Name:
Aqualine Complete 5K
Synonym:
None known
CAS:
111-90-0
Section 1 - Chemical Product
MSDS Name:Aqualine Complete 5K
Synonym:None known
Synonym:None known
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 111-90-0 | Diethylene glycol monoethyl ether | 50-60 | 203-919-7 |
| Hazard Symbols: XN Risk Phrases: 36/38 20 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes and skin. Harmful by inhalation.
Potential Health Effects
Eye:
May cause eye irritation. May cause transient corneal injury.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression. May cause thyroid abnormalities.
May produce aplastic anemia with tremors and marked mental dullness.
May produce blood disturbances with or without neurological signs.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation. May cause kidney damage. May cause edema of lungs or glottis and can produce respiratory paralysis.
Chronic:
May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Chronic exposure can affect thyroid function. May cause kidney damage.
Irritating to eyes and skin. Harmful by inhalation.
Potential Health Effects
Eye:
May cause eye irritation. May cause transient corneal injury.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression. May cause thyroid abnormalities.
May produce aplastic anemia with tremors and marked mental dullness.
May produce blood disturbances with or without neurological signs.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation. May cause kidney damage. May cause edema of lungs or glottis and can produce respiratory paralysis.
Chronic:
May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Chronic exposure can affect thyroid function. May cause kidney damage.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Monitor kidney function closely.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Monitor kidney function closely.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Do not flush into a sewer. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Do not flush into a sewer. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Store protected from light. If peroxide formation is suspected, do not open or move container.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. After opening, purge container with nitrogen before reclosing. Periodically test for peroxide formation on long-term storage. Addition of water or appropriate reducing materials will lessen peroxide formation.
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Store protected from light. If peroxide formation is suspected, do not open or move container.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. After opening, purge container with nitrogen before reclosing. Periodically test for peroxide formation on long-term storage. Addition of water or appropriate reducing materials will lessen peroxide formation.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 111-90-0: Netherlands: 32 ppm MAC; 180 mg/m3 MAC CAS# 5683-33-0: CAS# 7446-09-5: United States OSHA: 5 ppm TWA; 13 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 5 ppm VLE; 10 mg/m3 VLE Germany: 1 ppm TWA (paper production, chemical and pharmaceutical industries); 2.5 mg/m3 Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA Netherlands: 2 ppm MAC; 5 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC CAS# 7553-56-2: United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA Germany: Skin absorber Japan: 0.1 ppm OEL; 1 mg/m3 OEL Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling Russia: 1 mg/m3 TWA Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 111-90-0: Netherlands: 32 ppm MAC; 180 mg/m3 MAC CAS# 5683-33-0: CAS# 7446-09-5: United States OSHA: 5 ppm TWA; 13 mg/m3 TWA Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE France - VME: 2 ppm VME; 5 mg/m3 VME France - VLE: 5 ppm VLE; 10 mg/m3 VLE Germany: 1 ppm TWA (paper production, chemical and pharmaceutical industries); 2.5 mg/m3 Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA Netherlands: 2 ppm MAC; 5 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC CAS# 7553-56-2: United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA Germany: Skin absorber Japan: 0.1 ppm OEL; 1 mg/m3 OEL Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling Russia: 1 mg/m3 TWA Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless
Odor: sweet, fruity odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. Explosive peroxides may form on concentration. Peroxides can be detonated by friction, impact, or heating.
Conditions to Avoid:
Ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, acrolein, aluminum, chlorates, chlorine trifluoride, chromium, acids (mineral, non-oxidizing, e.g.
hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g.
acetaldehyde, acrolein, chloral hydrate, formaldehyde), amides (e.g.
butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates (e.g. carbanolate, carbofuran), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g.
butyl acetate, ethyl acetate, propyl formate), ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)), hydrocarbons (aromatic, e.g.
benzene, chrysene, cumene, toluene), halogenated organics (e.g.
dibromoethane, hexachlorobenzene, methyl chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (e.g. acetone, acetophenone, MEK, MIBK), mercaptans and other organic sulfides (e.g. butyl mercaptan, carbon disulfide, methanethiol), metals (alkali and alkaline, e.g. cesium, potassium, sodium), metals as powders (e.g. hafnium, raney nickel), metals as non-powders (e.g.
brass, bronze, iron), nitrides (e.g. potassium nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl cyanide), nitro compounds (organic, e.g. nitrobenzene, nitroglycerine, picric acid, trinitrotoluene), hydrocarbons (aliphatic, unsaturated, e.g.
cyclopentene, ethylene, heptene), hydrocarbons (aliphatic, saturated, e.g. butane, heptane, isooctane), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), phenols and cresols (e.g. carbolic acid, creosote, cresol, phenol, resorcinol), organophosphates, p.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Stable under normal temperatures and pressures. Explosive peroxides may form on concentration. Peroxides can be detonated by friction, impact, or heating.
