Name:
Collodion
Synonym:
Nitrocellulose; Cellulose nitrate; Guncotton; Nitrocotton; Pyroxyli
CAS:
60-29-7
Section 1 - Chemical Product
MSDS Name:Collodion
Synonym:Nitrocellulose; Cellulose nitrate; Guncotton; Nitrocotton; Pyroxyli
Synonym:Nitrocellulose; Cellulose nitrate; Guncotton; Nitrocotton; Pyroxyli
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 60-29-7 | Ethyl ether | 60-70 | 200-467-2 |
| Hazard Symbols: F+ Risk Phrases: 12 18 19 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Extremely flammable. In use, may form flammable/explosive vapour-air mixture. May form explosive peroxides.Hygroscopic (absorbs moisture from the air).Air sensitive.Light sensitive.
Potential Health Effects
Eye:
Causes moderate eye irritation. May cause painful sensitization to light. Causes redness and pain.
Skin:
May be harmful if absorbed through the skin. Causes severe skin irritation and possible burns.
Ingestion:
Aspiration hazard. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. May be harmful if swallowed.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Vapors may cause dizziness or suffocation. May be absorbed through the lungs. Causes irritation of the mucous membrane and upper respiratory tract. Inhalation may cause irritation of the nose and throat, vomiting, irregular respiration, dizziness, drowsiness, unconsciousness and possible death due to respiratory paralysis.
Chronic:
Prolonged or repeated skin contact may cause defatting and dermatitis. Prolonged or repeated exposure can cause psychic abnormalities such as anxiety, depression and excitability. May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. May cause kidney damage. Prolonged exposure to high vapor concentrations may cause eye injury.
Extremely flammable. In use, may form flammable/explosive vapour-air mixture. May form explosive peroxides.Hygroscopic (absorbs moisture from the air).Air sensitive.Light sensitive.
Potential Health Effects
Eye:
Causes moderate eye irritation. May cause painful sensitization to light. Causes redness and pain.
Skin:
May be harmful if absorbed through the skin. Causes severe skin irritation and possible burns.
Ingestion:
Aspiration hazard. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause systemic toxicity with acidosis. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. May be harmful if swallowed.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Vapors may cause dizziness or suffocation. May be absorbed through the lungs. Causes irritation of the mucous membrane and upper respiratory tract. Inhalation may cause irritation of the nose and throat, vomiting, irregular respiration, dizziness, drowsiness, unconsciousness and possible death due to respiratory paralysis.
Chronic:
Prolonged or repeated skin contact may cause defatting and dermatitis. Prolonged or repeated exposure can cause psychic abnormalities such as anxiety, depression and excitability. May cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. May cause kidney damage. Prolonged exposure to high vapor concentrations may cause eye injury.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Possible aspiration hazard. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Persons with kidney disease, chronic respiratory disease, liver disease, or skin disease may be at increased risk from exposure to this substance. Alcoholic beverage consumption may enhance the toxic effects of this substance. Treat symptomatically and supportively.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Possible aspiration hazard. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Persons with kidney disease, chronic respiratory disease, liver disease, or skin disease may be at increased risk from exposure to this substance. Alcoholic beverage consumption may enhance the toxic effects of this substance. Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Extremely flammable. Material will readily ignite at room temperature. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Containers may explode in the heat of a fire.
May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Will be easily ignited by heat, sparks or flame. Containers may explode when heated. May re-ignite after fire is extinguished.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Extremely flammable. Material will readily ignite at room temperature. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Containers may explode in the heat of a fire.
May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Will be easily ignited by heat, sparks or flame. Containers may explode when heated. May re-ignite after fire is extinguished.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. Cool containers with flooding quantities of water until well after fire is out.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Remove all sources of ignition. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as sawdust. Use a spark-proof tool.
Isolate area and deny entry. Provide ventilation. Place under an inert atmosphere. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Remove all sources of ignition. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Do not use combustible materials such as sawdust. Use a spark-proof tool.
Isolate area and deny entry. Provide ventilation. Place under an inert atmosphere. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Ground and bond containers when transferring material. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Keep container tightly closed. Do not ingest or inhale.
Store protected from light. Handle under an inert atmosphere. Store protected from air. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Unused chemicals should not be returned to the container. Do not distill since this removes peroxide-inhibitors.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Do not store near combustible materials. Do not store in direct sunlight. Store in a tightly closed container. Keep container closed to prevent drying out. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Keep refrigerated. (Store below 4C/39F.) Regularly check inhibitor levels to maintain peroxide levels below 1%. Do not expose to air.
