Name:
Aqualine Anolyte-K
Synonym:
None
CAS:
108-32-7
Section 1 - Chemical Product
MSDS Name:Aqualine Anolyte-K
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 108-32-7 | Propylene carbonate | 45-50 | 203-572-1 |
| Hazard Symbols: XN Risk Phrases: 20/21/22 36/38 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May produce aplastic anemia with tremors and marked mental dullness. May produce blood disturbances with or without neurological signs.
Inhalation:
May be harmful if inhaled. Causes upper respiratory tract irritation. May cause edema of lungs or glottis and can produce respiratory paralysis. May cause irritation and burning of the eyes, tearing, coughing and irritation of nose and throat.
Chronic:
Chronic exposure can affect thyroid function.
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May produce aplastic anemia with tremors and marked mental dullness. May produce blood disturbances with or without neurological signs.
Inhalation:
May be harmful if inhaled. Causes upper respiratory tract irritation. May cause edema of lungs or glottis and can produce respiratory paralysis. May cause irritation and burning of the eyes, tearing, coughing and irritation of nose and throat.
Chronic:
Chronic exposure can affect thyroid function.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Do not flush into a sewer. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Do not flush into a sewer. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 108-32-7: Russia: 7 mg/m3 TWA CAS# 111-90-0: Netherlands: 32 ppm MAC; 180 mg/m3 MAC CAS# 1122-58-3: CAS# 7446-09-5: United States OSHA: 5 ppm TWA; 13 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 5 ppm VLE; 10 mg/m3 VLE Germany: 1 ppm TWA (paper production, chemical and pharmaceutical industries); 2.5 mg/m3 Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA Netherlands: 2 ppm MAC; 5 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC CAS# 7553-56-2: United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA Germany: Skin absorber Japan: 0.1 ppm OEL; 1 mg/m3 OEL Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling Russia: 1 mg/m3 TWA Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC CAS# 17252-51-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 108-32-7: Russia: 7 mg/m3 TWA CAS# 111-90-0: Netherlands: 32 ppm MAC; 180 mg/m3 MAC CAS# 1122-58-3: CAS# 7446-09-5: United States OSHA: 5 ppm TWA; 13 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 5 ppm VLE; 10 mg/m3 VLE Germany: 1 ppm TWA (paper production, chemical and pharmaceutical industries); 2.5 mg/m3 Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA Netherlands: 2 ppm MAC; 5 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC CAS# 7553-56-2: United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA Germany: Skin absorber Japan: 0.1 ppm OEL; 1 mg/m3 OEL Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling Russia: 1 mg/m3 TWA Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC CAS# 17252-51-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear yellow
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 105 deg C ( 221.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: 1.14
Molecular Formula: Solution
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Metals, oxidizing agents, acrolein, aluminum, chlorates, chlorine trifluoride, fluorine, halogens, iron oxide, potassium chlorates, cesium acetylene carbide, rubidium acetylene carbide, sodium acetylene carbide, acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), amides (e.g. butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates (e.g. carbanolate, carbofuran), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g.
butyl acetate, ethyl acetate, propyl fo.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Metals, oxidizing agents, acrolein, aluminum, chlorates, chlorine trifluoride, fluorine, halogens, iron oxide, potassium chlorates, cesium acetylene carbide, rubidium acetylene carbide, sodium acetylene carbide, acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), amides (e.g. butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates (e.g. carbanolate, carbofuran), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g.
butyl acetate, ethyl acetate, propyl fo.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 108-32-7: FF9650000 CAS# 111-90-0: KK8750000 CAS# 1122-58-3: US9230000 CAS# 7446-09-5: WS4550000 CAS# 7553-56-2: NN1575000 CAS# 17252-51-6 unlisted.
LD50/LC50:
CAS# 108-32-7: Draize test, rabbit, eye: 60 mg Moderate; Draize test, rabbit, skin: 500 mg Moderate; Inhalation, rat: LC50 = >5 gm/m3; Oral, mouse: LD50 = 20700 mg/kg; Oral, rat: LD50 = 29100 uL/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 111-90-0: Dermal, guinea pig: LD50 = >32 gm/kg; Draize test, rabbit, eye: 500 mg Moderate; Draize test, rabbit, eye: 125 mg Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >5240 mg/m3/4H; Oral, mouse: LD50 = 6600 uL/kg; Oral, mouse: LD50 = 7250 mg/kg; Oral, rabbit: LD50 = 3620 mg/kg; Oral, rat: LD50 = 5500 uL/kg; Oral, rat: LD50 = 7500 mg/kg; Skin, rabbit: LD50 = 4200 uL/kg; Skin, rabbit: LD50 = 8.5 ml/kg/2H; Skin, rat: LD50 = 6 mL/kg.
