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Name:
Cyanocobalamin 96%
Synonym:
Anacobin; Vitamin B12; 1H-Benzimidazole, 5,6-dimethyl-1-(3-O-phosphono-alpha-d-ribofuranosyl)-, monoester with cobinamide cyanide hydroxide, inner salt; Cyanocobalamin
CAS:
68-19-9
Section 1 - Chemical Product
MSDS Name:Cyanocobalamin 96%
Synonym:Anacobin; Vitamin B12; 1H-Benzimidazole, 5,6-dimethyl-1-(3-O-phosphono-alpha-d-ribofuranosyl)-, monoester with cobinamide cyanide hydroxide, inner salt; Cyanocobalamin
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
68-19-9
Hazard Symbols: Not available.
Risk Phrases:

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Light sensitive.Hygroscopic.
Potential Health Effects
Eye:
Contact may cause transient eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause convulsions, tremors, muscular contractions or spasticity, diarrhea, or fever.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture. Store protected from light. Refrigeration has been recommended.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: dark red
Odor: odorless
pH: aq solns are neutral
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: > 300 deg C
Freezing/Melting Point: > 300 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Moderately soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: C63H88CoN14O14P
Molecular Weight: 1355.38

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures. May decompose when exposed to light. Darkens at 210 - 220C.
Conditions to Avoid:
Light, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizers, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of phosphorus, carbon dioxide, oxides of cobalt.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 68-19-9: GG3750000 LD50/LC50:
Not available.
Carcinogenicity:
Cyanobalamine - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 68-19-9: No information available.
United Kingdom Occupational Exposure Limits

United Kingdom Maximum Exposure Limits

Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 68-19-9 is not listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 68-19-9 (listed as ** undefined **): OEL-ARAB Republic of Egypt:T
WA 0.1 mg/m3
OEL-AUSTRALIA:TWA 0.05 mg/m3
OEL-BELGIUM:TWA 0.05 mg/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg/m3;STEL 0.1 mg/m3
OEL-DENMARK:TWA 0.05 mg/m3
OEL-FINLAND:TWA 0.05 mg/m3;Skin
OEL-GERMANY;Carcinogen
OEL-HUNGARY:TWA 0.1 mg/m3;STEL 0.2 mg/m3
OEL-THE NETHERLANDS:TWA 0.1 mg/m3
OEL-THE PHILIPPINES:TWA 0.1 mg/m3
OEL-POLAND:TWA 0.05 mg/m3
OEL-RUSSIA:STEL 0.5 mg/m3
OEL-SWEDEN:TWA 0.05 mg/m3
OEL-SWITZERLAND:TWA 0.1 mg/m3;Carcinogen
OEL-UNITED KINGDOM:TWA 0.1 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 68-19-9 is not listed on the TSCA inventory.
It is for research and development use only.