Store protected from moisture. Store protected from light. Store under an inert atmosphere. Long-term storage is not recommended.
Keep away from oxidizing agents.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Ground and bond containers when transferring material. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Keep container tightly closed. Do not ingest or inhale.
Store protected from light. Handle under an inert atmosphere. Store protected from air. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Unused chemicals should not be returned to the container. Do not distill since this removes peroxide-inhibitors.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Do not store near combustible materials. Do not store in direct sunlight. Store in a tightly closed container. Keep container closed to prevent drying out. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Keep refrigerated. (Store below 4C/39F.) Regularly check inhibitor levels to maintain peroxide levels below 1%. Do not expose to air.
Store protected from moisture. Store protected from light. Store under an inert atmosphere. Long-term storage is not recommended.
Keep away from oxidizing agents.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 60-29-7: United Kingdom, WEL - TWA: 100 ppm TWA; 310 mg/m3 TWA United Kingdom, WEL - STEL: 200 ppm STEL; 620 mg/m3 STEL United States OSHA: 400 ppm TWA; 1200 mg/m3 TWA Belgium - TWA: 100 ppm VLE; 308 mg/m3 VLE Belgium - STEL: 200 ppm VLE; 616 mg/m3 VLE France - VME: 400 ppm VME; 1200 mg/m3 VME France - VLE: 500 ppm VLE; 1500 mg/m3 VLE Germany: 400 ppm TWA; 1200 mg/m3 TWA Japan: 400 ppm OEL; 1200 mg/m3 OEL Malaysia: 400 ppm TWA; 1210 mg/m3 TWA Netherlands: 200 ppm STEL; 616 mg/m3 STEL Netherlands: 100 ppm MAC; 308 mg/m3 MAC Russia: 300 mg/m3 TWA Spain: 100 ppm VLA-ED; 308 mg/m3 VLA-ED Spain: 200 ppm VLA-EC; 616 mg/m3 VLA-EC CAS# 64-17-5: United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE France - VME: 1000 ppm VME; 1900 mg/m3 VME France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE Germany: 500 ppm TWA; 960 mg/m3 TWA Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA Netherlands: 500 ppm MAC; 1000 mg/m3 MAC Russia: 1000 mg/m3 TWA Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED CAS# 9004-70-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 60-29-7: United Kingdom, WEL - TWA: 100 ppm TWA; 310 mg/m3 TWA United Kingdom, WEL - STEL: 200 ppm STEL; 620 mg/m3 STEL United States OSHA: 400 ppm TWA; 1200 mg/m3 TWA Belgium - TWA: 100 ppm VLE; 308 mg/m3 VLE Belgium - STEL: 200 ppm VLE; 616 mg/m3 VLE France - VME: 400 ppm VME; 1200 mg/m3 VME France - VLE: 500 ppm VLE; 1500 mg/m3 VLE Germany: 400 ppm TWA; 1200 mg/m3 TWA Japan: 400 ppm OEL; 1200 mg/m3 OEL Malaysia: 400 ppm TWA; 1210 mg/m3 TWA Netherlands: 200 ppm STEL; 616 mg/m3 STEL Netherlands: 100 ppm MAC; 308 mg/m3 MAC Russia: 300 mg/m3 TWA Spain: 100 ppm VLA-ED; 308 mg/m3 VLA-ED Spain: 200 ppm VLA-EC; 616 mg/m3 VLA-EC CAS# 64-17-5: United Kingdom, WEL - TWA: 1000 ppm TWA; 1920 mg/m3 TWA United Kingdom, WEL - STEL: 3000 ppm STEL; 5760 mg/m3 STEL United States OSHA: 1000 ppm TWA; 1900 mg/m3 TWA Belgium - TWA: 1000 ppm VLE; 1907 mg/m3 VLE France - VME: 1000 ppm VME; 1900 mg/m3 VME France - VLE: 5000 ppm VLE; 9500 mg/m3 VLE Germany: 500 ppm TWA; 960 mg/m3 TWA Malaysia: 1000 ppm TWA; 1880 mg/m3 TWA Netherlands: 500 ppm MAC; 1000 mg/m3 MAC Russia: 1000 mg/m3 TWA Spain: 1000 ppm VLA-ED; 1910 mg/m3 VLA-ED CAS# 9004-70-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless to slightly yellow, syrupy liquid
Odor: alcohol-like
pH: Not available.
Vapor Pressure: 440 mm Hg @ 20C
Viscosity: Not available.
