Name:
Barium Chloride Solution 10%
Synonym:
Barium dichloride
CAS:
64-02-8
Section 1 - Chemical Product
MSDS Name:Barium Chloride Solution 10%
Synonym:Barium dichloride
Synonym:Barium dichloride
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 64-02-8 | Tetrasodium EDTA | < 0.1 | 200-573-9 |
| Hazard Symbols: XN Risk Phrases: 20/22 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to those described for ingestion.
Chronic:
No information found.
Harmful by inhalation and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to those described for ingestion.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid if cough or other symptoms appear. Get medical aid.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid if cough or other symptoms appear. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Section 7 - HANDLING and STORAGE
Handling:
Wash hands before eating. Use with adequate ventilation. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash hands before eating. Use with adequate ventilation. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: clear, colorless
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 212 deg F
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 1.0
Molecular Formula: Mixture
Molecular Weight: Not available
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Barium chloride is incompatible with bromine trifluoride and 2-furan percarboxylic acid.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine.
Hazardous Polymerization: Has not been reported.
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Barium chloride is incompatible with bromine trifluoride and 2-furan percarboxylic acid.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64-02-8: AH5075000 CAS# 7732-18-5: ZC0110000 CAS# 10326-27-9: CQ8751000 CAS# 10361-37-2: CQ8750000 LD50/LC50:
CAS# 64-02-8: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Moderate.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 10326-27-9.
CAS# 10361-37-2: Oral, rat: LD50 = 118 mg/kg.
Carcinogenicity:
Tetrasodium EDTA - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Water - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Barium chloride dihydrate - ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as ** Barium chloride anhydrous - ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as ** See actual entry in RTECS for complete information.
CAS# 64-02-8: AH5075000 CAS# 7732-18-5: ZC0110000 CAS# 10326-27-9: CQ8751000 CAS# 10361-37-2: CQ8750000 LD50/LC50:
CAS# 64-02-8: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 500 mg/24H Moderate.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 10326-27-9.
CAS# 10361-37-2: Oral, rat: LD50 = 118 mg/kg.
Carcinogenicity:
Tetrasodium EDTA - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Water - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Barium chloride dihydrate - ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as ** Barium chloride anhydrous - ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as ** See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 64-02-8: 2
CAS# 7732-18-5: No information available.
CAS# 10326-27-9: 1
CAS# 10361-37-2: 1
United Kingdom Occupational Exposure Limits
Canada
CAS# 64-02-8 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 10361-37-2 is listed on Canadas DSL List.
CAS# 64-02-8 is not listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
CAS# 10326-27-9 is not listed on Canadas Ingredient Disclosure List.
CAS# 10361-37-2 is listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 10326-27-9: OEL-AUSTRALIA:TWA 0.5 mg(Ba)/m3
OEL-AUSTRIA:TWA 0.5 mg(Ba)/m3
OEL-BELGIUM:TWA 0.5 mg(Ba)/m3
OEL-DENMARK:TWA 0.5 mg(Ba)/m3
OEL-FINLAND:TWA 0.5 mg(Ba)/m3
OEL-GERMANY:TWA 0.5 mg(Ba)/m3 (total dust)
OEL-HUNGARY:STEL 0.5 mg(Ba)/m3
OEL-THE NETHERLANDS:TWA 0.5 mg(Ba)/m3
OEL-THE PHILIPPINES:TWA 0.5 mg(Ba)/m3
OEL-POLAND:TWA 0.5 mg(Ba)/m3;STEL 1.5 mg(Ba)/m3
OEL-SWITZERLAND:TWA 0.5 mg(Ba)/m3;STEL 1 mg(Ba)/m
OEL-TURKEY:TWA 0.5 mg(Ba)/m3
OEL-UNITED KINGDOM:TWA 0.5 mg(Ba)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 10361-37-2: OEL-AUSTRALIA:TWA 0.5 mg(Ba)/m3
OEL-AUSTRIA:TWA 0.5 mg(Ba)/m3
OEL-BELGIUM:TWA 0.5 mg(Ba)/m3
OEL-DENMARK:TWA 0.5 mg(Ba)/m3
OEL-FINLAND:TWA 0.5 mg(Ba)/m3
OEL-GERMANY:TWA 0.5 mg(Ba)/m3 (total dust)
OEL-HUNGARY:STEL 0.5 mg(Ba)/m3
OEL-THE NETHERLANDS:TWA 0.5 mg(Ba)/m3
OEL-THE PHILIPPINES:TWA 0.5 mg(Ba)/m3
OEL-POLAND:TWA 0.5 mg(Ba)/m3;STEL 1.5 mg(Ba)/m3
OEL-RUSSIA:STEL 0.3 mg/m3
OEL-SWITZERLAND:TWA 0.5 mg(Ba)/m3;STEL 1 mg(Ba)/m
OEL-TURKEY:TWA 0.5 mg(Ba)/m3
OEL-UNITED KINGDOM:TWA 0.5 mg(Ba)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 64-02-8 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 10326-27-9 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).
CAS# 10361-37-2 is listed on the TSCA inventory.
