Name:
Acetic-D3 Acid-D Packaged in 0.50 ml Ampules 99.9 Atom % D
Synonym:
None known
CAS:
1186-52-3
Section 1 - Chemical Product
MSDS Name:Acetic-D3 Acid-D Packaged in 0.50 ml Ampules 99.9 Atom % D
Synonym:None known
Synonym:None known
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 1186-52-3 | Acetic-D3 Acid-D | 99.9 | 214-693-4 |
| Hazard Symbols: C Risk Phrases: 10 35 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Causes severe burns.Corrosive.Hygroscopic (absorbs moisture from the air).Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Eye:
Contact with liquid or vapor causes severe burns and possible irreversible eye damage. Lachrymator (substance which increases the flow of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Causes severe burns with delayed tissue destruction. Contact with the skin may cause blackening and hyperkeratosis of the skin of the hands. May cause cyanosis of the extremities. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. Causes severe pain, nausea, vomiting, diarrhea, and shock.
May cause polyuria, oliguria (excretion of a diminished amount of urine in relation to the fluid intake) and anuria (complete suppression of urination). Ingestion of large amounts may cause CNS depression. May cause systemic effects. Rapidly absorbed from the gastrointestinal tract.
Inhalation:
Effects may be delayed. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema.
Vapors may cause dizziness or suffocation. Exposure may lead to bronchitis, pharyngitis, and dental erosion. May cause systemic effects. May be absorbed through the lungs. May cause burning sensation in the chest.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth. Effects may be delayed. Repeated exposure may lead to blackening and hyperkeratosis of the skin and hands, conjunctivitis, bronchitis and pharyngitis and erosion of the teeth.
Prolonged exposure may cause corneal erosion, conjunctivitis, and possible blindness.
Flammable. Causes severe burns.Corrosive.Hygroscopic (absorbs moisture from the air).Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Eye:
Contact with liquid or vapor causes severe burns and possible irreversible eye damage. Lachrymator (substance which increases the flow of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Causes severe burns with delayed tissue destruction. Contact with the skin may cause blackening and hyperkeratosis of the skin of the hands. May cause cyanosis of the extremities. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. Causes severe pain, nausea, vomiting, diarrhea, and shock.
May cause polyuria, oliguria (excretion of a diminished amount of urine in relation to the fluid intake) and anuria (complete suppression of urination). Ingestion of large amounts may cause CNS depression. May cause systemic effects. Rapidly absorbed from the gastrointestinal tract.
Inhalation:
Effects may be delayed. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema.
Vapors may cause dizziness or suffocation. Exposure may lead to bronchitis, pharyngitis, and dental erosion. May cause systemic effects. May be absorbed through the lungs. May cause burning sensation in the chest.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth. Effects may be delayed. Repeated exposure may lead to blackening and hyperkeratosis of the skin and hands, conjunctivitis, bronchitis and pharyngitis and erosion of the teeth.
Prolonged exposure may cause corneal erosion, conjunctivitis, and possible blindness.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Persons with pre-existing skin disorders or impaired respiratory or pulmonary function may be at increased risk to the effects of this substance. Treat symptomatically and supportively.
Antidote: No specific antidote exists.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Persons with pre-existing skin disorders or impaired respiratory or pulmonary function may be at increased risk to the effects of this substance. Treat symptomatically and supportively.
Antidote: No specific antidote exists.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Reacts with most metals to form highly flammable hydrogen gas which can form explosive mixtures with air. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May be ignited by friction, heat, sparks, or flame.
May polymerize explosively when involved in a fire. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT get water inside containers. Do NOT use straight streams of water.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Reacts with most metals to form highly flammable hydrogen gas which can form explosive mixtures with air. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May be ignited by friction, heat, sparks, or flame.
May polymerize explosively when involved in a fire. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT get water inside containers. Do NOT use straight streams of water.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Cover with material such as dry soda ash or calcium carbonate and place into a closed container for disposal. A vapor suppressing foam may be used to reduce vapors.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Cover with material such as dry soda ash or calcium carbonate and place into a closed container for disposal. A vapor suppressing foam may be used to reduce vapors.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale.
Use with adequate ventilation. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Keep under a nitrogen blanket. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store in a suitable container in a dry area above the substances freezing point. Do not store near alkaline substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale.
Use with adequate ventilation. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Keep under a nitrogen blanket. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store in a suitable container in a dry area above the substances freezing point. Do not store near alkaline substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 1186-52-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 1186-52-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: Clear colourless liquid
Odor: acetic odor
pH: Acidic (<2.0)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 115.5 deg C @ 760.00mm Hg
Freezing/Melting Point: 15 - 16 deg C
Autoignition Temperature: Not available.
