Name:
FisherBrand General Purpose Cleaner
Synonym:
None
CAS:
111-76-2
Section 1 - Chemical Product
MSDS Name:FisherBrand General Purpose Cleaner
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 111-76-2 | 2-Butoxyethanol | 6 | 203-905-0 |
| Hazard Symbols: C Risk Phrases: 34 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Not available.
Ingestion:
Causes gastrointestinal tract burns. May cause central nervous system effects. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects. Central nervous system effects, which appear to predominate in acute cases are characterized by abnormal fatigue, memory difficulties and dizziness.
Chronic:
Prolonged or repeated skin contact may cause defatting and dermatitis. Effects may be delayed.
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Not available.
Ingestion:
Causes gastrointestinal tract burns. May cause central nervous system effects. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects. Central nervous system effects, which appear to predominate in acute cases are characterized by abnormal fatigue, memory difficulties and dizziness.
Chronic:
Prolonged or repeated skin contact may cause defatting and dermatitis. Effects may be delayed.
Section 4 - FIRST AID MEASURES
Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Discard contaminated shoes. Avoid breathing vapor or mist.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Corrosives area. Keep away from acids.
Wash thoroughly after handling. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Discard contaminated shoes. Avoid breathing vapor or mist.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Corrosives area. Keep away from acids.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 111-76-2: United Kingdom, WEL - TWA: 25 ppm TWA United Kingdom, WEL - STEL: 50 ppm STEL United States OSHA: 50 ppm TWA; 240 mg/m3 TWA Belgium - TWA: 20 ppm VLE; 98 mg/m3 VLE Belgium - STEL: 50 ppm VLE; 246 mg/m3 VLE France - VME: 25 ppm VME; 120 mg/m3 VME Germany: 20 ppm TWA; 98 mg/m3 TWA Germany: Skin absorber Malaysia: 20 ppm TWA; 96.7 mg/m3 TWA Netherlands: 50 ppm STEL; 246 mg/m3 STEL Netherlands: 20 ppm MAC; 100 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 20 ppm VLA-ED; 98 mg/m3 VLA-ED Spain: 50 ppm VLA-EC; 245 mg/m3 VLA-EC CAS# 6834-92-0: CAS# 7732-18-5: CAS# 68439-57-6: CAS# 127087-87-0: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 111-76-2: United Kingdom, WEL - TWA: 25 ppm TWA United Kingdom, WEL - STEL: 50 ppm STEL United States OSHA: 50 ppm TWA; 240 mg/m3 TWA Belgium - TWA: 20 ppm VLE; 98 mg/m3 VLE Belgium - STEL: 50 ppm VLE; 246 mg/m3 VLE France - VME: 25 ppm VME; 120 mg/m3 VME Germany: 20 ppm TWA; 98 mg/m3 TWA Germany: Skin absorber Malaysia: 20 ppm TWA; 96.7 mg/m3 TWA Netherlands: 50 ppm STEL; 246 mg/m3 STEL Netherlands: 20 ppm MAC; 100 mg/m3 MAC Russia: 5 mg/m3 TWA Spain: 20 ppm VLA-ED; 98 mg/m3 VLA-ED Spain: 50 ppm VLA-EC; 245 mg/m3 VLA-EC CAS# 6834-92-0: CAS# 7732-18-5: CAS# 68439-57-6: CAS# 127087-87-0: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: clear red
Odor: aromatic odor
pH: 12.3 @ use dilution
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: > 212 deg F
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.07
Molecular Formula: Not applicable.
Molecular Weight: Not available.
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Extreme temperatures.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported
Stable under normal temperatures and pressures.
Conditions to Avoid:
Extreme temperatures.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 111-76-2: KJ8575000 CAS# 6834-92-0: VV9275000 CAS# 7732-18-5: ZC0110000 CAS# 68439-57-6 unlisted.
