Name:
Ethylbenzene-d10 packaged in ampules 99+ atom% D
Synonym:
CAS:
25837-05-2
Section 1 - Chemical Product
MSDS Name:Ethylbenzene-d10 packaged in ampules 99+ atom% D
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 25837-05-2 | Ethylbenzene-d10, packaged in ampules | 247-292-8 |
| Hazard Symbols: XN F Risk Phrases: 11 20 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes severe eye irritation. Causes redness and pain.
Skin:
Causes mild skin irritation. Causes redness and pain.
Ingestion:
May cause irritation of the digestive tract. May cause headache.
Possible aspiration hazard. May cause nausea and vomiting. May cause central nervous system depression. May cause effects similar to those of acute inhalation.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation. May cause drowsiness, unconsciousness, and central nervous system depression.
Chronic:
Prolonged or repeated skin contact may cause defatting and dermatitis. May cause liver and kidney damage.
Highly flammable. Harmful by inhalation.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes severe eye irritation. Causes redness and pain.
Skin:
Causes mild skin irritation. Causes redness and pain.
Ingestion:
May cause irritation of the digestive tract. May cause headache.
Possible aspiration hazard. May cause nausea and vomiting. May cause central nervous system depression. May cause effects similar to those of acute inhalation.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation. May cause drowsiness, unconsciousness, and central nervous system depression.
Chronic:
Prolonged or repeated skin contact may cause defatting and dermatitis. May cause liver and kidney damage.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Containers may explode in the heat of a fire.
Flammable liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. Water may be ineffective.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Containers may explode in the heat of a fire.
Flammable liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. Water may be ineffective.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 25837-05-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 25837-05-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 134.5 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 15 deg C ( 59.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible with most common organic solven
Specific Gravity/Density: .9490g/cm3
Molecular Formula: C6D5C2D5
Molecular Weight: 116.25
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Not available.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Not available.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 25837-05-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethylbenzene-d10, packaged in ampules - Not listed by ACGIH, IARC, or NTP.
CAS# 25837-05-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethylbenzene-d10, packaged in ampules - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Ethylbenzene CAS# 100-41-4: Fish toxicity: LC50 bluegill sunfish, goldfish, guppy, fathead minnow 12-96 mg/l/96H (Blum, D.J.W. et al Res.J.-Water Pollut. Control Fed. 1991, 63(3), 198-207; Pickering, Q.J. et al J.-Water Pollut. Control Fed. 1966, 38, 1419).
Invertebrate toxicity: EC50 Photobacterium phosphoreum 9.68 ppm/30min Microtox test (Kaiser, K.L.E. et al Water Pollut.
Res.J.Can. 1991, 26(3), 361-431).
EC50 Daphnia magna 2.1 mg/L/48H (Vighi, M. et al Chemosphere 1987, 16(5), 1043-1051).
Ethylbenzene CAS# 100-41-4: Fish toxicity: LC50 bluegill sunfish, goldfish, guppy, fathead minnow 12-96 mg/l/96H (Blum, D.J.W. et al Res.J.-Water Pollut. Control Fed. 1991, 63(3), 198-207; Pickering, Q.J. et al J.-Water Pollut. Control Fed. 1966, 38, 1419).
Invertebrate toxicity: EC50 Photobacterium phosphoreum 9.68 ppm/30min Microtox test (Kaiser, K.L.E. et al Water Pollut.
Res.J.Can. 1991, 26(3), 361-431).
EC50 Daphnia magna 2.1 mg/L/48H (Vighi, M. et al Chemosphere 1987, 16(5), 1043-1051).
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: ETHYLBENZENE
Hazard Class: 3
UN Number: 1175
Packing Group: II
IMO
Shipping Name: ETHYLBENZENE
Hazard Class: 3.2
UN Number: 1175
Packing Group: II
RID/ADR
Shipping Name: ETHYLBENZENE
Hazard Class: 3
UN Number: 1175
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20 Harmful by inhalation.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 29 Do not empty into drains.
WGK (Water Danger/Protection)
CAS# 25837-05-2: No information available.
Canada
CAS# 25837-05-2 is listed on Canadas NDSL List.
CAS# 25837-05-2 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 25837-05-2 is listed on the TSCA inventory.