CAS# 1122-58-3: Oral, rat: LD50 = 250 mg/kg; Skin, rabbit: LD50 = 13 mg/kg.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild; Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520 ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 = 1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg.
CAS# 17252-51-6.
Carcinogenicity:
Propylene carbonate - Not listed by ACGIH, IARC, or NTP.
Diethylene glycol monoethyl ether - Not listed by ACGIH, IARC, or NTP.
4-Dimethylaminopyridine - Not listed by ACGIH, IARC, or NTP.
Sulfur dioxide - Not listed by ACGIH, IARC, or NTP.
Iodine - Not listed by ACGIH, IARC, or NTP.
1,3-di-4-pyridylpropane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 108-32-7: FF9650000 CAS# 111-90-0: KK8750000 CAS# 1122-58-3: US9230000 CAS# 7446-09-5: WS4550000 CAS# 7553-56-2: NN1575000 CAS# 17252-51-6 unlisted.
LD50/LC50:
CAS# 108-32-7: Draize test, rabbit, eye: 60 mg Moderate; Draize test, rabbit, skin: 500 mg Moderate; Inhalation, rat: LC50 = >5 gm/m3; Oral, mouse: LD50 = 20700 mg/kg; Oral, rat: LD50 = 29100 uL/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 111-90-0: Dermal, guinea pig: LD50 = >32 gm/kg; Draize test, rabbit, eye: 500 mg Moderate; Draize test, rabbit, eye: 125 mg Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >5240 mg/m3/4H; Oral, mouse: LD50 = 6600 uL/kg; Oral, mouse: LD50 = 7250 mg/kg; Oral, rabbit: LD50 = 3620 mg/kg; Oral, rat: LD50 = 5500 uL/kg; Oral, rat: LD50 = 7500 mg/kg; Skin, rabbit: LD50 = 4200 uL/kg; Skin, rabbit: LD50 = 8.5 ml/kg/2H; Skin, rat: LD50 = 6 mL/kg.
CAS# 1122-58-3: Oral, rat: LD50 = 250 mg/kg; Skin, rabbit: LD50 = 13 mg/kg.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild; Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520 ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 = 1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg.
CAS# 17252-51-6.
Carcinogenicity:
Propylene carbonate - Not listed by ACGIH, IARC, or NTP.
Diethylene glycol monoethyl ether - Not listed by ACGIH, IARC, or NTP.
4-Dimethylaminopyridine - Not listed by ACGIH, IARC, or NTP.
Sulfur dioxide - Not listed by ACGIH, IARC, or NTP.
Iodine - Not listed by ACGIH, IARC, or NTP.
1,3-di-4-pyridylpropane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Cas# 111-90-0: The Koc of diethylene glycol monoethyl ether is estimated as approximately 12, using a measured log Kow of -0.54 and a regression-derived equation. According to a recommended classification scheme, this estimated Koc value suggests that diethylene glycol monoethyl ether has very high mobility in soil.
Cas# 111-90-0: The Koc of diethylene glycol monoethyl ether is estimated as approximately 12, using a measured log Kow of -0.54 and a regression-derived equation. According to a recommended classification scheme, this estimated Koc value suggests that diethylene glycol monoethyl ether has very high mobility in soil.
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 108-32-7: 0
CAS# 111-90-0: 1
CAS# 1122-58-3: No information available.
CAS# 7446-09-5: 1
CAS# 7553-56-2: 1
CAS# 17252-51-6: No information available.
Canada
CAS# 108-32-7 is listed on Canadas DSL List.
CAS# 111-90-0 is listed on Canadas DSL List.
CAS# 1122-58-3 is listed on Canadas DSL List.
CAS# 7446-09-5 is listed on Canadas DSL List.
CAS# 7553-56-2 is listed on Canadas DSL List.
CAS# 17252-51-6 is listed on Canadas NDSL List.
CAS# 108-32-7 is listed on Canadas Ingredient Disclosure List.
CAS# 111-90-0 is listed on Canadas Ingredient Disclosure List.
CAS# 1122-58-3 is not listed on Canadas Ingredient Disclosure List.
CAS# 7446-09-5 is listed on Canadas Ingredient Disclosure List.
CAS# 7553-56-2 is listed on Canadas Ingredient Disclosure List.
CAS# 17252-51-6 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-32-7 is listed on the TSCA inventory.
CAS# 111-90-0 is listed on the TSCA inventory.
CAS# 1122-58-3 is listed on the TSCA inventory.
CAS# 7446-09-5 is listed on the TSCA inventory.
CAS# 7553-56-2 is listed on the TSCA inventory.
CAS# 17252-51-6 is listed on the TSCA inventory.
