Name:
Antimony trichloride reagent ACS crystals 99+%
Synonym:
Trichlorostibine; Antimonous chloride; Antimony(III) chloride; Antimony trichloride
CAS:
10025-91-9
Section 1 - Chemical Product
MSDS Name:Antimony trichloride reagent ACS crystals 99+%
Synonym:Trichlorostibine; Antimonous chloride; Antimony(III) chloride; Antimony trichloride
Synonym:Trichlorostibine; Antimonous chloride; Antimony(III) chloride; Antimony trichloride
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 10025-91-9 | Antimony(III) chloride | >99 | 233-047-2 |
| Hazard Symbols: C N Risk Phrases: 34 51/53 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Corrosive.Moisture sensitive.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May be harmful if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract. May cause lung damage. May produce cardiovascular effects.
Chronic:
Chronic exposure may cause liver damage.
Causes burns. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Corrosive.Moisture sensitive.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May be harmful if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract. May cause lung damage. May produce cardiovascular effects.
Chronic:
Chronic exposure may cause liver damage.
Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. May react with metals and lead to the formation of flammable hydrogen gas.
Substance may react with water, and may release corrosive and/or toxic gases.
Extinguishing Media:
Do NOT get water inside containers. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. For small fires, use carbon dioxide, dry chemical, dry sand, or alcohol-resistant foam. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. May react with metals and lead to the formation of flammable hydrogen gas.
Substance may react with water, and may release corrosive and/or toxic gases.
Extinguishing Media:
Do NOT get water inside containers. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. For small fires, use carbon dioxide, dry chemical, dry sand, or alcohol-resistant foam. Most foams will react with the material and release corrosive/toxic gases. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Keep away from metals. Corrosives area. Keep containers tightly closed.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Keep away from metals. Corrosives area. Keep containers tightly closed.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 10025-91-9: United Kingdom, WEL - TWA: (listed as antimony compounds): 0.5 mg TWA (except stibine, as Sb) United Kingdom, WEL - STEL: (listed as antimony compounds): 1.5 m STEL (except stibine, as Sb) United States OSHA: 0.5 mg/m3 TWA (listed under Antimony).0.5 mg TWA (as Sb) (listed under Antimony compounds).
Belgium - TWA: (listed as antimony compounds): 0.5 mg/m3 VLE (as France - VME: (listed as antimony compounds): 0.5 mg/m3 VME (as S Germany: (listed as antimony compounds): 0.5 mg/m3 VME (as Sb) Japan: (listed as antimony compounds): 0.1 mg/m3 OEL (except stib as Sb) Malaysia: (listed as antimony compounds): 0.5 mg/m3 TWA (as Sb) Netherlands: (listed as antimony compounds): 0.5 mg/m3 MAC (as Sb Russia: 0.3 mg/m3 TWA Russia: (listed as antimony): 0.2 mg/m3 STEL Spain: (listed as antimony compounds): 0.5 mg/m3 VLA-ED (except antimony hydride, as Sb) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 10025-91-9: United Kingdom, WEL - TWA: (listed as antimony compounds): 0.5 mg TWA (except stibine, as Sb) United Kingdom, WEL - STEL: (listed as antimony compounds): 1.5 m STEL (except stibine, as Sb) United States OSHA: 0.5 mg/m3 TWA (listed under Antimony).0.5 mg TWA (as Sb) (listed under Antimony compounds).
Belgium - TWA: (listed as antimony compounds): 0.5 mg/m3 VLE (as France - VME: (listed as antimony compounds): 0.5 mg/m3 VME (as S Germany: (listed as antimony compounds): 0.5 mg/m3 VME (as Sb) Japan: (listed as antimony compounds): 0.1 mg/m3 OEL (except stib as Sb) Malaysia: (listed as antimony compounds): 0.5 mg/m3 TWA (as Sb) Netherlands: (listed as antimony compounds): 0.5 mg/m3 MAC (as Sb Russia: 0.3 mg/m3 TWA Russia: (listed as antimony): 0.2 mg/m3 STEL Spain: (listed as antimony compounds): 0.5 mg/m3 VLA-ED (except antimony hydride, as Sb) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white
Odor: pungent odor
pH: Not available.
Vapor Pressure: 1 mm Hg @ 49.2C
Viscosity: Not available.
Boiling Point: 223 deg C
Freezing/Melting Point: 73 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: soluble (but hydrolysis to SbOCl)
Specific Gravity/Density: 3.14
Molecular Formula: SbCl3
Molecular Weight: 228.11
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Imcompatible with aluminum, potassium and sodium, perchloric acid.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, irritating and toxic fumes and gases, antimony/antimony oxides.
Hazardous Polymerization: Has not been reported.
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Imcompatible with aluminum, potassium and sodium, perchloric acid.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, irritating and toxic fumes and gases, antimony/antimony oxides.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10025-91-9: CC4900000 LD50/LC50:
CAS# 10025-91-9: Oral, rat: LD50 = 525 mg/kg.
Inhalation TCLo (human): 73 mg/m3.
Carcinogenicity:
Antimony(III) chloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 10025-91-9: CC4900000 LD50/LC50:
CAS# 10025-91-9: Oral, rat: LD50 = 525 mg/kg.
Inhalation TCLo (human): 73 mg/m3.
Carcinogenicity:
Antimony(III) chloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: ANTIMONY TRICHLORIDE, SOLID
Hazard Class: 8
UN Number: 1733
Packing Group: II
IMO
Shipping Name: ANTIMONY TRICHLORIDE, SOLID
Hazard Class: 8
UN Number: 1733
Packing Group: II
RID/ADR
Shipping Name: ANTIMONY TRICHLORIDE, SOLID
Hazard Class: 8
UN Number: 1733
Packing group: II
USA RQ: CAS# 10025-91-9: 1000 lb final RQ; 454 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C N
Risk Phrases:
R 34 Causes burns.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 10025-91-9: 2
Canada
CAS# 10025-91-9 is listed on Canadas DSL List.
CAS# 10025-91-9 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10025-91-9 is listed on the TSCA inventory.