Flash Point: 40 deg C ( 104.00 deg F)
Explosion Limits, lower: 4.00 vol %
Explosion Limits, upper: 17.00 vol %
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: 1.1370g/cm3
Molecular Formula: C2D4O2
Molecular Weight: 64.08
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Metals, oxidizing agents, bases, acetic anhydride, alcohols, amines, ammonia, ammonium nitrate, chlorine trifluoride, nitric acid, permanganates, peroxides, sodium hydroxide, sodium peroxide, alkylene oxides, alliphatic amines, hydrogen peroxides, acetaldehyde, caustics (e.g. ammonia, ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium hydroxide), isocyanates (e.g. methyl isocyanate), acid anhydrides, chlorosulfonic acid, oleum, chromium trioxide, potassium hydroxide, carbonates, bromine pentafluoride, perchloric acid, chromic anhydride, potassium-tert-butoxide, calcium salts, ethyleneimine, epichlorohydrin, Attacks some forms of plastics, rubbers, and coatings., 2-aminoethanol, ethylene diamine, phosphorus trichloride, alkanolamines, chromic acid anhydride, phosphorus isocyanate, diallyl methyl carbinol + ozone, nitric acid + acetone, xylene, sodium salts, chromic acid.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Metals, oxidizing agents, bases, acetic anhydride, alcohols, amines, ammonia, ammonium nitrate, chlorine trifluoride, nitric acid, permanganates, peroxides, sodium hydroxide, sodium peroxide, alkylene oxides, alliphatic amines, hydrogen peroxides, acetaldehyde, caustics (e.g. ammonia, ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium hydroxide), isocyanates (e.g. methyl isocyanate), acid anhydrides, chlorosulfonic acid, oleum, chromium trioxide, potassium hydroxide, carbonates, bromine pentafluoride, perchloric acid, chromic anhydride, potassium-tert-butoxide, calcium salts, ethyleneimine, epichlorohydrin, Attacks some forms of plastics, rubbers, and coatings., 2-aminoethanol, ethylene diamine, phosphorus trichloride, alkanolamines, chromic acid anhydride, phosphorus isocyanate, diallyl methyl carbinol + ozone, nitric acid + acetone, xylene, sodium salts, chromic acid.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1186-52-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Acetic-D3 Acid-D - Not listed by ACGIH, IARC, or NTP.
CAS# 1186-52-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Acetic-D3 Acid-D - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 88 mg/L; 96 Hr; Static bioassay @ 18-22CFish: Bluegill/Sunfish: LC50 = 75 mg/L; 96 Hr; UnspecifiedFish: Goldfish: LC50 = 423 mg/L; 24 Hr; UnspecifiedWater flea Daphnia: EC50 = 32-47 mg/L; 24-48 Hr; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 8.86-11 mg/L; 5,15,25 min; Microtox testIf released to water or soil, acetic acid will biodegrade readily. Evaporation from dry surfaces is likely to occur. When spilled on soil, the liquid will spread on the surface and penetrate into the soil at a rate dependent on the soil type and its water emsds. Acetic acid shows no potential for biological Other For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND EXPOSURE DATA."
Fish: Fathead Minnow: LC50 = 88 mg/L; 96 Hr; Static bioassay @ 18-22CFish: Bluegill/Sunfish: LC50 = 75 mg/L; 96 Hr; UnspecifiedFish: Goldfish: LC50 = 423 mg/L; 24 Hr; UnspecifiedWater flea Daphnia: EC50 = 32-47 mg/L; 24-48 Hr; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 8.86-11 mg/L; 5,15,25 min; Microtox testIf released to water or soil, acetic acid will biodegrade readily. Evaporation from dry surfaces is likely to occur. When spilled on soil, the liquid will spread on the surface and penetrate into the soil at a rate dependent on the soil type and its water emsds. Acetic acid shows no potential for biological Other For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND EXPOSURE DATA."
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: ACETIC ACID, GLACIAL
Hazard Class: 8 (3)
UN Number: 2789
Packing Group: II
IMO
Shipping Name: ACETIC ACID, GLACIAL
Hazard Class: 8 (3)
UN Number: 2789
Packing Group: II
RID/ADR
Shipping Name: ACETIC ACID, GLACIAL
Hazard Class: 8
UN Number: 2789
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 35 Causes severe burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1186-52-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1186-52-3 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1186-52-3 is not listed on the TSCA inventory.
It is for research and development use only.
