Name:
Cobalt(iii) fluoride 99%
Synonym:
None
CAS:
10026-18-3
Section 1 - Chemical Product
MSDS Name:Cobalt(iii) fluoride 99%
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 10026-18-3 | Cobalt(III)fluoride | 99.0 | 233-062-4 |
| Hazard Symbols: O C Risk Phrases: 20/21/22 34 8 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Causes burns. Contact with combustible material may cause fire.Moisture sensitive.Air sensitive.Corrosive.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.
Harmful by inhalation, in contact with skin and if swallowed. Causes burns. Contact with combustible material may cause fire.Moisture sensitive.Air sensitive.Corrosive.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Antidote: None reported.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Antidote: None reported.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Contact professional fire-fighters immediately.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Contact professional fire-fighters immediately.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. In case of spill, sweep up solid or absorb liquid with inert material, then place into a biohazard container. Wear protective equipment.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. In case of spill, sweep up solid or absorb liquid with inert material, then place into a biohazard container. Wear protective equipment.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
Wash thoroughly after handling. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10026-18-3: United Kingdom, WEL - TWA: (listed as cobalt compounds): 0.1 mg/m TWA (as Co) United Kingdom, WEL - STEL: (listed as cobalt compounds): 0.3 mg/ STEL (as Co) Japan: (listed as cobalt compounds): 0.05 mg/m3 OEL (as Co) Malaysia: (listed as cobalt, inorganic compounds): 0.02 mg/m3 TWA Co) Spain: (listed as cobalt, inorganic compounds): 0.02 mg/m3 VLA-ED Co) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10026-18-3: United Kingdom, WEL - TWA: (listed as cobalt compounds): 0.1 mg/m TWA (as Co) United Kingdom, WEL - STEL: (listed as cobalt compounds): 0.3 mg/ STEL (as Co) Japan: (listed as cobalt compounds): 0.05 mg/m3 OEL (as Co) Malaysia: (listed as cobalt, inorganic compounds): 0.02 mg/m3 TWA Co) Spain: (listed as cobalt, inorganic compounds): 0.02 mg/m3 VLA-ED Co) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: light brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: CoF3
Molecular Weight: 115.93
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable. May discolor on exposure to light. May discolor on exposure to air.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents.
Incompatibilities with Other Materials:
Reducing agents, acids, moisture, water, air, organic materials, hydrocarbons.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen fluoride gas, fluorine.
Hazardous Polymerization: Will not occur.
Stable. May discolor on exposure to light. May discolor on exposure to air.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents.
Incompatibilities with Other Materials:
Reducing agents, acids, moisture, water, air, organic materials, hydrocarbons.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen fluoride gas, fluorine.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10026-18-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Cobalt(III)fluoride - Not listed by ACGIH, IARC, or NTP.
CAS# 10026-18-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Cobalt(III)fluoride - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 34 Causes burns.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 25 Avoid contact with eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10026-18-3: No information available.
Canada
CAS# 10026-18-3 is listed on Canadas NDSL List.
CAS# 10026-18-3 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10026-18-3 is listed on the TSCA inventory.
