英文MSDS库
当前位置:化工字典 > 英文MSDS
Name:
CRANCO
Synonym:
None Known
CAS:
67-64-1
Section 1 - Chemical Product
MSDS Name:CRANCO
Synonym:None Known
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
67-64-1 Acetone 43-69 200-662-2
Hazard Symbols: XN F
Risk Phrases: 11 20/21 36/38 66 67

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation and in contact with skin.
Irritating to eyes and skin. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury.
Skin:
Causes skin irritation. Skin absorption is slight. Prolonged exposure may cause the formation of vesicles (blisters). Contact with the skin causes erythema (redness), dryness, and defatting.
Ingestion:
Aspiration hazard. May cause irritation of the digestive tract. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause effects similar to those of acute inhalation.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Prolonged exposure may result in dizziness and general weakness. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause liver and kidney damage. May cause motor incoordination and speech abnormalities. Exposure may cause blood abnormalities. May cause irritation of the mucous membranes. May cause hyperplasia (the abnormal multiplication or increase in the number of normal cells in normal arrangement) of the bone and spleen.
Chronic:
Chronic exposure to organic solvents has been associated with various neurotoxic effects including permanent brain and nervous system damage. Prolonged or repeated skin contact may cause dermatitis.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Discard contaminated clothing in a manner which limits further exposure.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Possible aspiration hazard. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May be ignited by heat, sparks, and flame. Vapors may form an explosive mixture with air. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 67-64-1: United Kingdom, WEL - TWA: 500 ppm TWA; 1210 mg/m3 TWA United Kingdom, WEL - STEL: 1500 ppm STEL; 3620 mg/m3 STEL United States OSHA: 1000 ppm TWA; 2400 mg/m3 TWA Belgium - TWA: 500 ppm VLE; 1210 mg/m3 VLE Belgium - STEL: 1000 ppm VLE; 2420 mg/m3 VLE France - VME: 750 ppm VME; 1800 mg/m3 VME Germany: 500 ppm TWA; 1200 mg/m3 TWA Japan: 200 ppm OEL; 470 mg/m3 OEL Malaysia: 500 ppm TWA; 1187 mg/m3 TWA Netherlands: 750 ppm MAC; 1780 mg/m3 MAC Russia: 200 mg/m3 TWA Spain: 500 ppm VLA-ED; 1210 mg/m3 VLA-ED CAS# 84-74-2: United Kingdom, WEL - TWA: 5 mg/m3 TWA United Kingdom, WEL - STEL: 10 mg/m3 STEL United States OSHA: 5 mg/m3 TWA Belgium - TWA: 5 mg/m3 VLE France - VME: 5 mg/m3 VME Japan: 5 mg/m3 OEL Malaysia: 1 ppm TWA; 8.6 mg/m3 TWA Russia: 0.5 mg/m3 TWA Spain: 5 mg/m3 VLA-ED CAS# 1330-20-7: United Kingdom, WEL - TWA: 50 ppm TWA; 220 mg/m3 TWA United Kingdom, WEL - STEL: 100 ppm STEL; 441 mg/m3 STEL United States OSHA: 100 ppm TWA; 435 mg/m3 TWA Belgium - TWA: 50 ppm VLE; 221 mg/m3 VLE Belgium - STEL: 150 ppm VLE; 442 mg/m3 VLE France - VME: 100 ppm VME; 435 mg/m3 VME France - VLE: 150 ppm VLE; 650 mg/m3 VLE Germany: 100 ppm TWA; 440 mg/m3 TWA Germany: Skin absorber Japan: 50 ppm OEL; 217 mg/m3 OEL Malaysia: 199 ppm TWA; 434 mg/m3 TWA Netherlands: 50 ppm MAC; 210 mg/m3 MAC Russia: 50 mg/m3 TWA Spain: 50 ppm VLA-ED; 221 mg/m3 VLA-ED Spain: 100 ppm VLA-EC; 442 mg/m3 VLA-EC CAS# 9003-63-8: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: clear colorless
Odor: acetone-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Perchlorates, aliphatic amines, chromyl chloride, hexachloromelamine, chromic anhydride, chloroform + alkali, potassium-tert-butoxide, strong acids, 1,3-Dichloro-5,5-dimethyl-2,4-imidazolidindione (dichlorohydrantoin), Attacks some forms of plastics, rubber, and coatings..
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 67-64-1: AL3150000 CAS# 84-74-2: TI0875000 CAS# 1330-20-7: ZE2100000 CAS# 9003-63-8: UD3399000 LD50/LC50:
CAS# 67-64-1: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test, rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 20 mg/24H Moderate; Draize test, rabbit, eye: 10 uL Mild; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 44 gm/m3/4H; Inhalation, rat: LC50 = 50100 mg/m3/8H; Oral, mouse: LD50 = 3 gm/kg; Oral, rabbit: LD50 = 5340 mg/kg; Oral, rat: LD50 = 5800 mg/kg.
CAS# 84-74-2: Inhalation, mouse: LC50 = 25 gm/m3/2H; Inhalation, rat: LC50 = 4250 mg/m3; Oral, mouse: LD50 = 3474 mg/kg; Oral, rat: LD50 = 7499 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 1330-20-7: Draize test, rabbit, eye: 87 mg Mild; Draize test, rabbit, eye: 5 mg/24H Severe; Draize test, rabbit, skin: 100% Moderate; Draize test, rabbit, skin: 500 mg/24H Moderate; Inhalation, rat: LC50 = 5000 ppm/4H; Oral, mouse: LD50 = 2119 mg/kg; Oral, rat: LD50 = 4300 mg/kg; Skin, rabbit: LD50 = >1700 mg/kg.
CAS# 9003-63-8.
Carcinogenicity:
Acetone - Not listed by ACGIH, IARC, or NTP.
Dibutyl phthalate - Not listed by ACGIH, IARC, or NTP.
Xylenes (o-, m-, p- isomers) - Not listed by ACGIH, IARC, or NTP.
2-propenoic acid, 2-methyl-, butyl ester, homopolymer - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Rainbow trout: LC50 = 13.5 mg/L; 96 Hr; UnspecifiedFish: Goldfish: LD50 = 13 mg/L; 24 Hr; UnspecifiedFish: Fathead Minnow: LC50 = 46 mg/L; 1 Hr; Static bioassayAcute and long-term toxicity to fish and invertebrates: LD50 for goldfish is 13 mg/L/24 Hr.
Cas#1330-20-7: LC50(96Hr.) rainbow trout = 8.05 mg/L, Static condition; LC50(96Hr.) fathead minnow = 16.1 mg/L, flow-through conditions; LC50(96Hr.) bluegill = 16.1 mg/L, flow-through; EC50 (48 Hr.) water flea = 3.82 mg/L, flow-through conditions; EC50(24 Hr.) photobacterium phosphoreum = 0.0084 mg/L, Microtox test.

Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: FLAMMABLE SOLID, N.O.S. (CONTAINS ACETONE AND XYLE
NES)
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE SOLID, N.O.S. (CONTAINS ACETONE AND XYLE
NES)
Hazard Class: 3
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE SOLID, N.O.S. (CONTAINS ACETONE AND XYLE
NES)
Hazard Class: 3,3b
UN Number: 1993
Packing group: II
USA RQ: CAS# 67-64-1: 5000 lb final RQ; 2270 kg final RQ
USA RQ: CAS# 84-74-2: 10 lb final RQ; 4.54 kg final RQ
USA RQ: CAS# 1330-20-7: 100 lb final RQ; 45.4 kg final RQ

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20/21 Harmful by inhalation and in contact with
skin.
R 36/38 Irritating to eyes and skin.
R 66 Repeated exposure may cause skin dryness or
cracking.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 67-64-1: 0
CAS# 84-74-2: 2
CAS# 1330-20-7: 2
CAS# 9003-63-8: No information available.
Canada
CAS# 67-64-1 is listed on Canadas DSL List.
CAS# 84-74-2 is listed on Canadas DSL List.
CAS# 1330-20-7 is listed on Canadas DSL List.
CAS# 9003-63-8 is listed on Canadas DSL List.
CAS# 67-64-1 is listed on Canadas Ingredient Disclosure List.
CAS# 84-74-2 is listed on Canadas Ingredient Disclosure List.
CAS# 1330-20-7 is not listed on Canadas Ingredient Disclosure List.
CAS# 9003-63-8 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-64-1 is listed on the TSCA inventory.
CAS# 84-74-2 is listed on the TSCA inventory.
CAS# 1330-20-7 is listed on the TSCA inventory.
CAS# 9003-63-8 is listed on the TSCA inventory.