Name:
Ammonium Sulfamate Reagent ACS 98+% (Titr.)
Synonym:
Ammonium Amidosulfonate; Ammonium Amidosulphate; Ammate
CAS:
7773-06-0
Section 1 - Chemical Product
MSDS Name:Ammonium Sulfamate Reagent ACS 98+% (Titr.)
Synonym:Ammonium Amidosulfonate; Ammonium Amidosulphate; Ammate
Synonym:Ammonium Amidosulfonate; Ammonium Amidosulphate; Ammate
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7773-06-0 | Ammonium Sulfamate | 98 | 231-871-7 |
| Hazard Symbols: O Risk Phrases: 8 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Contact with combustible material may cause fire.
Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis. May cause permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May be harmful if swallowed. May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
May cause respiratory tract irritation. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Effects may be delayed.
Contact with combustible material may cause fire.
Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis. May cause permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May be harmful if swallowed. May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
May cause respiratory tract irritation. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Effects may be delayed.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Use water with caution and in flooding amounts. May polymerize explosively when involved in a fire. Containers may explode when heated.
Extinguishing Media:
For large fires, use water spray, fog or regular foam. For small fires, use dry chemical, carbon dioxide, water spray or regular foam.
Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Use water with caution and in flooding amounts. May polymerize explosively when involved in a fire. Containers may explode when heated.
Extinguishing Media:
For large fires, use water spray, fog or regular foam. For small fires, use dry chemical, carbon dioxide, water spray or regular foam.
Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a cool, dry place. Keep container closed when not in use.
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a cool, dry place. Keep container closed when not in use.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7773-06-0: United Kingdom, WEL - TWA: 10 mg/m3 TWA United Kingdom, WEL - STEL: 20 mg/m3 STEL United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 10 mg/m3 VLE France - VME: 10 mg/m3 VME Germany: 15 mg/m3 TWA (inhalable fraction) Malaysia: 10 mg/m3 TWA Netherlands: 10 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 10 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7773-06-0: United Kingdom, WEL - TWA: 10 mg/m3 TWA United Kingdom, WEL - STEL: 20 mg/m3 STEL United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 10 mg/m3 VLE France - VME: 10 mg/m3 VME Germany: 15 mg/m3 TWA (inhalable fraction) Malaysia: 10 mg/m3 TWA Netherlands: 10 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 10 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 160 deg C (decomposes)
Freezing/Melting Point: 131 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 160 deg C
Solubility in water: Soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: H2NO3S.H4N
Molecular Weight: 96.0789
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents, temperatures above 150C.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Oxides of sulfur, nitrogen oxides (NOx) and ammonia (NH3).
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents, temperatures above 150C.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Oxides of sulfur, nitrogen oxides (NOx) and ammonia (NH3).
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7773-06-0: WO6125000 LD50/LC50:
CAS# 7773-06-0: Oral, mouse: LD50 = 3100 mg/kg; Oral, rat: LD50 = 2 gm/kg.
Carcinogenicity:
Ammonium Sulfamate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7773-06-0: WO6125000 LD50/LC50:
CAS# 7773-06-0: Oral, mouse: LD50 = 3100 mg/kg; Oral, rat: LD50 = 2 gm/kg.
Carcinogenicity:
Ammonium Sulfamate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 7773-06-0: 5000 lb final RQ; 2270 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7773-06-0: 1
Canada
CAS# 7773-06-0 is listed on Canadas DSL List.
CAS# 7773-06-0 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7773-06-0 is listed on the TSCA inventory.
