Name:
Barium perchlorate anhydrous 99%
Synonym:
Barium Perchlorat
CAS:
13465-95-7
Section 1 - Chemical Product
MSDS Name:Barium perchlorate anhydrous 99%
Synonym:Barium Perchlorat
Synonym:Barium Perchlorat
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 13465-95-7 | Barium perchlorate | 99.0 | 236-710-4 |
| Hazard Symbols: XN O Risk Phrases: 20/22 9 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Explosive when mixed with combustible material.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause severe eye irritation. May cause conjunctivitis. May cause permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May be harmful if swallowed. May cause burns to the gastrointestinal tract. May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
May cause severe irritation of the respiratory tract with possible burns. May be harmful if inhaled. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
No information found.
Harmful by inhalation and if swallowed. Explosive when mixed with combustible material.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause severe eye irritation. May cause conjunctivitis. May cause permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May be harmful if swallowed. May cause burns to the gastrointestinal tract. May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
May cause severe irritation of the respiratory tract with possible burns. May be harmful if inhaled. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Use water with caution and in flooding amounts.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Contact professional fire-fighters immediately.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Use water with caution and in flooding amounts.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Contact professional fire-fighters immediately.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Remove all sources of ignition.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Remove all sources of ignition.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Keep container tightly closed. Avoid contact with clothing and other combustible materials.
Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store protected from moisture.
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Keep container tightly closed. Avoid contact with clothing and other combustible materials.
Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store protected from moisture.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 13465-95-7: United States OSHA: 0.5 mg/m3 TWA (listed under Barium).
Belgium - TWA: (listed as barium): 0.5 mg/m3 VLE Malaysia: (listed as barium): 0.5 mg/m3 TWA Netherlands: (listed as barium): 0.5 mg/m3 MAC Spain: (listed as barium): 0.5 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 13465-95-7: United States OSHA: 0.5 mg/m3 TWA (listed under Barium).
Belgium - TWA: (listed as barium): 0.5 mg/m3 VLE Malaysia: (listed as barium): 0.5 mg/m3 TWA Netherlands: (listed as barium): 0.5 mg/m3 MAC Spain: (listed as barium): 0.5 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 505 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: 3.2000g/cm3
Molecular Formula: BaCl2O8
Molecular Weight: 336.23
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents, exposure to moist air or water.
Incompatibilities with Other Materials:
Reducing agents, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, barium oxide.
Hazardous Polymerization: Has not been reported
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents, exposure to moist air or water.
Incompatibilities with Other Materials:
Reducing agents, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, barium oxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13465-95-7: SC7550000 LD50/LC50:
Not available.
Carcinogenicity:
Barium perchlorate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 13465-95-7: SC7550000 LD50/LC50:
Not available.
Carcinogenicity:
Barium perchlorate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: BARIUM PERCHLORATE
Hazard Class: 5.1 (6.1)
UN Number: 1447
Packing Group: II
IMO
Shipping Name: BARIUM PERCHLORATE, SOLID
Hazard Class: 5.1 (6.1)
UN Number: 1447
Packing Group: II
RID/ADR
Shipping Name: BARIUM PERCHLORATE
Hazard Class: 5.1
UN Number: 1447
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 9 Explosive when mixed with combustible material.
Safety Phrases:
S 27 Take off immediately all contaminated clothing.
WGK (Water Danger/Protection)
CAS# 13465-95-7: 1
Canada
CAS# 13465-95-7 is listed on Canadas DSL List.
CAS# 13465-95-7 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13465-95-7 is listed on the TSCA inventory.
