Name:
Dibutylboron trifluoromethanesulfonate in dichloromethane
Synonym:
CAS:
75-09-2
Section 1 - Chemical Product
MSDS Name:Dibutylboron trifluoromethanesulfonate in dichloromethane
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 75-09-2 | Methylene chloride | 200-838-9 |
| Hazard Symbols: T Risk Phrases: 10 14 23/24/25 34 40 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Reacts violently with water. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. Limited evidence of a carcinogenic effect.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Toxic in contact with skin.
Ingestion:
Causes gastrointestinal tract burns. Toxic if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract. Toxic if inhaled.
Chronic:
Limited evidence of a carcinogenic effect.
Flammable. Reacts violently with water. Toxic by inhalation, in contact with skin and if swallowed. Causes burns. Limited evidence of a carcinogenic effect.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. Toxic in contact with skin.
Ingestion:
Causes gastrointestinal tract burns. Toxic if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract. Toxic if inhaled.
Chronic:
Limited evidence of a carcinogenic effect.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Water Reactive. Material will react with water and may release a flammable and/or toxic gas.
Flammable liquid and vapor.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Water Reactive. Material will react with water and may release a flammable and/or toxic gas.
Flammable liquid and vapor.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Do not expose spill to water.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Do not expose spill to water.
Section 7 - HANDLING and STORAGE
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area. Corrosives area. Water free area. Store under nitrogen.
Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area. Corrosives area. Water free area. Store under nitrogen.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 75-09-2: United Kingdom, WEL - TWA: 100 ppm TWA; 350 mg/m3 TWA United Kingdom, WEL - STEL: 300 ppm STEL; 1060 mg/m3 STEL United States OSHA: ; 25 ppm TWA (8 hr); 125 ppm STEL (15 min); 1 ppm Action Level (See 29 CFR 1910 .1052) Belgium - TWA: 50 ppm VLE; 177 mg/m3 VLE France - VME: 50 ppm VME; 180 mg/m3 VME France - VLE: 100 ppm VLE; 350 mg/m3 VLE Germany: 100 ppm TWA; 350 mg/m3 TWA Japan: 50 ppm OEL; 170 mg/m3 OEL Japan: 100 ppm Ceiling; 340 mg/m3 Ceiling Malaysia: 50 ppm TWA Netherlands: 500 ppm STEL; 1750 mg/m3 STEL Netherlands: 100 ppm MAC; 350 mg/m3 MAC Russia: 50 mg/m3 TWA Spain: 50 ppm VLA-ED; 177 mg/m3 VLA-ED CAS# 60669-69-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 75-09-2: United Kingdom, WEL - TWA: 100 ppm TWA; 350 mg/m3 TWA United Kingdom, WEL - STEL: 300 ppm STEL; 1060 mg/m3 STEL United States OSHA: ; 25 ppm TWA (8 hr); 125 ppm STEL (15 min); 1 ppm Action Level (See 29 CFR 1910 .1052) Belgium - TWA: 50 ppm VLE; 177 mg/m3 VLE France - VME: 50 ppm VME; 180 mg/m3 VME France - VLE: 100 ppm VLE; 350 mg/m3 VLE Germany: 100 ppm TWA; 350 mg/m3 TWA Japan: 50 ppm OEL; 170 mg/m3 OEL Japan: 100 ppm Ceiling; 340 mg/m3 Ceiling Malaysia: 50 ppm TWA Netherlands: 500 ppm STEL; 1750 mg/m3 STEL Netherlands: 100 ppm MAC; 350 mg/m3 MAC Russia: 50 mg/m3 TWA Spain: 50 ppm VLA-ED; 177 mg/m3 VLA-ED CAS# 60669-69-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 27 deg C ( 80.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 1.271
Molecular Formula: C9H18BF3O3S
Molecular Weight: 274.11
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Air sensitive. Moisture sensitive.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to air, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, alcohols.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride gas, boron oxides.
Hazardous Polymerization: Not available.
Air sensitive. Moisture sensitive.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to air, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, alcohols.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride gas, boron oxides.
Hazardous Polymerization: Not available.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 75-09-2: PA8050000 CAS# 60669-69-4 unlisted.
LD50/LC50:
CAS# 75-09-2: Draize test, rabbit, eye: 162 mg Moderate; Draize test, rabbit, eye: 10 mg Mild; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 810 mg/24H Severe; Draize test, rabbit, skin: 100 mg/24H Moderate; Inhalation, mouse: LC50 = 14400 ppm/7H; Inhalation, mouse: LC50 = 49100 mg/m3/6H; Inhalation, mouse: LC50 = 54000 mg/m3/2H; Inhalation, mouse: LC50 = 56220 mg/m3/7H; Inhalation, rat: LC50 = 52 gm/m3; Inhalation, rat: LC50 = 76000 mg/m3/4H; Inhalation, rat: LC50 = 52000 mg/m3/6H; Oral, mouse: LD50 = 873 mg/kg; Oral, rabbit: LD50 = 2000 mg/kg; Oral, rat: LD50 = 1600 mg/kg; Oral, rat: LD50 = 985 mg/kg.
CAS# 60669-69-4.
Carcinogenicity:
Methylene chloride - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 4/1/88 NTP: Suspect carcinogen IARC: Group 2B carcinogen Dibutylboron trifluoromethanesulfonate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 75-09-2: PA8050000 CAS# 60669-69-4 unlisted.
LD50/LC50:
CAS# 75-09-2: Draize test, rabbit, eye: 162 mg Moderate; Draize test, rabbit, eye: 10 mg Mild; Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 810 mg/24H Severe; Draize test, rabbit, skin: 100 mg/24H Moderate; Inhalation, mouse: LC50 = 14400 ppm/7H; Inhalation, mouse: LC50 = 49100 mg/m3/6H; Inhalation, mouse: LC50 = 54000 mg/m3/2H; Inhalation, mouse: LC50 = 56220 mg/m3/7H; Inhalation, rat: LC50 = 52 gm/m3; Inhalation, rat: LC50 = 76000 mg/m3/4H; Inhalation, rat: LC50 = 52000 mg/m3/6H; Oral, mouse: LD50 = 873 mg/kg; Oral, rabbit: LD50 = 2000 mg/kg; Oral, rat: LD50 = 1600 mg/kg; Oral, rat: LD50 = 985 mg/kg.
CAS# 60669-69-4.
Carcinogenicity:
Methylene chloride - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 4/1/88 NTP: Suspect carcinogen IARC: Group 2B carcinogen Dibutylboron trifluoromethanesulfonate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.*
(forbidden to ship via passenger or cargo air)
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing group: II
USA RQ: CAS# 75-09-2: 1000 lb final RQ; 454 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 10 Flammable.
R 14 Reacts violently with water.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 34 Causes burns.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-09-2: 2
CAS# 60669-69-4: No information available.
Canada
CAS# 75-09-2 is listed on Canadas DSL List.
CAS# 75-09-2 is listed on Canadas Ingredient Disclosure List.
CAS# 60669-69-4 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-09-2 is listed on the TSCA inventory.
CAS# 60669-69-4 is not listed on the TSCA inventory.
It is for research and development use only.
