Name:
Aqualine Complete 5 2 & 1
Synonym:
None
CAS:
111-90-0
Section 1 - Chemical Product
MSDS Name:Aqualine Complete 5 2 & 1
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 111-90-0 | Diethylene glycol monoethyl ether | 65-85 | 203-919-7 |
| Hazard Symbols: C N Risk Phrases: 20/21/22 34 50 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Causes burns. Very toxic to aquatic organisms.
Potential Health Effects
Eye:
Causes eye burns. May cause transient corneal injury. Causes redness and pain.
Skin:
Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. May cause kidney damage. May cause central nervous system depression. May cause thyroid abnormalities. May produce aplastic anemia with tremors and marked mental dullness. May produce blood disturbances with or without neurological signs.
Inhalation:
Causes chemical burns to the respiratory tract. May cause kidney damage. May cause edema of lungs or glottis and can produce respiratory paralysis. Harmful if inhaled.
Chronic:
May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Chronic exposure can affect thyroid function. May cause kidney damage.
Harmful by inhalation, in contact with skin and if swallowed. Causes burns. Very toxic to aquatic organisms.
Potential Health Effects
Eye:
Causes eye burns. May cause transient corneal injury. Causes redness and pain.
Skin:
Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. May cause kidney damage. May cause central nervous system depression. May cause thyroid abnormalities. May produce aplastic anemia with tremors and marked mental dullness. May produce blood disturbances with or without neurological signs.
Inhalation:
Causes chemical burns to the respiratory tract. May cause kidney damage. May cause edema of lungs or glottis and can produce respiratory paralysis. Harmful if inhaled.
Chronic:
May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Chronic exposure can affect thyroid function. May cause kidney damage.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Monitor kidney function closely.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Monitor kidney function closely.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray, dry chemical, carbon dioxide, or chemical foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Do not flush into a sewer. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Do not flush into a sewer. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Store protected from light. If peroxide formation is suspected, do not open or move container. Discard contaminated shoes. Use only with adequate ventilation.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. After opening, purge container with nitrogen before reclosing. Periodically test for peroxide formation on long-term storage. Addition of water or appropriate reducing materials will lessen peroxide formation.
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Store protected from light. If peroxide formation is suspected, do not open or move container. Discard contaminated shoes. Use only with adequate ventilation.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. After opening, purge container with nitrogen before reclosing. Periodically test for peroxide formation on long-term storage. Addition of water or appropriate reducing materials will lessen peroxide formation.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 111-90-0: Netherlands: 32 ppm MAC; 180 mg/m3 MAC CAS# 288-32-4: CAS# 7446-09-5: United States OSHA: 5 ppm TWA; 13 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 5 ppm VLE; 10 mg/m3 VLE Germany: 1 ppm TWA (paper production, chemical and pharmaceutical industries); 2.5 mg/m3 Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA Netherlands: 2 ppm MAC; 5 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC CAS# 7553-56-2: United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA Germany: Skin absorber Japan: 0.1 ppm OEL; 1 mg/m3 OEL Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling Russia: 1 mg/m3 TWA Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 111-90-0: Netherlands: 32 ppm MAC; 180 mg/m3 MAC CAS# 288-32-4: CAS# 7446-09-5: United States OSHA: 5 ppm TWA; 13 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 5 ppm VLE; 10 mg/m3 VLE Germany: 1 ppm TWA (paper production, chemical and pharmaceutical industries); 2.5 mg/m3 Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA Netherlands: 2 ppm MAC; 5 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC CAS# 7553-56-2: United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA Germany: Skin absorber Japan: 0.1 ppm OEL; 1 mg/m3 OEL Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling Russia: 1 mg/m3 TWA Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless
Odor: alcohol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. Explosive peroxides may form on concentration. Peroxides can be detonated by friction, impact, or heating.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, acid chlorides, acid anhydrides.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported
Stable under normal temperatures and pressures. Explosive peroxides may form on concentration. Peroxides can be detonated by friction, impact, or heating.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, acid chlorides, acid anhydrides.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 111-90-0: KK8750000 CAS# 288-32-4: NI3325000 CAS# 7446-09-5: WS4550000 CAS# 7553-56-2: NN1575000 LD50/LC50:
CAS# 111-90-0: Dermal, guinea pig: LD50 = >32 gm/kg; Draize test, rabbit, eye: 500 mg Moderate; Draize test, rabbit, eye: 125 mg Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >5240 mg/m3/4H; Oral, mouse: LD50 = 6600 uL/kg; Oral, mouse: LD50 = 7250 mg/kg; Oral, rabbit: LD50 = 3620 mg/kg; Oral, rat: LD50 = 5500 uL/kg; Oral, rat: LD50 = 7500 mg/kg; Skin, rabbit: LD50 = 4200 uL/kg; Skin, rabbit: LD50 = 8.5 ml/kg/2H; Skin, rat: LD50 = 6 mL/kg.