Boiling Point: 32 deg C
Freezing/Melting Point: -123 deg C
Autoignition Temperature: 170 deg C ( 338.00 deg F)
Flash Point: -17.7 deg C ( 0.14 deg F)
Explosion Limits, lower: 1.9 vol %
Explosion Limits, upper: 36 vol %
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.765-0.775
Molecular Formula: Mixture
Molecular Weight: 0
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Prolonged exposure to air and sunlight may form unstable peroxides.
Explosive peroxides may form on concentration. Peroxides can be detonated by friction, impact, or heating. May form peroxides in the absence of inhibitors.
Conditions to Avoid:
Incompatible materials, light, ignition sources, exposure to air, excess heat, strong acids, strong oxidants, exposure to moist air or water, oxidizers, allowing solvents to evaporate, loss of inhibitor.
Incompatibilities with Other Materials:
Strong oxidizing agents, ammonia, bromine trifluoride, chlorine trifluoride, halogens, hydrazine, nitric acid, permanganates, silver perchlorate, sodium peroxide, sulfur, sulfuric acid, hydrogen peroxide, ozone, sodium, calcium hypochlorite, bromine, chromyl chloride, fluorine nitrate, nitrosyl perchlorate, bromine pentafluoride, perchloric acid, silver nitrate, chromic anhydride, mercuric nitrate, potassium-tert-butoxide, interhalogens, chlorine, magnesium perchlorate, uranyl nitrate, platinum, moisture, air, uranium hexafluoride, silver oxide, iodine heptafluoride, acetyl bromide, boron triazide, wood pulp extracts + heat, acetyl peroxide, bromoazide, potassium peroxide, triethyl or trimethyl aluminum + air, lithium aluminum hydride, disulfuryl difluoride, tetrachlorosilane + water, acetyl chloride, thiotriazyl perchlorate, nitryl perchlorate, permanganic acid, peroxodisulfuric acid, iodine (VII) oxide, sulfonyl chloride, liquid air, ruthenium (VIII) oxide, uranyl perchlorate.
Hazardous Decomposition Products:
Hydrogen cyanide, carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide, peroxides.
Hazardous Polymerization: Has not been reported.
Prolonged exposure to air and sunlight may form unstable peroxides.
Explosive peroxides may form on concentration. Peroxides can be detonated by friction, impact, or heating. May form peroxides in the absence of inhibitors.
Conditions to Avoid:
Incompatible materials, light, ignition sources, exposure to air, excess heat, strong acids, strong oxidants, exposure to moist air or water, oxidizers, allowing solvents to evaporate, loss of inhibitor.
Incompatibilities with Other Materials:
Strong oxidizing agents, ammonia, bromine trifluoride, chlorine trifluoride, halogens, hydrazine, nitric acid, permanganates, silver perchlorate, sodium peroxide, sulfur, sulfuric acid, hydrogen peroxide, ozone, sodium, calcium hypochlorite, bromine, chromyl chloride, fluorine nitrate, nitrosyl perchlorate, bromine pentafluoride, perchloric acid, silver nitrate, chromic anhydride, mercuric nitrate, potassium-tert-butoxide, interhalogens, chlorine, magnesium perchlorate, uranyl nitrate, platinum, moisture, air, uranium hexafluoride, silver oxide, iodine heptafluoride, acetyl bromide, boron triazide, wood pulp extracts + heat, acetyl peroxide, bromoazide, potassium peroxide, triethyl or trimethyl aluminum + air, lithium aluminum hydride, disulfuryl difluoride, tetrachlorosilane + water, acetyl chloride, thiotriazyl perchlorate, nitryl perchlorate, permanganic acid, peroxodisulfuric acid, iodine (VII) oxide, sulfonyl chloride, liquid air, ruthenium (VIII) oxide, uranyl perchlorate.
Hazardous Decomposition Products:
Hydrogen cyanide, carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide, peroxides.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 60-29-7: KI5775000 CAS# 64-17-5: KQ6300000 CAS# 9004-70-0: QW0970000 LD50/LC50:
CAS# 60-29-7: Draize test, rabbit, eye: 100 mg Moderate; Inhalation, mouse: LC50 = 31000 ppm/30M; Oral, mouse: LD50 = 1760 mg/kg; Oral, rat: LD50 = 1215 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg.
CAS# 9004-70-0: Oral, mouse: LD50 = >5 gm/kg; Oral, rat: LD50 = >5 gm/kg.
CAS# 60-29-7: Administration onto the skin, rabbit: LD50 = >20 mL/kg.
Ingestion of 1 to 2 ounces may be Carcinogenicity:
Ethyl ether - Not listed by ACGIH, IARC, or NTP.
