Name:
Acetic acid 1N
Synonym:
CAS:
64-19-7
Section 1 - Chemical Product
MSDS Name:Acetic acid 1N
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 64-19-7 | Acetic acid | 3-4 | 200-580-7 |
| Hazard Symbols: None Listed. Risk Phrases: None Listed. |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation and possible damage.
Skin:
May cause severe skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause lung damage.
Inhalation:
Effects may be delayed. May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth. May cause reproductive and fetal effects.
Laboratory experiments have resulted in mutagenic effects.
Not available.
Potential Health Effects
Eye:
May cause eye irritation and possible damage.
Skin:
May cause severe skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause lung damage.
Inhalation:
Effects may be delayed. May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth. May cause reproductive and fetal effects.
Laboratory experiments have resulted in mutagenic effects.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Reacts with most metals to form highly flammable hydrogen gas which can form explosive mixtures with air.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Reacts with most metals to form highly flammable hydrogen gas which can form explosive mixtures with air.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 64-19-7: United States OSHA: 10 ppm TWA; 25 mg/m3 TWA Belgium - TWA: 10 ppm VLE; 25 mg/m3 VLE Belgium - STEL: 15 ppm VLE; 38 mg/m3 VLE France - VLE: 10 ppm VLE; 25 mg/m3 VLE Germany: 10 ppm TWA; 25 mg/m3 TWA Japan: 10 ppm OEL; 25 mg/m3 OEL Malaysia: 10 ppm TWA; 25 mg/m3 TWA Netherlands: 10 ppm MAC; 25 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 10 ppm VLA-ED; 25 mg/m3 VLA-ED Spain: 15 ppm VLA-EC; 37 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 64-19-7: United States OSHA: 10 ppm TWA; 25 mg/m3 TWA Belgium - TWA: 10 ppm VLE; 25 mg/m3 VLE Belgium - STEL: 15 ppm VLE; 38 mg/m3 VLE France - VLE: 10 ppm VLE; 25 mg/m3 VLE Germany: 10 ppm TWA; 25 mg/m3 TWA Japan: 10 ppm OEL; 25 mg/m3 OEL Malaysia: 10 ppm TWA; 25 mg/m3 TWA Netherlands: 10 ppm MAC; 25 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 10 ppm VLA-ED; 25 mg/m3 VLA-ED Spain: 15 ppm VLA-EC; 37 mg/m3 VLA-EC CAS# 7732-18-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: CH3CO2H
Molecular Weight: 60.0268
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Metals, oxidizing agents, acids, bases, acetic anhydride, alcohols, amines, ammonium nitrate, bromine trifluoride, chlorine trifluoride, nitric acid, permanganates, sodium hydroxide, sodium peroxide, hydrogen peroxides, acetaldehyde, acid anhydrides, chlorosulfonic acid, oleum, potassium hydroxide, perchloric acid, potassium-tert-butoxide, ethyleneimine, 2-aminoethanol, ethylene diamine, phosphorus trichloride, chromic acid anhydride, phosphorus isocyanate, diallyl methyl carbinol + ozone, nitric acid + acetone, xylene.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Metals, oxidizing agents, acids, bases, acetic anhydride, alcohols, amines, ammonium nitrate, bromine trifluoride, chlorine trifluoride, nitric acid, permanganates, sodium hydroxide, sodium peroxide, hydrogen peroxides, acetaldehyde, acid anhydrides, chlorosulfonic acid, oleum, potassium hydroxide, perchloric acid, potassium-tert-butoxide, ethyleneimine, 2-aminoethanol, ethylene diamine, phosphorus trichloride, chromic acid anhydride, phosphorus isocyanate, diallyl methyl carbinol + ozone, nitric acid + acetone, xylene.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64-19-7: AF1225000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 64-19-7: Draize test, rabbit, skin: 50 mg/24H Mild; Inhalation, mouse: LC50 = 5620 ppm/1H; Oral, rat: LD50 = 3310 mg/kg; Skin, rabbit: LD50 = 1060 uL/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Acetic acid - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 64-19-7: AF1225000 CAS# 7732-18-5: ZC0110000 LD50/LC50:
CAS# 64-19-7: Draize test, rabbit, skin: 50 mg/24H Mild; Inhalation, mouse: LC50 = 5620 ppm/1H; Oral, rat: LD50 = 3310 mg/kg; Skin, rabbit: LD50 = 1060 uL/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Acetic acid - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Bluegill/Sunfish: TLm = 100; Unspecified; CAS# 64-19-7 Fresh waterFish: Goldfish: TLm = 75 ppm; 96 Hr; CAS# 64-19-7 Fresh waterFish: Fathead Minnow: LC50 = 88 mg/L; 96 Hr; Static bioassay @ 18-22CFish: Bluegill/Sunfish: LC50 = 75 mg/L; 96 Hr; UnspecifiedFish: Goldfish: LC50 = 423 mg/L; 24 Hr; UnspecifiedWater flea Daphnia: EC50 = 32-47 mg/L; 24-48 Hr; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 8.86-11 mg/L; 5,15,25 min; Microtox testAcetic acid: Bluegill (fresh water) TLm=75 ppm/96H Goldfish (fresh water) TLm=100 ppm/96H Shrimp (aerated water) LC50=100-330 ppm/48H
Fish: Bluegill/Sunfish: TLm = 100; Unspecified; CAS# 64-19-7 Fresh waterFish: Goldfish: TLm = 75 ppm; 96 Hr; CAS# 64-19-7 Fresh waterFish: Fathead Minnow: LC50 = 88 mg/L; 96 Hr; Static bioassay @ 18-22CFish: Bluegill/Sunfish: LC50 = 75 mg/L; 96 Hr; UnspecifiedFish: Goldfish: LC50 = 423 mg/L; 24 Hr; UnspecifiedWater flea Daphnia: EC50 = 32-47 mg/L; 24-48 Hr; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 8.86-11 mg/L; 5,15,25 min; Microtox testAcetic acid: Bluegill (fresh water) TLm=75 ppm/96H Goldfish (fresh water) TLm=100 ppm/96H Shrimp (aerated water) LC50=100-330 ppm/48H
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 64-19-7: 5000 lb final RQ; 2270 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 64-19-7: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 64-19-7 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 64-19-7 is listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 64-19-7 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
