Name:
Ethylene diacrylate stabilized 70-90%
Synonym:
Ethylene glycol diacrylate; 1,2-Diacrylyl ethane; 2-Propenoic acid, 1,2-ethanediyl ester
CAS:
107-21-1
Section 1 - Chemical Product
MSDS Name:Ethylene diacrylate stabilized 70-90%
Synonym:Ethylene glycol diacrylate; 1,2-Diacrylyl ethane; 2-Propenoic acid, 1,2-ethanediyl ester
Synonym:Ethylene glycol diacrylate; 1,2-Diacrylyl ethane; 2-Propenoic acid, 1,2-ethanediyl ester
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 107-21-1 | Ethylene glycol | <30 | 203-473-3 |
| Hazard Symbols: XN Risk Phrases: 21/22 36/37/38 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause eye injury. Lachrymator (substance which increases the flow of tears).
Skin:
Causes skin irritation. Harmful if absorbed through the skin. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
No information found.
Harmful in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause eye injury. Lachrymator (substance which increases the flow of tears).
Skin:
Causes skin irritation. Harmful if absorbed through the skin. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
No information found.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not breathe vapor or mist.
Storage:
Store in a cool, dry place. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed. Store protected from light.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not breathe vapor or mist.
Storage:
Store in a cool, dry place. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed. Store protected from light.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 107-21-1: United Kingdom, WEL - TWA: 20 ppm TWA (vapor); 52 mg/m3 TWA (vapo 10 mg/m3 TWA (particulate) United Kingdom, WEL - STEL: 40 ppm STEL (vapor); 104 mg/m3 STEL (vapor); 30 mg/m3 STEL (particulate) Belgium - TWA: 20 ppm VLE; 52 mg/m3 VLE Belgium - STEL: 40 ppm VLE; 104 mg/m3 VLE France - VLE: 50 ppm VLE (vapor); 125 mg/m3 VLE (vapor) Germany: 10 ppm TWA; 26 mg/m3 TWA Germany: Skin absorber Malaysia: 39.4 ppm Ceiling (aerosol); 100 mg/m3 Ceiling (aerosol) Netherlands: 40 ppm STEL; 104 mg/m3 STEL Netherlands: 20 ppm MAC (fume); 52 mg/m3 MAC (fume); 10 mg/m3 MAC (droplets) Russia: 5 mg/m3 TWA (aerosol, particulate, mist) Spain: 20 ppm VLA-ED; 52 mg/m3 VLA-ED Spain: 40 ppm VLA-EC; 104 mg/m3 VLA-EC CAS# 150-76-5: Belgium - TWA: 5 mg/m3 VLE France - VME: 5 mg/m3 VME Germany: 5 mg/m3 TWA Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED CAS# 2274-11-5: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 107-21-1: United Kingdom, WEL - TWA: 20 ppm TWA (vapor); 52 mg/m3 TWA (vapo 10 mg/m3 TWA (particulate) United Kingdom, WEL - STEL: 40 ppm STEL (vapor); 104 mg/m3 STEL (vapor); 30 mg/m3 STEL (particulate) Belgium - TWA: 20 ppm VLE; 52 mg/m3 VLE Belgium - STEL: 40 ppm VLE; 104 mg/m3 VLE France - VLE: 50 ppm VLE (vapor); 125 mg/m3 VLE (vapor) Germany: 10 ppm TWA; 26 mg/m3 TWA Germany: Skin absorber Malaysia: 39.4 ppm Ceiling (aerosol); 100 mg/m3 Ceiling (aerosol) Netherlands: 40 ppm STEL; 104 mg/m3 STEL Netherlands: 20 ppm MAC (fume); 52 mg/m3 MAC (fume); 10 mg/m3 MAC (droplets) Russia: 5 mg/m3 TWA (aerosol, particulate, mist) Spain: 20 ppm VLA-ED; 52 mg/m3 VLA-ED Spain: 40 ppm VLA-EC; 104 mg/m3 VLA-EC CAS# 150-76-5: Belgium - TWA: 5 mg/m3 VLE France - VME: 5 mg/m3 VME Germany: 5 mg/m3 TWA Malaysia: 5 mg/m3 TWA Netherlands: 5 mg/m3 MAC Spain: 5 mg/m3 VLA-ED CAS# 2274-11-5: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: colorless
Odor: suffocating odor - disagreeable odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 62 - 65 deg C @ 2mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.040
Molecular Formula: C8H10O4
Molecular Weight: 170.17
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable. However, it may undergo explosive polymerization if uninhibited.
