Name:
Ethylene Bromide
Synonym:
1,2-Dibromoethane; Ethylene dibromide; EDB
CAS:
106-93-4
Section 1 - Chemical Product
MSDS Name:Ethylene Bromide
Synonym:1,2-Dibromoethane; Ethylene dibromide; EDB
Synonym:1,2-Dibromoethane; Ethylene dibromide; EDB
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 106-93-4 | 1,2-Dibromoethane | 100 | 203-444-5 |
| Hazard Symbols: T N Risk Phrases: 23/24/25 36/37/38 45 51/53 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin. May cause cancer.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Skin:
Causes severe skin irritation. Harmful if absorbed through the skin.
May cause skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause effects similar to those for inhalation exposure.
Inhalation:
Effects may be delayed. Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause liver and kidney damage.
May cause heart disturbances, possibly leading to cardiac arrest and death. May cause lung damage.
Chronic:
May cause fetal effects. May cause cancer in humans.
Toxic by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin. May cause cancer.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Skin:
Causes severe skin irritation. Harmful if absorbed through the skin.
May cause skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause effects similar to those for inhalation exposure.
Inhalation:
Effects may be delayed. Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Irritation may lead to chemical pneumonitis and pulmonary edema. May cause liver and kidney damage.
May cause heart disturbances, possibly leading to cardiac arrest and death. May cause lung damage.
Chronic:
May cause fetal effects. May cause cancer in humans.
Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
POISON material. If inhaled, get medical aid immediately. Remove victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
POISON material. If inhaled, get medical aid immediately. Remove victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). A vapor suppressing foam may be used to reduce vapors.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). A vapor suppressing foam may be used to reduce vapors.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Do not breathe vapor. Use only with adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Storage under a nitrogen blanket has been recommended. Separate from oxidizing materials.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not get in eyes, on skin, or on clothing. Do not breathe vapor. Use only with adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Storage under a nitrogen blanket has been recommended. Separate from oxidizing materials.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 106-93-4: United Kingdom, WEL - TWA: 0.5 ppm TWA; 3.9 mg/m3 TWA United Kingdom, WEL - STEL: 1.5 ppm STEL; 11.7 mg/m3 STEL United States OSHA: 20 ppm TWA; 30 ppm Ceiling Germany: 0.1 ppm TWA; 0.8 mg/m3 TWA Germany: Skin absorber Netherlands: 0.002 mg/m3 MAC Spain: 0.5 ppm VLA-ED; 3.9 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 106-93-4: United Kingdom, WEL - TWA: 0.5 ppm TWA; 3.9 mg/m3 TWA United Kingdom, WEL - STEL: 1.5 ppm STEL; 11.7 mg/m3 STEL United States OSHA: 20 ppm TWA; 30 ppm Ceiling Germany: 0.1 ppm TWA; 0.8 mg/m3 TWA Germany: Skin absorber Netherlands: 0.002 mg/m3 MAC Spain: 0.5 ppm VLA-ED; 3.9 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear colorless to faint yellow
Odor: Sweet, chloroform-like.
pH: Not available.
Vapor Pressure: 11 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 131-132 deg C
Freezing/Melting Point: 9-10 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 2.18 (water=1)
Molecular Formula: C2H4Br2
Molecular Weight: 187.86
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Exposure to light and/or heat in the presence of water (including moist air).
Incompatibilities with Other Materials:
Strong oxidizing agents, alkali metals, ammonia.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Exposure to light and/or heat in the presence of water (including moist air).
Incompatibilities with Other Materials:
Strong oxidizing agents, alkali metals, ammonia.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 106-93-4: KH9275000 LD50/LC50:
CAS# 106-93-4: Draize test, rabbit, eye: 1%; Draize test, rabbit, skin: 1%/14D Severe; Inhalation, rat: LC50 = 14300 mg/m3/30M; Oral, rabbit: LD50 = 55 mg/kg; Oral, rat: LD50 = 108 mg/kg; Skin, rabbit: LD50 = 300 mg/kg; Skin, rat: LD50 = 300 mg/kg.
Carcinogenicity:
1,2-Dibromoethane - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 7/1/87 NTP: Suspect carcinogen IARC: Group 2A carcinogen Other:
See actual entry in RTECS for complete information.
CAS# 106-93-4: KH9275000 LD50/LC50:
CAS# 106-93-4: Draize test, rabbit, eye: 1%; Draize test, rabbit, skin: 1%/14D Severe; Inhalation, rat: LC50 = 14300 mg/m3/30M; Oral, rabbit: LD50 = 55 mg/kg; Oral, rat: LD50 = 108 mg/kg; Skin, rabbit: LD50 = 300 mg/kg; Skin, rat: LD50 = 300 mg/kg.
Carcinogenicity:
1,2-Dibromoethane - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 7/1/87 NTP: Suspect carcinogen IARC: Group 2A carcinogen Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Bluegill (fresh water) 18mg/L/48H
Bluegill (fresh water) 18mg/L/48H
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: ETHYLENE DIBROMIDE
Hazard Class: 6.1
UN Number: 1605
Packing Group: I
IMO
Shipping Name: ETHYLENE DIBROMIDE
Hazard Class: 6.1
UN Number: 1605
Packing Group: I
RID/ADR
Shipping Name: ETHYLENE DIBROMIDE
Hazard Class: 6.1
UN Number: 1605
Packing group: I
USA RQ: CAS# 106-93-4: 1 lb final RQ; 0.454 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 45 May cause cancer.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 106-93-4: 3
Canada
CAS# 106-93-4 is listed on Canadas DSL List.
CAS# 106-93-4 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-93-4 is listed on the TSCA inventory.
