Name:
Butyl acetate Electronic use grade residue free
Synonym:
CAS:
123-86-4
Section 1 - Chemical Product
MSDS Name:Butyl acetate Electronic use grade residue free
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 123-86-4 | Butyl acetate | 204-658-1 |
| Hazard Symbols: None Listed. Risk Phrases: 10 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable.
Potential Health Effects
Eye:
Causes severe eye irritation. Causes redness and pain.
Skin:
Prolonged and/or repeated contact may cause defatting of the skin and dermatitis.
Ingestion:
May cause central nervous system depression. May cause severe irritation of the mouth and throat.
Inhalation:
Causes respiratory tract irritation. May cause narcotic effects in high concentration.
Chronic:
Not available.
Flammable.
Potential Health Effects
Eye:
Causes severe eye irritation. Causes redness and pain.
Skin:
Prolonged and/or repeated contact may cause defatting of the skin and dermatitis.
Ingestion:
May cause central nervous system depression. May cause severe irritation of the mouth and throat.
Inhalation:
Causes respiratory tract irritation. May cause narcotic effects in high concentration.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Containers may explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Containers may explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
Section 7 - HANDLING and STORAGE
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Appearance: APHA: 15 max
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: 0.69 mPas 25 deg C
Boiling Point: 127 deg C @760 mmHg
Freezing/Melting Point: -77.9 deg C
Autoignition Temperature: 370 deg C ( 698.00 deg F)
Flash Point: 22 deg C ( 71.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C6H12O2
Molecular Weight: 116.0828
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong bases, nitrates, potassium-tert-butoxide.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong bases, nitrates, potassium-tert-butoxide.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 123-86-4: AF7350000 LD50/LC50:
CAS# 123-86-4: Draize test, rabbit, eye: 100 mg Moderate; Draize test, rabbit, skin: 500 mg/24H Moderate; Inhalation, mouse: LC50 = 6 gm/m3/2H; Inhalation, rat: LC50 = 390 ppm/4H; Oral, mouse: LD50 = 6 gm/kg; Oral, rabbit: LD50 = 3200 mg/kg; Oral, rat: LD50 = 10768 mg/kg; Skin, rabbit: LD50 = >17600 mg/kg.
Carcinogenicity:
Butyl acetate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
CAS# 123-86-4: AF7350000 LD50/LC50:
CAS# 123-86-4: Draize test, rabbit, eye: 100 mg Moderate; Draize test, rabbit, skin: 500 mg/24H Moderate; Inhalation, mouse: LC50 = 6 gm/m3/2H; Inhalation, rat: LC50 = 390 ppm/4H; Oral, mouse: LD50 = 6 gm/kg; Oral, rabbit: LD50 = 3200 mg/kg; Oral, rat: LD50 = 10768 mg/kg; Skin, rabbit: LD50 = >17600 mg/kg.
Carcinogenicity:
Butyl acetate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 123-86-4: 1
United Kingdom Occupational Exposure Limits
CAS# 123-86-4: OES-United Kingdom, TWA 150 ppm TWA; 724 mg/m3 TWA
CAS# 123-86-4: OES-United Kingdom, STEL 200 ppm STEL; 966 mg/m3 STEL
Canada
CAS# 123-86-4 is listed on Canadas DSL List.
CAS# 123-86-4 is listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 123-86-4: OEL-AUSTRALIA:TWA 150 ppm (710 mg/m3);STEL 200 ppm (950
mg/m3)
OEL-AUSTRIA:TWA 200 ppm (950 mg/m3)
OEL-BELGIUM:TWA 150 ppm (713 mg/m3);STEL 200 ppm (950 mg/m3)
OEL-CZECHOSLOVAKIA:TWA 400 mg/m3;STEL 1000 mg/m3
OEL-DENMARK:TWA 150 ppm (710 mg/m3)
OEL-FINLAND:TWA 150 ppm (710 mg/m3);STEL 200 ppm (950 mg/m3)
OEL-FRANCE:TWA 150 ppm (710 mg/m3);STEL 200 ppm (940 mg/m3)
OEL-GERMANY:TWA 200 ppm (950 mg/m3)
OEL-HUNGARY:TWA 200 mg/m3;STEL 600 mg/m3
OEL-INDIA:TWA 150 ppm (710 mg/m3);STEL 200 ppm (950 mg/m3)
OEL-JAPAN:TWA 200 ppm (950 mg/m3)
OEL-THE NETHERLANDS:TWA 150 ppm (710 mg/m3)
OEL-THE PHILIPPINES:TWA 150 ppm (710 mg/m3)
OEL-POLAND:TWA 200 mg/m3
OEL-RUSSIA:TWA 200 ppm;STEL 200 mg/m3
OEL-SWEDEN:TWA 100 ppm (500 mg/m3);STEL 150 ppm (700 mg/m3)
OEL-SWITZERLAND:TWA 150 ppm (700 mg/m3);STEL 300 ppm
OEL-TURKEY:TWA 150 ppm (710 mg/m3)
OEL-UNITED KINGDOM:TWA 150 ppm (710 mg/m3);STEL 200 ppm
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 123-86-4 is listed on the TSCA inventory.