Conditions to Avoid:
Light, excess heat, loss of inhibitor.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, peroxides.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
Stable. However, it may undergo explosive polymerization if uninhibited.
Conditions to Avoid:
Light, excess heat, loss of inhibitor.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, peroxides.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 107-21-1: KW2975000 CAS# 150-76-5: SL7700000 CAS# 2274-11-5: AT0350000 LD50/LC50:
CAS# 107-21-1: Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, eye: 100 mg/1H Mild; Draize test, rabbit, eye: 0.012 ppm/3D; Draize test, rabbit, eye: 1440 mg/6H Moderate; Oral, mouse: LD50 = 5500 mg/kg; Oral, rat: LD50 = 4700 mg/kg; Skin, rabbit: LD50 = 9530 uL/kg.
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent) Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
CAS# 2274-11-5: Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 350 mg/m3; Oral, mouse: LD50 = 300 mg/kg; Oral, rat: LD50 = 300 mg/kg; Skin, rabbit: LD50 = 570 uL/kg.
Carcinogenicity:
Ethylene glycol - Not listed by ACGIH, IARC, or NTP.
4-Methoxyphenol - Not listed by ACGIH, IARC, or NTP.
2-Propenoic acid, 1,2-ethanediyl ester - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 107-21-1: KW2975000 CAS# 150-76-5: SL7700000 CAS# 2274-11-5: AT0350000 LD50/LC50:
CAS# 107-21-1: Draize test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, eye: 100 mg/1H Mild; Draize test, rabbit, eye: 0.012 ppm/3D; Draize test, rabbit, eye: 1440 mg/6H Moderate; Oral, mouse: LD50 = 5500 mg/kg; Oral, rat: LD50 = 4700 mg/kg; Skin, rabbit: LD50 = 9530 uL/kg.
CAS# 150-76-5: Draize test, rabbit, skin: 6 gm/12D (Intermittent) Mild; Draize test, rabbit, skin: 10%; Oral, rat: LD50 = 1600 mg/kg.
CAS# 2274-11-5: Draize test, rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 350 mg/m3; Oral, mouse: LD50 = 300 mg/kg; Oral, rat: LD50 = 300 mg/kg; Skin, rabbit: LD50 = 570 uL/kg.
Carcinogenicity:
Ethylene glycol - Not listed by ACGIH, IARC, or NTP.
4-Methoxyphenol - Not listed by ACGIH, IARC, or NTP.
2-Propenoic acid, 1,2-ethanediyl ester - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
USA RQ: CAS# 107-21-1: 5000 lb final RQ; 2270 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 107-21-1: 0
CAS# 150-76-5: 1
CAS# 2274-11-5: No information available.
Canada
CAS# 107-21-1 is listed on Canadas DSL List.
CAS# 150-76-5 is listed on Canadas DSL List.
CAS# 2274-11-5 is listed on Canadas NDSL List.
CAS# 107-21-1 is listed on Canadas Ingredient Disclosure List.
CAS# 150-76-5 is listed on Canadas Ingredient Disclosure List.
CAS# 2274-11-5 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 107-21-1 is listed on the TSCA inventory.
CAS# 150-76-5 is listed on the TSCA inventory.
CAS# 2274-11-5 is listed on the TSCA inventory.
