Name:
Etoh anhydrous denat. with up to 5% mek and meoh/etoac
Synonym:
CAS:
64-17-5
Section 1 - Chemical Product
MSDS Name:Etoh anhydrous denat. with up to 5% mek and meoh/etoac
Synonym:
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 64-17-5 | Ethyl alcohol | 200-578-6 |
| Hazard Symbols: F Risk Phrases: 11 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Highly flammable.Highly flammable.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause muscle tremor and impaired motor function. May cause cardiac disturbances.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause central nervous system effects including vertigo, anxiety, depression, muscle incoordination, and emotional instability. May cause narcotic effects.
Chronic:
Not available.
Highly flammable.Highly flammable.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Symptoms may include: headache, excitement, fatigue, nausea, vomiting, stupor, and coma. May cause muscle tremor and impaired motor function. May cause cardiac disturbances.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause central nervous system effects including vertigo, anxiety, depression, muscle incoordination, and emotional instability. May cause narcotic effects.
Chronic:
Not available.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Treat symptomatically.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Containers may explode in the heat of a fire.
Extinguishing Media:
In case of fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Autoignition Temperature: 370 deg C ( 698.00 deg F) Flash Point: 12 deg C ( 53.60 deg F) NFPA Rating: Not published.
Explosion Limits, Lower: 4.00 vol % Upper: 19.00 vol %
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Containers may explode in the heat of a fire.
Extinguishing Media:
In case of fire use water spray, dry chemical, carbon dioxide, or chemical foam.
Autoignition Temperature: 370 deg C ( 698.00 deg F) Flash Point: 12 deg C ( 53.60 deg F) NFPA Rating: Not published.
Explosion Limits, Lower: 4.00 vol % Upper: 19.00 vol %
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition.
Spills/Leaks:
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition.
Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
Flammables-area.
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
Flammables-area.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Personal Protective Equipment Eyes: Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Personal Protective Equipment Eyes: Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 59 mbar @20 deg C
Vapor Density: 1.59
Evaporation Rate: Not available.
Viscosity: 1.2 mPas 20 deg
Boiling Point: 78 deg C @ 760.00mm Hg
Freezing/Melting Point: -144 deg C
Decomposition Temperature: Not available.
Solubility: miscible
Specific Gravity/Density: .7890g/cm3
Molecular Formula: C2H6O
Molecular Weight: 46.06
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Acids, acid chlorides, acid anhydrides, oxidizing agents, reducing agents, alkali metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Acids, acid chlorides, acid anhydrides, oxidizing agents, reducing agents, alkali metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 78-93-3: EL6475000 LD50/LC50:
CAS# 64-17-5: Inhalation, mouse: LC50 =39 gm/m3/4H; Inhalation, rat: LC50 =20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg.
CAS# 67-56-1: Inhalation, rat: LC50 =64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5628 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 78-93-3: Inhalation, mouse: LC50 =40 gm/m3/2H; Inhalation, rat: LC50 =23500 mg/m3/8H; Oral, mouse: LD50 = 4050 mg/kg; Oral, rat: LD50 = 2737 mg/kg; Skin, rabbit: LD50 = 6480 mg/kg.
Carcinogenicity:
Ethyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl ethyl ketone - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
CAS# 64-17-5: KQ6300000 CAS# 67-56-1: PC1400000 CAS# 78-93-3: EL6475000 LD50/LC50:
CAS# 64-17-5: Inhalation, mouse: LC50 =39 gm/m3/4H; Inhalation, rat: LC50 =20000 ppm/10H; Oral, mouse: LD50 = 3450 mg/kg; Oral, rabbit: LD50 = 6300 mg/kg; Oral, rat: LD50 = 7060 mg/kg.
CAS# 67-56-1: Inhalation, rat: LC50 =64000 ppm/4H; Oral, mouse: LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50 = 5628 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
CAS# 78-93-3: Inhalation, mouse: LC50 =40 gm/m3/2H; Inhalation, rat: LC50 =23500 mg/m3/8H; Oral, mouse: LD50 = 4050 mg/kg; Oral, rat: LD50 = 2737 mg/kg; Skin, rabbit: LD50 = 6480 mg/kg.
Carcinogenicity:
Ethyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl alcohol - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Methyl ethyl ketone - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
For further information, contact Fisher Scientific.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
CDG/CPL
IMO
Shipping Name: ETHANOL
Hazard Class: 3.2
UN Number: 1170
Packing Group: II
IATA
Shipping Name: ETHANOL
Hazard Class: 3
UN Number: 1170
Packing Group: II
RID/ADR
Shipping Name: ETHANOL
Dangerous Goods Code: 3(3B)
UN Number: 1170
Canadian TDG
Shipping Name: ETHANOL
Hazard Class: 3
UN Number: UN1170
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 7 Keep container tightly closed.
WGK (Water Danger/Protection)
CAS# 64-17-5: 0
CAS# 67-56-1: 1
CAS# 78-93-3: 1
Canada
CAS# 64-17-5 is listed on Canadas DSL/NDSL List.
CAS# 67-56-1 is listed on Canadas DSL/NDSL List.
CAS# 78-93-3 is listed on Canadas DSL/NDSL List.
This product does not have a WHMIS classification.
CAS# 64-17-5 is listed on Canadas Ingredient Disclosure List.
CAS# 67-56-1 is listed on Canadas Ingredient Disclosure List.
CAS# 78-93-3 is listed on Canadas Ingredient Disclosure List.
