Name:
Chlorine Water
Synonym:
Non
CAS:
7732-18-5
Section 1 - Chemical Product
MSDS Name:Chlorine Water
Synonym:Non
Synonym:Non
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 7732-18-5 | Water | 99.2-99. | 231-791-2 |
| Hazard Symbols: C Risk Phrases: 34 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause irreversible eye injury. May cause painful sensitization to light. May cause conjunctivitis.
Skin:
Causes skin burns. May cause photosensitive skin reactions in certain individuals.
Ingestion:
May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.
Inhalation:
Harmful if inhaled. Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma.
May cause pulmonary edema and severe respiratory disturbances.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth.
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause irreversible eye injury. May cause painful sensitization to light. May cause conjunctivitis.
Skin:
Causes skin burns. May cause photosensitive skin reactions in certain individuals.
Ingestion:
May cause circulatory system failure. Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.
Inhalation:
Harmful if inhaled. Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma.
May cause pulmonary edema and severe respiratory disturbances.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated exposure may cause erosion of teeth.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure. Remove contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Antidote: None reported.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure. Remove contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Antidote: None reported.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as sawdust. Provide ventilation.
Spills/Leaks:
Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as sawdust. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Keep away from heat and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Keep away from heat and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 7732-18-5: CAS# 7782-50-5: United Kingdom, WEL - TWA: 0.5 ppm TWA; 1.5 mg/m3 TWA United Kingdom, WEL - STEL: 1 ppm STEL; 2.9 mg/m3 STEL United States OSHA: ; 1 ppm Ceiling; 3 mg/m3 Ceiling Belgium - TWA: 0.5 ppm VLE; 1.5 mg/m3 VLE Belgium - STEL: 1 ppm VLE; 2.9 mg/m3 VLE France - VLE: 1 ppm VLE; 3 mg/m3 VLE Germany: 0.5 ppm TWA; 1.5 mg/m3 TWA Japan: 0.5 ppm Ceiling; 1.5 mg/m3 Ceiling Malaysia: 0.5 ppm TWA; 1.5 mg/m3 TWA Russia: 1 mg/m3 TWA Spain: 0.5 ppm VLA-ED; 1.5 mg/m3 VLA-ED Spain: 1 ppm VLA-EC; 3 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 7732-18-5: CAS# 7782-50-5: United Kingdom, WEL - TWA: 0.5 ppm TWA; 1.5 mg/m3 TWA United Kingdom, WEL - STEL: 1 ppm STEL; 2.9 mg/m3 STEL United States OSHA: ; 1 ppm Ceiling; 3 mg/m3 Ceiling Belgium - TWA: 0.5 ppm VLE; 1.5 mg/m3 VLE Belgium - STEL: 1 ppm VLE; 2.9 mg/m3 VLE France - VLE: 1 ppm VLE; 3 mg/m3 VLE Germany: 0.5 ppm TWA; 1.5 mg/m3 TWA Japan: 0.5 ppm Ceiling; 1.5 mg/m3 Ceiling Malaysia: 0.5 ppm TWA; 1.5 mg/m3 TWA Russia: 1 mg/m3 TWA Spain: 0.5 ppm VLA-ED; 1.5 mg/m3 VLA-ED Spain: 1 ppm VLA-EC; 3 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: pale-yellow
Odor: chlorine-like
pH: 1.734
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Decomposes.
Freezing/Melting Point: 32 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 1.02
Molecular Formula:
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, combustible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, active metals, ammonia, organic matter.
Hazardous Decomposition Products:
Hydrogen chloride, hydrogen gas.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, combustible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, active metals, ammonia, organic matter.
Hazardous Decomposition Products:
Hydrogen chloride, hydrogen gas.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7732-18-5: ZC0110000 CAS# 7782-50-5: FO2100000 LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 7782-50-5: Inhalation, mouse: LC50 = 137 ppm/1H; Inhalation, mouse: LC50 = 368 mg/m3/30M; Inhalation, rat: LC50 = 293 ppm/1H.
Carcinogenicity:
Water - Not listed by ACGIH, IARC, or NTP.
Chlorine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 7732-18-5: ZC0110000 CAS# 7782-50-5: FO2100000 LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 7782-50-5: Inhalation, mouse: LC50 = 137 ppm/1H; Inhalation, mouse: LC50 = 368 mg/m3/30M; Inhalation, rat: LC50 = 293 ppm/1H.
Carcinogenicity:
Water - Not listed by ACGIH, IARC, or NTP.
Chlorine - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 7782-50-5: 10 lb final RQ; 4.54 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 7782-50-5: 2
Canada
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 7782-50-5 is listed on Canadas DSL List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
CAS# 7782-50-5 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 7782-50-5 is listed on the TSCA inventory.