Ethyl alcohol - Not listed by ACGIH, IARC, or NTP.
Nitrocellulose - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 60-29-7: KI5775000 CAS# 64-17-5: KQ6300000 CAS# 9004-70-0: QW0970000 LD50/LC50:
CAS# 60-29-7: Draize test, rabbit, eye: 100 mg Moderate; Inhalation, mouse: LC50 = 31000 ppm/30M; Oral, mouse: LD50 = 1760 mg/kg; Oral, rat: LD50 = 1215 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 64-17-5: Draize test, rabbit, eye: 500 mg Severe; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 39 gm/m3/4H; Inhalation, rat: LC50 = 20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg; Oral, rat: LD50 = 9000 mg/kg.
CAS# 9004-70-0: Oral, mouse: LD50 = >5 gm/kg; Oral, rat: LD50 = >5 gm/kg.
CAS# 60-29-7: Administration onto the skin, rabbit: LD50 = >20 mL/kg.
Ingestion of 1 to 2 ounces may be Carcinogenicity:
Ethyl ether - Not listed by ACGIH, IARC, or NTP.
Ethyl alcohol - Not listed by ACGIH, IARC, or NTP.
Nitrocellulose - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 2600 mg/L; 96 Hr; Flow-through bioassayFish: Bluegill/Sunfish: LC50 >10000 mg/L; 96 Hr; Static bioassayBacteria: Phytobacterium phosphoreum: EC50 = 5625 mg/L; 15 min; Microtox testFish: Fathead Minnow: LC50 = 2600 mg/L; 96 Hr; CAS# 60-29-7: Flow-through bioassayFish: Bluegill/Sunfish: LC50 >10000 mg/L; 96 Hr; CAS# 60-29-7: Static bioassayBacteria: Phytobacterium phosphoreum: EC50 = 5625 mg/L; 15 min; CAS# 60-29-7: Microtox testFish: Rainbow trout: LC50 = 12900-15300 mg/L; 96 Hr; Flow-through @ 24-24.3CFish: Rainbow trout: LC50 = 11200 mg/L; 24 Hr; Fingerling (Unspecified)Bacteria: Phytobacterium phosphoreum:
Fish: Fathead Minnow: LC50 = 2600 mg/L; 96 Hr; Flow-through bioassayFish: Bluegill/Sunfish: LC50 >10000 mg/L; 96 Hr; Static bioassayBacteria: Phytobacterium phosphoreum: EC50 = 5625 mg/L; 15 min; Microtox testFish: Fathead Minnow: LC50 = 2600 mg/L; 96 Hr; CAS# 60-29-7: Flow-through bioassayFish: Bluegill/Sunfish: LC50 >10000 mg/L; 96 Hr; CAS# 60-29-7: Static bioassayBacteria: Phytobacterium phosphoreum: EC50 = 5625 mg/L; 15 min; CAS# 60-29-7: Microtox testFish: Rainbow trout: LC50 = 12900-15300 mg/L; 96 Hr; Flow-through @ 24-24.3CFish: Rainbow trout: LC50 = 11200 mg/L; 24 Hr; Fingerling (Unspecified)Bacteria: Phytobacterium phosphoreum:
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: FLAMMABLE LIQUID, NOS(Ethanol solution)
Hazard Class: 3
UN Number: 1993
Packing Group: I
IMO
Shipping Name: FLAMMABLE LIQUID, NOS(Ethanol solution)
Hazard Class: 3
UN Number: 1993
Packing Group: I
RID/ADR
Shipping Name: FLAMMABLE LIQUID, NOS(Ethanol solution)
Hazard Class: 3
UN Number: 1993
Packing group: II
USA RQ: CAS# 60-29-7: 100 lb final RQ; 45.4 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F+
Risk Phrases:
R 12 Extremely flammable.
R 18 In use, may form flammable/explosive vapour-air
mixture.
R 19 May form explosive peroxides.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 60-29-7: 1
CAS# 64-17-5: 0
CAS# 9004-70-0: 0
Canada
CAS# 60-29-7 is listed on Canadas DSL List.
CAS# 64-17-5 is listed on Canadas DSL List.
CAS# 9004-70-0 is listed on Canadas DSL List.
CAS# 60-29-7 is listed on Canadas Ingredient Disclosure List.
CAS# 64-17-5 is listed on Canadas Ingredient Disclosure List.
CAS# 9004-70-0 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 60-29-7 is listed on the TSCA inventory.
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 9004-70-0 is listed on the TSCA inventory.
