
RID/ADR
Shipping Name: METAL CATALYST, DRY
Hazard Class: 4.2
UN Number: 2881
Packing group: II
USA RQ: CAS# 7440-02-0: 100 lb final RQ (no reporting of releases of this hazard
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 49 May cause cancer by inhalation.
R 17 Spontaneously flammable in air.
R 40 Limited evidence of a carcinogenic effect.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 24 Avoid contact with skin.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1313-99-1: 3
CAS# 1344-28-1: 0
CAS# 7440-02-0: No information available.
Canada
CAS# 1313-99-1 is listed on Canadas DSL List.
CAS# 1344-28-1 is listed on Canadas DSL List.
CAS# 7440-02-0 is listed on Canadas DSL List.
CAS# 1313-99-1 is listed on Canadas Ingredient Disclosure List.
CAS# 1344-28-1 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-02-0 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1313-99-1 is listed on the TSCA inventory.
CAS# 1344-28-1 is listed on the TSCA inventory.
CAS# 7440-02-0 is listed on the TSCA inventory.