Exposure Limits
CAS# 64-17-5:. OEL-AUSTRALIA:TWA 1000 ppm (1900 mg/m3). OEL-BELGIUM:T
WA 1000 ppm (1880 mg/m3). OEL-CZECHOSLOVAKIA:TWA 1000 mg/m3;STEL 5000
mg/m3. OEL-DENMARK:TWA 1000 ppm (1900 mg/m3). OEL-FINLAND:TWA 1000 ppm
(1900 mg/m3);STEL 1250 ppm (2400 mg/m3). OEL-FRANCE:TWA 1000 ppm (190
0 mg/m3);STEL 5000 pp. OEL-GERMANY:TWA 1000 ppm (1900 mg/m3). OEL-HUNG
ARY:TWA 1000 mg/m3;STEL 3000 mg/m3. OEL-THE NETHERLANDS:TWA 1000 ppm (
1900 mg/m3). OEL-THE PHILIPPINES:TWA 1000 ppm (1900 mg/m3). OEL-POLAND
:TWA 1000 mg/m3. OEL-RUSSIA:STEL 1000 mg/m3. OEL-SWEDEN:TWA 1000 ppm (
1900 mg/m3). OEL-SWITZERLAND:TWA 1000 ppm (1900 mg/m3). OEL-THAILAND:T
WA 1000 ppm (1900 mg/m3). OEL-TURKEY:TWA 1000 ppm (1900 mg/m3). OEL-UN
ITED KINGDOM:TWA 1000 ppm (1900 mg/m3) JAN9. OEL IN BULGARIA, COLOMBIA
, JORDAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SINGAPORE, VIETNA
M check ACGI TLV
CAS# 67-56-1:. OEL-ARAB Republic of Egypt:TWA 200 ppm (260 mg/m3);Ski
n. OEL-AUSTRALIA:TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin. OEL-BELGIU
M:TWA 200 ppm (262 mg/m3);STEL 250 ppm;Skin. OEL-CZECHOSLOVAKIA:TWA 10
0 mg/m3;STEL 500 mg/m3. OEL-DENMARK:TWA 200 ppm (260 mg/m3);Skin. OEL-
FINLAND:TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin. OEL-FRANCE:TWA 200
ppm (260 mg/m3);STEL 1000 ppm (1300 mg/m3). OEL-GERMANY:TWA 200 ppm (2
60 mg/m3);Skin. OEL-HUNGARY:TWA 50 mg/m3;STEL 100 mg/m3;Skin JAN9. OEL
-JAPAN:TWA 200 ppm (260 mg/m3);Skin. OEL-THE NETHERLANDS:TWA 200 ppm (
260 mg/m3);Skin. OEL-THE PHILIPPINES:TWA 200 ppm (260 mg/m3). OEL-POLA
ND:TWA 100 mg/m3. OEL-RUSSIA:TWA 200 ppm;STEL 5 mg/m3;Skin. OEL-SWEDEN
:TWA 200 ppm (250 mg/m3);STEL 250 ppm (350 mg/m3);Skin. OEL-SWITZERLAN
D:TWA 200 ppm (260 mg/m3);STEL 400 ppm;Skin. OEL-THAILAND:TWA 200 ppm
(260 mg/m3). OEL-TURKEY:TWA 200 ppm (260 mg/m3). OEL-UNITED KINGDOM:TW
A 200 ppm (260 mg/m3);STEL 250 ppm;Skin. OEL IN BULGARIA, COLOMBIA, JO
RDAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SINGAPORE, VIETNAM ch
eck ACGI TLV
CAS# 78-93-3:. OEL-AUSTRALIA:TWA 150 ppm (445 mg/m3);STEL 300 ppm (89
0 mg/m3). OEL-AUSTRIA:TWA 200 ppm (590 mg/m3). OEL-BELGIUM:TWA 200 ppm
(590 mg/m3);STEL 300 ppm (885 mg/m3). OEL-DENMARK:TWA 100 ppm (290 mg
/m3);Skin. OEL-FINLAND:TWA 150 ppm (440 mg/m3);STEL 190 ppm;Skin. OEL-
FRANCE:TWA 200 ppm (600 mg/m3);Skin. OEL-GERMANY:TWA 200 ppm (590 mg/m
3). OEL-HUNGARY:TWA 200 mg/m3;STEL 600 mg/m3. OEL-INDIA:TWA 200 ppm (5
90 mg/m3);STEL 300 ppm (885 mg/m3). OEL-JAPAN:TWA 200 ppm (590 mg/m3)
OEL-THE NETHERLANDS:TWA 200 ppm (590 mg/m3). OEL-THE PHILIPPINES:TWA
200 ppm (590 mg/m3). OEL-POLAND:TWA 200 mg/m3. OEL-RUSSIA:TWA 200 ppm;
STEL 200 mg/m3. OEL-SWEDEN:TWA 50 ppm (150 mg/m3);STEL 100 ppm (300 mg
/m3). OEL-SWITZERLAND:TWA 200 ppm (590 mg/m3);STEL 400 ppm. OEL-TURKEY
:TWA 200 ppm (590 mg/m3). OEL-UNITED KINGDOM:TWA 200 ppm (590 mg/m3);S
TEL 300 ppm. OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 64-17-5 is listed on the TSCA inventory.
CAS# 67-56-1 is listed on the TSCA inventory.
CAS# 78-93-3 is listed on the TSCA inventory.