Conditions to Avoid:
Ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, acrolein, aluminum, chlorates, chlorine trifluoride, chromium, acids (mineral, non-oxidizing, e.g.
hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g.
acetaldehyde, acrolein, chloral hydrate, formaldehyde), amides (e.g.
butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates (e.g. carbanolate, carbofuran), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g.
butyl acetate, ethyl acetate, propyl formate), ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)), hydrocarbons (aromatic, e.g.
benzene, chrysene, cumene, toluene), halogenated organics (e.g.
dibromoethane, hexachlorobenzene, methyl chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (e.g. acetone, acetophenone, MEK, MIBK), mercaptans and other organic sulfides (e.g. butyl mercaptan, carbon disulfide, methanethiol), metals (alkali and alkaline, e.g. cesium, potassium, sodium), metals as powders (e.g. hafnium, raney nickel), metals as non-powders (e.g.
brass, bronze, iron), nitrides (e.g. potassium nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl cyanide), nitro compounds (organic, e.g. nitrobenzene, nitroglycerine, picric acid, trinitrotoluene), hydrocarbons (aliphatic, unsaturated, e.g.
cyclopentene, ethylene, heptene), hydrocarbons (aliphatic, saturated, e.g. butane, heptane, isooctane), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), phenols and cresols (e.g. carbolic acid, creosote, cresol, phenol, resorcinol), organophosphates, p.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 111-90-0: KK8750000 CAS# 5683-33-0: US9200000 CAS# 7446-09-5: WS4550000 CAS# 7553-56-2: NN1575000 LD50/LC50:
CAS# 111-90-0: Dermal, guinea pig: LD50 = >32 gm/kg; Draize test, rabbit, eye: 500 mg Moderate; Draize test, rabbit, eye: 125 mg Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >5240 mg/m3/4H; Oral, mouse: LD50 = 6600 uL/kg; Oral, mouse: LD50 = 7250 mg/kg; Oral, rabbit: LD50 = 3620 mg/kg; Oral, rat: LD50 = 5500 uL/kg; Oral, rat: LD50 = 7500 mg/kg; Skin, rabbit: LD50 = 4200 uL/kg; Skin, rabbit: LD50 = 8.5 ml/kg/2H; Skin, rat: LD50 = 6 mL/kg.
CAS# 5683-33-0.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild; Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520 ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 = 1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg.
Carcinogenicity:
Diethylene glycol monoethyl ether - Not listed by ACGIH, IARC, or NTP.
N,n-dimethylpyridin-2-amine - Not listed by ACGIH, IARC, or NTP.
Sulfur dioxide - Not listed by ACGIH, IARC, or NTP.
Iodine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 111-90-0: KK8750000 CAS# 5683-33-0: US9200000 CAS# 7446-09-5: WS4550000 CAS# 7553-56-2: NN1575000 LD50/LC50:
CAS# 111-90-0: Dermal, guinea pig: LD50 = >32 gm/kg; Draize test, rabbit, eye: 500 mg Moderate; Draize test, rabbit, eye: 125 mg Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >5240 mg/m3/4H; Oral, mouse: LD50 = 6600 uL/kg; Oral, mouse: LD50 = 7250 mg/kg; Oral, rabbit: LD50 = 3620 mg/kg; Oral, rat: LD50 = 5500 uL/kg; Oral, rat: LD50 = 7500 mg/kg; Skin, rabbit: LD50 = 4200 uL/kg; Skin, rabbit: LD50 = 8.5 ml/kg/2H; Skin, rat: LD50 = 6 mL/kg.
CAS# 5683-33-0.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild; Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520 ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 = 1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14 gm/kg.
Carcinogenicity:
Diethylene glycol monoethyl ether - Not listed by ACGIH, IARC, or NTP.
N,n-dimethylpyridin-2-amine - Not listed by ACGIH, IARC, or NTP.
Sulfur dioxide - Not listed by ACGIH, IARC, or NTP.
Iodine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Cas# 111-90-0: The Koc of diethylene glycol monoethyl ether is estimated as approximately 12, using a measured log Kow of -0.54 and a regression-derived equation. According to a recommended classification scheme, this estimated Koc value suggests that diethylene glycol monoethyl ether has very high mobility in soil.
Cas# 111-90-0: The Koc of diethylene glycol monoethyl ether is estimated as approximately 12, using a measured log Kow of -0.54 and a regression-derived equation. According to a recommended classification scheme, this estimated Koc value suggests that diethylene glycol monoethyl ether has very high mobility in soil.
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Not Regulated
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not Regulated
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not Regulated
Hazard Class:
UN Number:
Packing group:
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20 Harmful by inhalation.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 111-90-0: 1
CAS# 5683-33-0: No information available.
CAS# 7446-09-5: 1
CAS# 7553-56-2: 1
Canada
CAS# 111-90-0 is listed on Canadas DSL List.
CAS# 7446-09-5 is listed on Canadas DSL List.
CAS# 7553-56-2 is listed on Canadas DSL List.
CAS# 111-90-0 is listed on Canadas Ingredient Disclosure List.
CAS# 5683-33-0 is not listed on Canadas Ingredient Disclosure List.
CAS# 7446-09-5 is listed on Canadas Ingredient Disclosure List.
CAS# 7553-56-2 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-90-0 is listed on the TSCA inventory.
CAS# 5683-33-0 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 7446-09-5 is listed on the TSCA inventory.
CAS# 7553-56-2 is listed on the TSCA inventory.
