MSDS Name:Chloroform-d stabilized with silver foil 99.8 atom% D
Synonym:

EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin. Limited evidence of a carcinogenic effect. Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed.Light sensitive.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Vapors may cause eye irritation. Contact produces irritation, tearing, and burning pain. May cause conjunctivitis. Causes redness and pain.
Skin:
Prolonged and/or repeated contact may cause irritation and/or dermatitis. May cause severe skin irritation with possible burns, especially if skin is wet or moist. Causes redness and pain.
Ingestion:
Harmful if swallowed. May cause central nervous system depression, kidney damage, and liver damage. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause cardiac disturbances.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause liver and kidney damage. May cause cardiac sensitization and possible failure.
May cause narcotic effects in high concentration.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated exposure may cause adverse reproductive effects. May cause liver and kidney damage.

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:

General Information:
Use extinguishing media appropriate to the surrounding fire.
Substance is noncombustible.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store under an inert atmosphere.

Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 865-49-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 60.8 deg C @ 760.00mm Hg
Freezing/Melting Point: -64 deg C
Autoignition Temperature: 982 deg C ( 1,799.60 deg F)
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 8.2 G/L (20C)
Specific Gravity/Density: 1.5000
Molecular Formula: CDCl3
Molecular Weight: 120.39

Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
High temperatures, incompatible materials, light, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents, bases, alcohols, aluminum, fluorine, magnesium, sodium hydroxide, potassium, lithium, methyl alcohol, sodium, caustics (e.g. ammonia, ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium hydroxide), ketones (e.g.
acetone, acetophenone, MEK, MIBK), acetone, dinitrogen tetraoxide, potassium hydroxide, perchloric acid, potassium-tert-butoxide, phosphorus pentoxide, sodium potassium alloys, calcium hydroxide.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, chlorine, phosgene gas.
Hazardous Polymerization: Will not occur.

RTECS#:
CAS# 865-49-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Chloroform-d - Not listed by ACGIH, IARC, or NTP.

Ecotoxicity:
Toxic to Daphnia: >1000 mg/l Fish-toxicity: 162 mg/l

Dispose of in a manner consistent with federal, state, and local regulations.

IATA
Shipping Name: CHLOROFORM
Hazard Class: 6.1
UN Number: 1888
Packing Group: III
IMO
Shipping Name: CHLOROFORM
Hazard Class: 6.1
UN Number: 1888
Packing Group: III
RID/ADR
No information available.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
R 40 Limited evidence of a carcinogenic effect.
R 48/20/22 Harmful : danger of serious damage to
health by prolonged exposure through inhalation and if
swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 865-49-6: No information available.
Canada
CAS# 865-49-6 is listed on Canadas DSL List.
CAS# 865-49-6 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 865-49-6 is not listed on the TSCA inventory.
It is for research and development use only.