Name:
Benzalkonium chloride alkyl distribution from C8H17 to C16H33
Synonym:
Ammonium, alkyldimethylbenzyl-, chloride; Alkyl dimethylbenzyl ammonium chloride; Alkyldimethyl(phenylmethyl)quaternary ammonium chlorides; Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides; Zephiran chlorid
CAS:
7732-18-5
Section 1 - Chemical Product
MSDS Name:Benzalkonium chloride alkyl distribution from C8H17 to C16H33
Synonym:Ammonium, alkyldimethylbenzyl-, chloride; Alkyl dimethylbenzyl ammonium chloride; Alkyldimethyl(phenylmethyl)quaternary ammonium chlorides; Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides; Zephiran chlorid
Synonym:Ammonium, alkyldimethylbenzyl-, chloride; Alkyl dimethylbenzyl ammonium chloride; Alkyldimethyl(phenylmethyl)quaternary ammonium chlorides; Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides; Zephiran chlorid
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7732-18-5 | Water | Balance | 231-791-2 |
| Hazard Symbols: C Risk Phrases: 21/22 34 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Causes burns.Hygroscopic (absorbs moisture from the air).Corrosive.
Potential Health Effects
Eye:
Causes severe eye irritation and burns.
Skin:
Causes severe skin irritation and burns. Exposure may cause skin lesions with cutaneous necrosis and scarring.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause central nervous system depression. Ingestion may produce burning pains in the mouth, throat and abdomen, profuse salivation, muscle weakness, labored breathing, circulatory shock, and possible cardiovascular collapse.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Causes irritation of the mucous membrane.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Repeated or prolonged exposure may cause allergic reactions in sensitive individuals. May cause cyanosis - a blue-gray coloring of the skin and lips caused by a lack of oxygen.
Harmful in contact with skin and if swallowed. Causes burns.Hygroscopic (absorbs moisture from the air).Corrosive.
Potential Health Effects
Eye:
Causes severe eye irritation and burns.
Skin:
Causes severe skin irritation and burns. Exposure may cause skin lesions with cutaneous necrosis and scarring.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause central nervous system depression. Ingestion may produce burning pains in the mouth, throat and abdomen, profuse salivation, muscle weakness, labored breathing, circulatory shock, and possible cardiovascular collapse.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Causes irritation of the mucous membrane.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. Repeated or prolonged exposure may cause allergic reactions in sensitive individuals. May cause cyanosis - a blue-gray coloring of the skin and lips caused by a lack of oxygen.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
If cyanosis is severe, intravenous injection of Methylene Blue, 1mg/kg of body weight may be of value. Treat symptomatically and supportively.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
If cyanosis is severe, intravenous injection of Methylene Blue, 1mg/kg of body weight may be of value. Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode in the heat of a fire.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use extinguishing media most appropriate for the surrounding fire. Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode in the heat of a fire.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use extinguishing media most appropriate for the surrounding fire. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale.
Discard contaminated shoes.
Storage:
Keep from freezing. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store protected from moisture. Store below 40C.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale.
Discard contaminated shoes.
Storage:
Keep from freezing. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store protected from moisture. Store below 40C.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7732-18-5: CAS# 8001-54-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7732-18-5: CAS# 8001-54-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: clear colorless to faint yellow
Odor: aromatic odor
pH: alkaline in soln.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 250 deg C ( 482.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >140 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 0.9800
Molecular Formula: Not applicable.
Molecular Weight:
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, nitrates, moisture, anion detergents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen, ammonia.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, nitrates, moisture, anion detergents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen, ammonia.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7732-18-5: ZC0110000 CAS# 8001-54-5: BO3150000 LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 8001-54-5: Draize test, rabbit, eye: 100 ug; Draize test, rabbit, eye: 1 mg/24H Severe; Draize test, rabbit, eye: 10 mg Mild; Draize test, rabbit, skin: 50 mg/24H Moderate; Oral, rat: LD50 = 240 mg/kg.
Carcinogenicity:
Water - Not listed by ACGIH, IARC, or NTP.
Benzalkonium chloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7732-18-5: ZC0110000 CAS# 8001-54-5: BO3150000 LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 8001-54-5: Draize test, rabbit, eye: 100 ug; Draize test, rabbit, eye: 1 mg/24H Severe; Draize test, rabbit, eye: 10 mg Mild; Draize test, rabbit, skin: 50 mg/24H Moderate; Oral, rat: LD50 = 240 mg/kg.
Carcinogenicity:
Water - Not listed by ACGIH, IARC, or NTP.
Benzalkonium chloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 0.6 mg/L; 15 min; Microtox test at 15CFish: Striped bass: LC50 = 0.5 mg/L; 24-96 Hr; (larvae) Static bioassayFish: Striped bass: LC50 = 1.5 mg/L; 24-96 Hr; (fingerling) Static bioassay
Bacteria: Phytobacterium phosphoreum: EC50 = 0.6 mg/L; 15 min; Microtox test at 15CFish: Striped bass: LC50 = 0.5 mg/L; 24-96 Hr; (larvae) Static bioassayFish: Striped bass: LC50 = 1.5 mg/L; 24-96 Hr; (fingerling) Static bioassay
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28B After contact with skin, wash immediately with
plenty of water and soap.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 8001-54-5: 3
Canada
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 8001-54-5 is listed on Canadas DSL List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
CAS# 8001-54-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 8001-54-5 is not listed on the TSCA inventory.
It is for research and development use only.
