Name:
Eosin Y 1 % Alcoholic
Synonym:
None
CAS:
64-17-5
Section 1 - Chemical Product
MSDS Name:Eosin Y 1 % Alcoholic
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 64-17-5 | Ethyl alcohol | 94 % | 200-578-6 |
| Hazard Symbols: Not available. Risk Phrases: |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable liquid.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Vapors may cause eye irritation. May cause painful sensitization to light.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis. May be absorbed through the skin.
Ingestion:
May be fatal or cause blindness if swallowed. May cause central nervous system depression, kidney damage, and liver damage. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause systemic toxicity with acidosis.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. Prolonged exposure may result in dizziness and general weakness.
Chronic:
Prolonged or repeated eye contact may cause conjunctivitis.
Prolonged or repeated skin contact may cause defatting and dermatitis. Prolonged or repeated exposure may cause adverse reproductive effects. May cause liver and kidney damage.
Flammable liquid.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Vapors may cause eye irritation. May cause painful sensitization to light.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis. May be absorbed through the skin.
Ingestion:
May be fatal or cause blindness if swallowed. May cause central nervous system depression, kidney damage, and liver damage. Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause systemic toxicity with acidosis.
Inhalation:
Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. Prolonged exposure may result in dizziness and general weakness.
Chronic:
Prolonged or repeated eye contact may cause conjunctivitis.
Prolonged or repeated skin contact may cause defatting and dermatitis. Prolonged or repeated exposure may cause adverse reproductive effects. May cause liver and kidney damage.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
General Information:
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material.
Autoignition Temperature: Not applicable.
Flash Point: 55 deg F ( 12.78 deg C) NFPA Rating: Not published.
Explosion Limits, Lower: 3.3 Upper: 19.0
Containers can build up pressure if exposed to heat and/or fire. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material.
Autoignition Temperature: Not applicable.
Flash Point: 55 deg F ( 12.78 deg C) NFPA Rating: Not published.
Explosion Limits, Lower: 3.3 Upper: 19.0
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR ??1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirators use.
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR ??1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirators use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: red
Odor: Characteristic alcohol odor.
pH: Not available.
Vapor Pressure: 40 mm Hg
Vapor Density: 1.59
Evaporation Rate: 3.3
Viscosity: Not available.
Boiling Point: 79 deg C
Freezing/Melting Point: -114 deg C
Decomposition Temperature: Not available.
Solubility: Soluble in water.
Specific Gravity/Density: 0.789
Molecular Formula: Mixture
Molecular Weight: Not available.
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
The incompatibilities associated with ethanol include: acetic anhydride, acetyl bromide, ammonia + silver nitrate, disulfuric acid + nitric acid, dichloromethane + sulfuric acid, disulfuryl difluoride, magnesium perchlorate, nitric acid + silver, oxidants, phosphorus (III) oxide, platinum, potassium, potassium tert-butoxide, silver nitrate, silver oxide, sodium, tetrachlorosilane, acetyl chloride, sodium hydrazide. The incompatibilities associated with methanol include: acetyl bromide alkylaluminum solutions, beryllium hydride, carbon tetrachloride, chloroform + sodium, chloroform + sodium hydroxide, cyanuric chloride, dichloromethane, diethylzinc, metals, oxidants, phosphorus (III) oxide, potassium tert-butoxide.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
The incompatibilities associated with ethanol include: acetic anhydride, acetyl bromide, ammonia + silver nitrate, disulfuric acid + nitric acid, dichloromethane + sulfuric acid, disulfuryl difluoride, magnesium perchlorate, nitric acid + silver, oxidants, phosphorus (III) oxide, platinum, potassium, potassium tert-butoxide, silver nitrate, silver oxide, sodium, tetrachlorosilane, acetyl chloride, sodium hydrazide. The incompatibilities associated with methanol include: acetyl bromide alkylaluminum solutions, beryllium hydride, carbon tetrachloride, chloroform + sodium, chloroform + sodium hydroxide, cyanuric chloride, dichloromethane, diethylzinc, metals, oxidants, phosphorus (III) oxide, potassium tert-butoxide.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 17372-87-1: LM5850000 LD50/LC50:
CAS# 64-17-5: Inhalation, mouse: LC50 =39 gm/m3/4H; Inhalation, rat: LC50 =20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg.
CAS# 67-56-1: Inhalation, rat: LC50 =64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5628 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 17372-87-1: Oral, mouse: LD50 = 2344 mg/kg.
Carcinogenicity:
Ethyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Acid red 87 - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 17372-87-1: LM5850000 LD50/LC50:
CAS# 64-17-5: Inhalation, mouse: LC50 =39 gm/m3/4H; Inhalation, rat: LC50 =20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg.