CAS# 288-32-4: Oral, mouse: LD50 = 880 mg/kg; Oral, rat: LD50 = 220 mg/kg.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild; Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520 ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 = 1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg.
Carcinogenicity:
Diethylene glycol monoethyl ether - Not listed by ACGIH, IARC, or NTP.
Imidazole - Not listed by ACGIH, IARC, or NTP.
Sulfur dioxide - Not listed by ACGIH, IARC, or NTP.
Iodine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 111-90-0: KK8750000 CAS# 288-32-4: NI3325000 CAS# 7446-09-5: WS4550000 CAS# 7553-56-2: NN1575000 LD50/LC50:
CAS# 111-90-0: Dermal, guinea pig: LD50 = >32 gm/kg; Draize test, rabbit, eye: 500 mg Moderate; Draize test, rabbit, eye: 125 mg Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >5240 mg/m3/4H; Oral, mouse: LD50 = 6600 uL/kg; Oral, mouse: LD50 = 7250 mg/kg; Oral, rabbit: LD50 = 3620 mg/kg; Oral, rat: LD50 = 5500 uL/kg; Oral, rat: LD50 = 7500 mg/kg; Skin, rabbit: LD50 = 4200 uL/kg; Skin, rabbit: LD50 = 8.5 ml/kg/2H; Skin, rat: LD50 = 6 mL/kg.
CAS# 288-32-4: Oral, mouse: LD50 = 880 mg/kg; Oral, rat: LD50 = 220 mg/kg.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild; Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520 ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 = 1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg.
Carcinogenicity:
Diethylene glycol monoethyl ether - Not listed by ACGIH, IARC, or NTP.
Imidazole - Not listed by ACGIH, IARC, or NTP.
Sulfur dioxide - Not listed by ACGIH, IARC, or NTP.
Iodine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Pseudomonas putida:
Fish: Pseudomonas putida:
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: CORROSIVE LIQUIDS, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUIDS, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUIDS, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: III
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 34 Causes burns.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 111-90-0: 1
CAS# 288-32-4: 1
CAS# 7446-09-5: 1
CAS# 7553-56-2: 1
Canada
CAS# 111-90-0 is listed on Canadas DSL List.
CAS# 288-32-4 is listed on Canadas DSL List.
CAS# 7446-09-5 is listed on Canadas DSL List.
CAS# 7553-56-2 is listed on Canadas DSL List.
CAS# 111-90-0 is listed on Canadas Ingredient Disclosure List.
CAS# 288-32-4 is not listed on Canadas Ingredient Disclosure List.
CAS# 7446-09-5 is listed on Canadas Ingredient Disclosure List.
CAS# 7553-56-2 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-90-0 is listed on the TSCA inventory.
CAS# 288-32-4 is listed on the TSCA inventory.
CAS# 7446-09-5 is listed on the TSCA inventory.
CAS# 7553-56-2 is listed on the TSCA inventory.