CAS# 127087-87-0: RB2451000 TR1581962 LD50/LC50:
CAS# 111-76-2: Dermal, guinea pig: LD50 = 230 uL/kg; Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 100 mg/24H Moderate; Inhalation, mouse: LC50 = 700 ppm/7H; Inhalation, mouse: LC50 = 3380 mg/m3/7H; Inhalation, rat: LC50 = 450 ppm/4H; Inhalation, rat: LC50 = 2900 mg/m3/7H; Oral, mouse: LD50 = 1230 mg/kg; Oral, mouse: LD50 = 1167 mg/kg; Oral, rabbit: LD50 = 300 mg/kg; Oral, rabbit: LD50 = 320 mg/kg; Oral, rat: LD50 = 470 mg/kg; Oral, rat: LD50 = 917 mg/kg; Skin, rabbit: LD50 = 220 mg/kg.
CAS# 6834-92-0: Draize test, rabbit, skin: 250 mg/24H Severe; Oral, mouse: LD50 = 770 mg/kg; Oral, rat: LD50 = 1153 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 68439-57-6.
CAS# 127087-87-0.
Carcinogenicity:
2-Butoxyethanol - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to Sodium metasilicate - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Sodium C14-16-alkane hydroxy & alkene sufonates - Not listed by ACGIH, IARC, or NTP.
4-Nonylphenol, branched, ethoxylated - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 111-76-2: KJ8575000 CAS# 6834-92-0: VV9275000 CAS# 7732-18-5: ZC0110000 CAS# 68439-57-6 unlisted.
CAS# 127087-87-0: RB2451000 TR1581962 LD50/LC50:
CAS# 111-76-2: Dermal, guinea pig: LD50 = 230 uL/kg; Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 100 mg/24H Moderate; Inhalation, mouse: LC50 = 700 ppm/7H; Inhalation, mouse: LC50 = 3380 mg/m3/7H; Inhalation, rat: LC50 = 450 ppm/4H; Inhalation, rat: LC50 = 2900 mg/m3/7H; Oral, mouse: LD50 = 1230 mg/kg; Oral, mouse: LD50 = 1167 mg/kg; Oral, rabbit: LD50 = 300 mg/kg; Oral, rabbit: LD50 = 320 mg/kg; Oral, rat: LD50 = 470 mg/kg; Oral, rat: LD50 = 917 mg/kg; Skin, rabbit: LD50 = 220 mg/kg.
CAS# 6834-92-0: Draize test, rabbit, skin: 250 mg/24H Severe; Oral, mouse: LD50 = 770 mg/kg; Oral, rat: LD50 = 1153 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 68439-57-6.
CAS# 127087-87-0.
Carcinogenicity:
2-Butoxyethanol - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to Sodium metasilicate - Not listed by ACGIH, IARC, or NTP.
Water - Not listed by ACGIH, IARC, or NTP.
Sodium C14-16-alkane hydroxy & alkene sufonates - Not listed by ACGIH, IARC, or NTP.
4-Nonylphenol, branched, ethoxylated - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Other The high pH of this material makes it harmful to aquatic life.
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 111-76-2: 1
CAS# 6834-92-0: 1
CAS# 7732-18-5: No information available.
CAS# 68439-57-6: No information available.
CAS# 127087-87-0: 2
Canada
CAS# 111-76-2 is listed on Canadas DSL List.
CAS# 6834-92-0 is listed on Canadas DSL List.
CAS# 7732-18-5 is listed on Canadas DSL List.
CAS# 68439-57-6 is listed on Canadas DSL List.
CAS# 127087-87-0 is listed on Canadas DSL List.
CAS# 111-76-2 is listed on Canadas Ingredient Disclosure List.
CAS# 6834-92-0 is listed on Canadas Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canadas Ingredient Disclosure List.
CAS# 68439-57-6 is not listed on Canadas Ingredient Disclosure List.
CAS# 127087-87-0 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-76-2 is listed on the TSCA inventory.
CAS# 6834-92-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 68439-57-6 is listed on the TSCA inventory.
CAS# 127087-87-0 is listed on the TSCA inventory.
