Name:
Ethylene-d4 glycol packaged in ampules 99 atom% d
Synonym:
CAS:
2219-51-4
Section 1 - Chemical Product
MSDS Name:Ethylene-d4 glycol packaged in ampules 99 atom% d
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 2219-51-4 | Ethylene-d4 glycol | 218-730-5 |
| Hazard Symbols: XN Risk Phrases: 22 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful if swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause moderate eye irritation.
Skin:
May cause skin irritation. Low hazard for usual industrial handling.
May be absorbed through the skin.
Ingestion:
May cause kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause nausea and vomiting.
Inhalation:
May cause respiratory tract irritation. Heated or misted substance may cause headache, irregular eye movements, and possible coma.
Chronic:
May cause liver and kidney damage.
Harmful if swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause moderate eye irritation.
Skin:
May cause skin irritation. Low hazard for usual industrial handling.
May be absorbed through the skin.
Ingestion:
May cause kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause nausea and vomiting.
Inhalation:
May cause respiratory tract irritation. Heated or misted substance may cause headache, irregular eye movements, and possible coma.
Chronic:
May cause liver and kidney damage.
Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Store under nitrogen.
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Store under nitrogen.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 2219-51-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 2219-51-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: Clear - colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 86 - 87 deg C @ 8.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: practically insoluble in benzene
Specific Gravity/Density: 1.1890g/cm3
Molecular Formula: C2H2D4O2
Molecular Weight: 66.10
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, contact with water, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, sodium hydroxide, sodium peroxide, sulfuric acid, potassium permanganate, chlorosulfonic acid, oleum, chromium trioxide, phosphorus pentasulfide, silvered-copper wire, titanium butoxide, ammonium dichromate, silver chlorate, sodium chloride.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, contact with water, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, sodium hydroxide, sodium peroxide, sulfuric acid, potassium permanganate, chlorosulfonic acid, oleum, chromium trioxide, phosphorus pentasulfide, silvered-copper wire, titanium butoxide, ammonium dichromate, silver chlorate, sodium chloride.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 2219-51-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethylene-d4 glycol - Not listed by ACGIH, IARC, or NTP.
CAS# 2219-51-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethylene-d4 glycol - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Goldfish LD50:>5000 mg/L/24Hr ; Guppies LC50:493,000 ppm/7D ; Shrimp (salt water) LC50:>100 ppm/48Hr
Goldfish LD50:>5000 mg/L/24Hr ; Guppies LC50:493,000 ppm/7D ; Shrimp (salt water) LC50:>100 ppm/48Hr
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 2 Keep out of reach of children.
WGK (Water Danger/Protection)
CAS# 2219-51-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2219-51-4 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2219-51-4 is not listed on the TSCA inventory.
It is for research and development use only.