CAS# 67-56-1: Inhalation, rat: LC50 =64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5628 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 17372-87-1: Oral, mouse: LD50 = 2344 mg/kg.
Carcinogenicity:
Ethyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Acid red 87 - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
For further information, contact Fisher Scientific.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
CDG/CPL
IMO
No information available.
IATA
No information available.
RID/ADR
No information available.
Canadian TDG
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 64-17-5: 0
CAS# 67-56-1: 1
CAS# 17372-87-1: 1
Canada
CAS# 64-17-5 is listed on Canadas DSL/NDSL List.
CAS# 67-56-1 is listed on Canadas DSL/NDSL List.
CAS# 17372-87-1 is listed on Canadas DSL/NDSL List.
WHMIS: Not available.
CAS# 64-17-5 is listed on Canadas Ingredient Disclosure List.
CAS# 67-56-1 is listed on Canadas Ingredient Disclosure List.
CAS# 17372-87-1 is not listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 64-17-5:. OEL-AUSTRALIA:TWA 1000 ppm (1900 mg/m3). OEL-BELGIUM:T
WA 1000 ppm (1880 mg/m3). OEL-CZECHOSLOVAKIA:TWA 1000 mg/m3;STEL 5000
mg/m3. OEL-DENMARK:TWA 1000 ppm (1900 mg/m3). OEL-FINLAND:TWA 1000 ppm
(1900 mg/m3);STEL 1250 ppm (2400 mg/m3). OEL-FRANCE:TWA 1000 ppm (190
0 mg/m3);STEL 5000 pp. OEL-GERMANY:TWA 1000 ppm (1900 mg/m3). OEL-HUNG
ARY:TWA 1000 mg/m3;STEL 3000 mg/m3. OEL-THE NETHERLANDS:TWA 1000 ppm (
1900 mg/m3). OEL-THE PHILIPPINES:TWA 1000 ppm (1900 mg/m3). OEL-POLAND
:TWA 1000 mg/m3. OEL-RUSSIA:STEL 1000 mg/m3. OEL-SWEDEN:TWA 1000 ppm (
1900 mg/m3). OEL-SWITZERLAND:TWA 1000 ppm (1900 mg/m3). OEL-THAILAND:T
WA 1000 ppm (1900 mg/m3). OEL-TURKEY:TWA 1000 ppm (1900 mg/m3). OEL-UN
ITED KINGDOM:TWA 1000 ppm (1900 mg/m3) JAN9. OEL IN BULGARIA, COLOMBIA
, JORDAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SINGAPORE, VIETNA
M check ACGI TLV
CAS# 67-56-1:. OEL-ARAB Republic of Egypt:TWA 200 ppm (260 mg/m3);Ski
n. OEL-AUSTRALIA:TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin. OEL-BELGIU
M:TWA 200 ppm (262 mg/m3);STEL 250 ppm;Skin. OEL-CZECHOSLOVAKIA:TWA 10
0 mg/m3;STEL 500 mg/m3. OEL-DENMARK:TWA 200 ppm (260 mg/m3);Skin. OEL-
FINLAND:TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin. OEL-FRANCE:TWA 200
ppm (260 mg/m3);STEL 1000 ppm (1300 mg/m3). OEL-GERMANY:TWA 200 ppm (2
60 mg/m3);Skin. OEL-HUNGARY:TWA 50 mg/m3;STEL 100 mg/m3;Skin JAN9. OEL
-JAPAN:TWA 200 ppm (260 mg/m3);Skin. OEL-THE NETHERLANDS:TWA 200 ppm (
260 mg/m3);Skin. OEL-THE PHILIPPINES:TWA 200 ppm (260 mg/m3). OEL-POLA
ND:TWA 100 mg/m3. OEL-RUSSIA:TWA 200 ppm;STEL 5 mg/m3;Skin. OEL-SWEDEN
:TWA 200 ppm (250 mg/m3);STEL 250 ppm (350 mg/m3);Skin. OEL-SWITZERLAN
D:TWA 200 ppm (260 mg/m3);STEL 400 ppm;Skin. OEL-THAILAND:TWA 200 ppm
(260 mg/m3). OEL-TURKEY:TWA 200 ppm (260 mg/m3). OEL-UNITED KINGDOM:TW
A 200 ppm (260 mg/m3);STEL 250 ppm;Skin. OEL IN BULGARIA, COLOMBIA, JO
RDAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SINGAPORE, VIETNAM ch
eck ACGI TLV
US FEDERAL
TSCA
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 17372-87-1 is listed on the TSCA inventory.
