Name:
FisherBrand Citrisolv
Synonym:
Carvene; (+)-4-Isopropenyl-1-methylcyclohexene; (+)-R-Limonene; (R)-1-Methyl-4-(1-methylethenyl)cyclohexene; D-(+)-Limonene; d-Limonene; d-p-Mentha-1,8-diene; optically active terpene
CAS:
5989-27-5
Section 1 - Chemical Product
MSDS Name:FisherBrand Citrisolv
Synonym:Carvene; (+)-4-Isopropenyl-1-methylcyclohexene; (+)-R-Limonene; (R)-1-Methyl-4-(1-methylethenyl)cyclohexene; D-(+)-Limonene; d-Limonene; d-p-Mentha-1,8-diene; optically active terpene
Synonym:Carvene; (+)-4-Isopropenyl-1-methylcyclohexene; (+)-R-Limonene; (R)-1-Methyl-4-(1-methylethenyl)cyclohexene; D-(+)-Limonene; d-Limonene; d-p-Mentha-1,8-diene; optically active terpene
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 5989-27-5 | d-Limonene | 98 | 227-813-5 |
| Hazard Symbols: XI N Risk Phrases: 10 38 43 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Irritating to skin. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Prolonged and/or repeated contact may cause defatting of the skin and dermatitis.
Ingestion:
May cause digestive tract disturbances.
Inhalation:
May cause respiratory tract irritation.
Chronic:
In 2-year gavage studies, there was clear evidence of carcinogenic activity of d-limonene for male rats, as shown by increased incidences of tubular cell hyperplasia, adenomas, and adenocarcinomas of the kidney. There was NO evidence of carcinogenic activity of d-limonene for female rats, for male mice, or for female mice.
Flammable. Irritating to skin. May cause sensitization by skin contact. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Prolonged and/or repeated contact may cause defatting of the skin and dermatitis.
Ingestion:
May cause digestive tract disturbances.
Inhalation:
May cause respiratory tract irritation.
Chronic:
In 2-year gavage studies, there was clear evidence of carcinogenic activity of d-limonene for male rats, as shown by increased incidences of tubular cell hyperplasia, adenomas, and adenocarcinomas of the kidney. There was NO evidence of carcinogenic activity of d-limonene for female rats, for male mice, or for female mice.
Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Get medical aid if symptoms occur. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Skin:
In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Get medical aid if symptoms occur. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. This liquid floats on water and may travel to a source of ignition and spread fire.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide or alcohol type foam.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. This liquid floats on water and may travel to a source of ignition and spread fire.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide or alcohol type foam.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Forms smooth, slippery surfaces on floors, posing an accident risk. Remove all sources of ignition.
Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Forms smooth, slippery surfaces on floors, posing an accident risk. Remove all sources of ignition.
Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Avoid breathing vapor or mist.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area. Separate from oxidizing materials. Partially filled containers should be blanketed with nitrogen.
Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Avoid breathing vapor or mist.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area. Separate from oxidizing materials. Partially filled containers should be blanketed with nitrogen.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirators use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirators use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear almost colorless
Odor: citrus-like odor
pH: Not available.
Vapor Pressure: 1.98 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 175-176 deg C @ 760 mmHg
Freezing/Melting Point: -74 deg C
Autoignition Temperature: 255 deg C ( 491.00 deg F)
Flash Point: 48 deg C ( 118.40 deg F)
Explosion Limits, lower: .70 vol %
Explosion Limits, upper: 6.10 vol %
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .8400 g/ml
Molecular Formula: C10H16
Molecular Weight: 136.24
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, prolonged exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, prolonged exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 5989-27-5: GW6360000 CAS# 25013-16-5: SL1945000 LD50/LC50:
CAS# 5989-27-5: Oral, mouse: LD50 = 5600 mg/kg; Oral, rat: LD50 = 4400 mg/kg; Skin, rabbit: LD50 = >5 gm/kg.
CAS# 25013-16-5: Oral, mouse: LD50 = 1100 mg/kg; Oral, rabbit: LD50 = 2100 mg/kg; Oral, rat: LD50 = 2 gm/kg.
Carcinogenicity:
d-Limonene - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Butylated hydroxyanisole - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
CAS# 5989-27-5: GW6360000 CAS# 25013-16-5: SL1945000 LD50/LC50:
CAS# 5989-27-5: Oral, mouse: LD50 = 5600 mg/kg; Oral, rat: LD50 = 4400 mg/kg; Skin, rabbit: LD50 = >5 gm/kg.
CAS# 25013-16-5: Oral, mouse: LD50 = 1100 mg/kg; Oral, rabbit: LD50 = 2100 mg/kg; Oral, rat: LD50 = 2 gm/kg.
Carcinogenicity:
d-Limonene - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Butylated hydroxyanisole - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other No information available.
Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: Dipentene
Hazard Class: 3
UN Number: 2052
Packing Group: III
IMO
Shipping Name: Dipentene
Hazard Class: 3
UN Number: 2052
Packing Group: III
RID/ADR
Shipping Name: Dipentene
Hazard Class: 3
UN Number: 2052
Packing group: III
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI N
Risk Phrases:
R 10 Flammable.
R 38 Irritating to skin.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 5989-27-5: No information available.
CAS# 25013-16-5: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5989-27-5 is not listed on Canadas Ingredient Disclosure List.
CAS# 25013-16-5 is not listed on Canadas Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 5989-27-5 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 25013-16-5 is not listed on the TSCA inventory.
It is for research and development use only.
