Name:
Arsenic(iii)bromide 99.9%
Synonym:
CAS:
7784-33-0
Section 1 - Chemical Product
MSDS Name:Arsenic(iii)bromide 99.9%
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7784-33-0 | Arsenic(III)bromide | 99.9% | 232-057-4 |
| Hazard Symbols: T Risk Phrases: 23/25 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation and if swallowed.Moisture sensitive.Light sensitive.Cancer suspect agent.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Poison by ingestion. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage.
The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. The toxicological properties of this substance have not been fully investigated. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Toxic if inhaled.
Chronic:
Not available.
Toxic by inhalation and if swallowed.Moisture sensitive.Light sensitive.Cancer suspect agent.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Poison by ingestion. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage.
The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. The toxicological properties of this substance have not been fully investigated. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Toxic if inhaled.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Provide ventilation.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket.
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7784-33-0: United Kingdom, WEL - TWA: (listed as arsenic): 0.1 mg/m3 TWA United Kingdom, WEL - STEL: (listed as arsenic): 0.3 mg/m3 STEL United States OSHA: 0.5 mg/m3 TWA (listed under Arsenic).5 ??g/m3 Action Level (as As); 10 ??g/m3 PEL (as As. Cancer hazard - see 2 CFR 1 910.1018. Arsine excepted) (listed under Arsenic, inorgani compounds).
Belgium - TWA: (listed as arsenic, inorganic compounds): 0.01 mg/ VLE (as As) Japan: (listed as arsenic): 3 ??g/m3 OEL (reference value) Malaysia: (listed as arsenic, inorganic compounds): 0.01 mg/m3 TW (as As, except arsine) Netherlands: (listed as arsenic, inorganic compounds): 0.1 mg/m3 (as As) Netherlands: (listed as arsenic, inorganic compounds): 0.050 mg/m MAC (as As) Russia: (listed as arsenic, inorganic compounds): 0.04 mg/m3 TWA As) Russia: (listed as arsenic, inorganic compounds): 0.01 mg/m3 STEL As) Spain: (listed as arsenic): 0.1 mg/m3 VLA-ED Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7784-33-0: United Kingdom, WEL - TWA: (listed as arsenic): 0.1 mg/m3 TWA United Kingdom, WEL - STEL: (listed as arsenic): 0.3 mg/m3 STEL United States OSHA: 0.5 mg/m3 TWA (listed under Arsenic).5 ??g/m3 Action Level (as As); 10 ??g/m3 PEL (as As. Cancer hazard - see 2 CFR 1 910.1018. Arsine excepted) (listed under Arsenic, inorgani compounds).
Belgium - TWA: (listed as arsenic, inorganic compounds): 0.01 mg/ VLE (as As) Japan: (listed as arsenic): 3 ??g/m3 OEL (reference value) Malaysia: (listed as arsenic, inorganic compounds): 0.01 mg/m3 TW (as As, except arsine) Netherlands: (listed as arsenic, inorganic compounds): 0.1 mg/m3 (as As) Netherlands: (listed as arsenic, inorganic compounds): 0.050 mg/m MAC (as As) Russia: (listed as arsenic, inorganic compounds): 0.04 mg/m3 TWA As) Russia: (listed as arsenic, inorganic compounds): 0.01 mg/m3 STEL As) Spain: (listed as arsenic): 0.1 mg/m3 VLA-ED Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Lumps
Color: colorless - yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 221 deg C
Freezing/Melting Point: 31 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts with water
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 314.65
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, light, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Water, oxidizing agents, active metals, acids, bases, aluminum, potassium, sodium.
Hazardous Decomposition Products:
Hydrogen bromide, oxides of arsenic.
Hazardous Polymerization: Will not occur.
Not available.
Conditions to Avoid:
Incompatible materials, light, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Water, oxidizing agents, active metals, acids, bases, aluminum, potassium, sodium.
Hazardous Decomposition Products:
Hydrogen bromide, oxides of arsenic.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7784-33-0: CG1375000 LD50/LC50:
Not available.
Carcinogenicity:
Arsenic(III)bromide - California: carcinogen, initial date 2/27/87 (listed as Arsenic, inorg NTP: Known carcinogen (listed as Arsenic, inorganic compounds).
IARC: Group 1 carcinogen (listed as Arsenic).
Other:
See actual entry in RTECS for complete information.
CAS# 7784-33-0: CG1375000 LD50/LC50:
Not available.
Carcinogenicity:
Arsenic(III)bromide - California: carcinogen, initial date 2/27/87 (listed as Arsenic, inorg NTP: Known carcinogen (listed as Arsenic, inorganic compounds).
IARC: Group 1 carcinogen (listed as Arsenic).
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: ARSENIC BROMIDE
Hazard Class: 6.1
UN Number: 1555
Packing Group: II
IMO
Shipping Name: ARSENIC BROMIDE
Hazard Class: 6.1
UN Number: 1555
Packing Group: II
RID/ADR
Shipping Name: ARSENIC BROMIDE
Hazard Class: 6.1
UN Number: 1555
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/25 Toxic by inhalation and if swallowed.
Safety Phrases:
S 20/21 When using do not eat, drink or smoke.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7784-33-0: No information available.
Canada
CAS# 7784-33-0 is listed on Canadas NDSL List.
CAS# 7784-33-0 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7784-33-0 is listed on the TSCA inventory.
