Name:
Ammonium Bifluoride
Synonym:
Ammonium Bifluoride; Ammonium Hydrofluoride; Ammonium Difluoride
CAS:
1341-49-7
Section 1 - Chemical Product
MSDS Name:Ammonium Bifluoride
Synonym:Ammonium Bifluoride; Ammonium Hydrofluoride; Ammonium Difluoride
Synonym:Ammonium Bifluoride; Ammonium Hydrofluoride; Ammonium Difluoride
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 1341-49-7 | AMMONIUM BIFLUORIDE | 100 | 215-676-4 |
| Hazard Symbols: T C Risk Phrases: 25 34 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic if swallowed. Causes burns.Corrosive.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Contact with liquid is corrosive and causes severe burns and ulceration. May penetrate the skin and cause severe tissue and bone destruction. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the digestive tract. May cause kidney damage. May cause perforation of the digestive tract. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. Inorganic fluorides can be harmful. Acute exposure to fluorine compounds can lead to digestive tract burns, and abdominal pain. Fluoride can reduce calcium levels leading to fatal hypocalcemia. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Aspiration may lead to pulmonary edema. Depletes calcium levels in the body which can lead to hypocalcemia and death. May cause systemic effects.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride poisoning (fluorosis) characterized by weight loss, weakness, anemia, brittle bones, and stiff joints. May cause digestive tract disturbances. Effects may be delayed. Chronic exposure to fluoride compounds may cause systemic toxicity.
Toxic if swallowed. Causes burns.Corrosive.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Contact with liquid is corrosive and causes severe burns and ulceration. May penetrate the skin and cause severe tissue and bone destruction. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the digestive tract. May cause kidney damage. May cause perforation of the digestive tract. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. Inorganic fluorides can be harmful. Acute exposure to fluorine compounds can lead to digestive tract burns, and abdominal pain. Fluoride can reduce calcium levels leading to fatal hypocalcemia. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Aspiration may lead to pulmonary edema. Depletes calcium levels in the body which can lead to hypocalcemia and death. May cause systemic effects.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride poisoning (fluorosis) characterized by weight loss, weakness, anemia, brittle bones, and stiff joints. May cause digestive tract disturbances. Effects may be delayed. Chronic exposure to fluoride compounds may cause systemic toxicity.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Keep away from heat and flame. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Keep away from acids. Keep away from strong bases. Store protected from moisture.
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Keep away from heat and flame. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Keep away from acids. Keep away from strong bases. Store protected from moisture.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirators use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirators use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white
Odor: Slightly pungent
pH: 3.5 @ 5% solution.
Vapor Pressure: 1 hPa @ 20 deg C
Viscosity: Not available.
Boiling Point: 239.5 deg C @ 760.00mm Hg
Freezing/Melting Point: 125 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 630 G/L WATER (20C)
Specific Gravity/Density: 1.50
Molecular Formula: H5F2N
Molecular Weight: 57.04
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture, exposure to moist air or water, temperatures above 300C.
Incompatibilities with Other Materials:
Moisture, acids, bases, glass.
Hazardous Decomposition Products:
Hydrogen fluoride gas, ammonia and/or derivatives.
Hazardous Polymerization: Will not occur.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture, exposure to moist air or water, temperatures above 300C.
Incompatibilities with Other Materials:
Moisture, acids, bases, glass.
Hazardous Decomposition Products:
Hydrogen fluoride gas, ammonia and/or derivatives.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1341-49-7: BQ9200000 LD50/LC50:
Not available.
Carcinogenicity:
AMMONIUM BIFLUORIDE - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
CAS# 1341-49-7: BQ9200000 LD50/LC50:
Not available.
Carcinogenicity:
AMMONIUM BIFLUORIDE - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: AMMONIUM HYDROGEN DIFLUORIDE, SOLID
Hazard Class: 8
UN Number: 1727
Packing Group: II
IMO
Shipping Name: AMMONIUM HYDROGEN DIFLUORIDE, SOLID
Hazard Class: 8
UN Number: 1727
Packing Group: II
RID/ADR
Shipping Name: AMMONIUM HYDROGEN DIFLUORIDE, SOLID
Hazard Class: 8
UN Number: 1727
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T C
Risk Phrases:
R 25 Toxic if swallowed.
R 34 Causes burns.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1341-49-7: 1
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1341-49-7 is not listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 1341-49-7: OEL-AUSTRALIA:TWA 2.5 mg(F)/m3
OEL-BELGIUM:TWA 2.5 mg(F)/m3
OEL-CZECHOSLOVAKIA:TWA 1 mg(F)/m3;STEL 5 mg(F)/m3
OEL-DENMARK:TWA 2.5 mg(F)/m3
OEL-FINLAND:TWA 2.5 mg(F)/m3
OEL-FRANCE:TWA 2.5 mg(F)/m3
OEL-GERMANY:TWA 2.5 mg(F)/m3
OEL-HUNGARY:TWA 1 mg(F)/m3;STEL 2 mg(F)/m3
OEL-THE NETHERLANDS:TWA 2.5 mg(F)/m3
OEL-THE PHILIPPINES:TWA 2.5 mg(F)/m3
OEL-POLAND:TWA 1 mg(F)/m3
OEL-RUSSIA:TWA 0.2 mg/m3;STEL 1 mg/m3
OEL-SWEDEN:TWA 2 mg(F)/m3
OEL-SWITZERLAND:TWA 1.8 ppm (1.5 mg(F)/m3);STEL 9.0 ppm
OEL-THAILAND:TWA 2.5 mg(F)/m3
OEL-TURKEY:TWA 2.5 mg(F)/m3
OEL-UNITED KINGDOM:TWA 2.5 mg(F)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 1341-49-7 is not listed on the TSCA inventory.
It is for research and development use only.
