MSDS Name:Borane-methyl sulfide complex 2m solution in thf
Synonym:BMS; Dimethyl sulfideboran

EMERGENCY OVERVIEW
Highly flammable. Contact with water liberates extremely flammable gases. Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.Moisture sensitive.
Potential Health Effects
Eye:
Causes severe eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. May cause headache.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Reacts violently with water giving off flammable gas which may explode. Will burn if involved in a fire.
Extinguishing Media:
Use carbon dioxide or dry chemical. DO NOT USE WATER!

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition.

Handling:
Wash thoroughly after handling. Wash hands before eating. Use only in a well-ventilated area. Do not allow water to get into the container because of violent reaction. emsdss may develop pressure upon prolonged storage. Avoid breathing dust, vapor, mist, or gas.
Keep away from heat, sparks and flame. Do not get on skin or in eyes.
Do not ingest or inhale.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Refrigerator/flammables.

Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Exposure Limits CAS# 13292-87-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Physical State: Liquid
Color: clear, colorless
Odor: Stench; odor like rotting eggs.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -17 deg C ( 1.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .8550g/cm3
Molecular Formula: C2H9BS
Molecular Weight: 75.95

Chemical Stability:
Unstable.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition sources, contact with water, exposure to moist air or water.
Incompatibilities with Other Materials:
Acids, acid chlorides, acid anhydrides, oxidizing agents, alcohols, and water.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide, oxides of boron, borane.
Hazardous Polymerization: Has not been reported.

RTECS#:
CAS# 13292-87-0: PV5080000 LD50/LC50:
CAS# 13292-87-0: Draize test, rabbit, eye: 100 mg Severe.
Carcinogenicity:
Borane-methyl sulfide complex, 2M solution in tetrahydrofura - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Dispose of in a manner consistent with federal, state, and local regulations.

IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 15 Contact with water liberates extremely
flammable gases.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 13292-87-0: No information available.
Canada
CAS# 13292-87-0 is listed on Canadas NDSL List.
CAS# 13292-87-0 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13292-87-0 is listed on the TSCA inventory.