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Name:
Barium chloride dihydrate p.a.
Synonym:
Barium dichloride dihydrat
CAS:
10326-27-9
Section 1 - Chemical Product
MSDS Name:Barium chloride dihydrate p.a.
Synonym:Barium dichloride dihydrat
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
10326-27-9 Barium chloride dihydrate unlisted
Hazard Symbols: T
Risk Phrases: 25 20

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic if swallowed. Harmful by inhalation.
Potential Health Effects
Eye:
Contact produces irritation, tearing, and burning pain. May cause conjunctivitis.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Poison by ingestion. May cause kidney damage. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea. May cause hemorrhaging of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation. May cause effects similar to those described for ingestion.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Section 7 - HANDLING and STORAGE
Handling:
Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10326-27-9: United States OSHA: 0.5 mg/m3 TWA (listed under Barium).
Belgium - TWA: (listed as barium): 0.5 mg/m3 VLE Malaysia: (listed as barium): 0.5 mg/m3 TWA Netherlands: (listed as barium): 0.5 mg/m3 MAC Spain: (listed as barium): 0.5 mg/m3 VLA-ED Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystals
Color: white
Odor: Not available.
pH: 5-8 (5% aq.solution)
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 1560 deg C
Freezing/Melting Point: 962 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >100 deg C
Solubility in water: Soluble.
Specific Gravity/Density: Not available.
Molecular Formula: BaCl2.2H2O
Molecular Weight: 244.28

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, bromine trifluoride, 2-furan + percarboxylic acid.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10326-27-9: CQ8751000 LD50/LC50:
Not available.
Carcinogenicity:
Barium chloride dihydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Barium chloride accumulates in plants when it exceeds calcium and magnesium levels in soil.

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing Group: III
IMO
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing Group: III
RID/ADR
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 20 Harmful by inhalation.
R 25 Toxic if swallowed.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10326-27-9: 1
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10326-27-9 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10326-27-9 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).