Name:
Bromoethane
Synonym:
Ethyl bromide; bromic ether; monobromoethane; hydrobromic ether
CAS:
74-96-4
Section 1 - Chemical Product
MSDS Name:Bromoethane
Synonym:Ethyl bromide; bromic ether; monobromoethane; hydrobromic ether
Synonym:Ethyl bromide; bromic ether; monobromoethane; hydrobromic ether
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 74-96-4 | Ethyl bromide | 100 % | 200-825-8 |
| Hazard Symbols: XN F Risk Phrases: 11 20/22 40 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation and if swallowed. Limited evidence of a carcinogenic effect.Water-reactive.Carcinogen.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Exposure may cause irritation characterized by redness, dryness, and inflammation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause respiratory failure. May cause systemic toxic effects on the heart, liver, and kidneys.
Inhalation:
Causes respiratory tract irritation. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause effects similar to those described for ingestion. Causes narcotic effects including headache, dizziness, weakness, unconsciousness, and possible death.
Chronic:
Prolonged or repeated skin contact may cause irritation. Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. May cause cancer in humans.
Highly flammable. Harmful by inhalation and if swallowed. Limited evidence of a carcinogenic effect.Water-reactive.Carcinogen.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Exposure may cause irritation characterized by redness, dryness, and inflammation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause respiratory failure. May cause systemic toxic effects on the heart, liver, and kidneys.
Inhalation:
Causes respiratory tract irritation. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause effects similar to those described for ingestion. Causes narcotic effects including headache, dizziness, weakness, unconsciousness, and possible death.
Chronic:
Prolonged or repeated skin contact may cause irritation. Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. May cause cancer in humans.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use carbon dioxide or dry chemical. DO NOT USE WATER!
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use carbon dioxide or dry chemical. DO NOT USE WATER!
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Scoop up with a nonsparking tool, then place into a suitable container for disposal.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Scoop up with a nonsparking tool, then place into a suitable container for disposal.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Keep away from water.
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Do not ingest or inhale.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Keep away from water.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Exposure Limits CAS# 74-96-4: United States OSHA: 200 ppm TWA; 890 mg/m3 TWA Belgium - TWA: 5 ppm VLE; 22 mg/m3 VLE France - VME: 200 ppm VME; 890 mg/m3 VME Malaysia: 5 ppm TWA; 22 mg/m3 TWA Netherlands: 5 ppm MAC; 22 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 5 ppm VLA-ED; 23 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
Exposure Limits CAS# 74-96-4: United States OSHA: 200 ppm TWA; 890 mg/m3 TWA Belgium - TWA: 5 ppm VLE; 22 mg/m3 VLE France - VME: 200 ppm VME; 890 mg/m3 VME Malaysia: 5 ppm TWA; 22 mg/m3 TWA Netherlands: 5 ppm MAC; 22 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 5 ppm VLA-ED; 23 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless
Odor: Perceptible odor @ 200 ppm.
pH: Not available.
Vapor Pressure: 400 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: 38.4 deg C
Freezing/Melting Point: -119 deg C
Autoignition Temperature: 952 deg F ( 511.11 deg C)
Flash Point: -4 deg F ( -20.00 deg C)
Explosion Limits, lower: 6.7
Explosion Limits, upper: 11.3
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: 1.45
Molecular Formula: C2H5Br
Molecular Weight: 108.939
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong bases, strong oxidizers, magnesium, and water.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong bases, strong oxidizers, magnesium, and water.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 74-96-4: KH6475000 LD50/LC50:
CAS# 74-96-4: Inhalation, mouse: LC50 = 16230 ppm/1H; Inhalation, mouse: LC50 = 36000 mg/m3/2H; Inhalation, rat: LC50 = 26980 ppm/1H; Inhalation, rat: LC50 = 534000 mg/m3/4H; Oral, rat: LD50 = 1350 mg/kg.
Carcinogenicity:
Ethyl bromide - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 12/22/00 Other:
See actual entry in RTECS for complete information.
CAS# 74-96-4: KH6475000 LD50/LC50:
CAS# 74-96-4: Inhalation, mouse: LC50 = 16230 ppm/1H; Inhalation, mouse: LC50 = 36000 mg/m3/2H; Inhalation, rat: LC50 = 26980 ppm/1H; Inhalation, rat: LC50 = 534000 mg/m3/4H; Oral, rat: LD50 = 1350 mg/kg.
Carcinogenicity:
Ethyl bromide - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 12/22/00 Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: ETHYL BROMIDE
Hazard Class: 6.1
UN Number: 1891
Packing Group: II
IMO
Shipping Name: ETHYL BROMIDE
Hazard Class: 6.1
UN Number: 1891
Packing Group: II
RID/ADR
Shipping Name: ETHYL BROMIDE
Hazard Class: 6.1
UN Number: 1891
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 74-96-4: 2
Canada
CAS# 74-96-4 is listed on Canadas DSL List.
CAS# 74-96-4 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 74-96-4 is listed on the TSCA inventory.
