Name:
Fluorotrichloromethane 99.5+% nmr grade
Synonym:
Fluorotrichloromethane; Methane, fluorotrichloro-; Monofluorotrichloromethane; Trichloromonofluoromethan
CAS:
75-69-4
Section 1 - Chemical Product
MSDS Name:Fluorotrichloromethane 99.5+% nmr grade
Synonym:Fluorotrichloromethane; Methane, fluorotrichloro-; Monofluorotrichloromethane; Trichloromonofluoromethan
Synonym:Fluorotrichloromethane; Methane, fluorotrichloro-; Monofluorotrichloromethane; Trichloromonofluoromethan
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| 75-69-4 | Fluorotrichloromethane | 99.5+ | 200-892-3 |
| Hazard Symbols: XI Risk Phrases: 36/37/38 |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Causes respiratory tract irritation. High vapor concentrations may cause drowsiness. Causes cardiac sensitization with effects similar to those of ingestion. Vapor or mist is irritating to the mucous membranes and upper respiratory tract.
Chronic:
Prolonged or repeated skin contact may cause defatting and dermatitis. High concentrations of fluorotrichloromethane causes narcosis and anesthesia in humans.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Causes respiratory tract irritation. High vapor concentrations may cause drowsiness. Causes cardiac sensitization with effects similar to those of ingestion. Vapor or mist is irritating to the mucous membranes and upper respiratory tract.
Chronic:
Prolonged or repeated skin contact may cause defatting and dermatitis. High concentrations of fluorotrichloromethane causes narcosis and anesthesia in humans.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote: None reported.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote: None reported.
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Substance is nonflammable. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Substance is nonflammable. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) Keep containers tightly closed.
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.) Keep containers tightly closed.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 75-69-4: United States OSHA: 1000 ppm TWA; 5600 mg/m3 TWA France - VLE: 1000 ppm VLE; 5600 mg/m3 VLE Germany: 1000 ppm TWA; 5700 mg/m3 TWA Japan: 1000 ppm Ceiling; 5600 mg/m3 Ceiling Malaysia: 1000 ppm Ceiling; 5620 mg/m3 Ceiling Netherlands: 1000 ppm STEL; 5600 mg/m3 STEL Russia: 1000 mg/m3 TWA Spain: 1000 ppm VLA-EC; 5720 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 75-69-4: United States OSHA: 1000 ppm TWA; 5600 mg/m3 TWA France - VLE: 1000 ppm VLE; 5600 mg/m3 VLE Germany: 1000 ppm TWA; 5700 mg/m3 TWA Japan: 1000 ppm Ceiling; 5600 mg/m3 Ceiling Malaysia: 1000 ppm Ceiling; 5620 mg/m3 Ceiling Netherlands: 1000 ppm STEL; 5600 mg/m3 STEL Russia: 1000 mg/m3 TWA Spain: 1000 ppm VLA-EC; 5720 mg/m3 VLA-EC Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 680 mm Hg @21C
Viscosity: Not available.
Boiling Point: 24 deg C
Freezing/Melting Point: -111 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble in water.
Specific Gravity/Density:
Molecular Formula: CCl3F
Molecular Weight: 137.3574
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants, excess light.
Incompatibilities with Other Materials:
Aluminum, magnesium, zinc, potassium, lithium, sodium, heat, direct light, barium.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide, hydrogen fluoride gas, phosgene gas.
Hazardous Polymerization: Has not been reported.
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants, excess light.
Incompatibilities with Other Materials:
Aluminum, magnesium, zinc, potassium, lithium, sodium, heat, direct light, barium.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide, hydrogen fluoride gas, phosgene gas.
Hazardous Polymerization: Has not been reported.
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 75-69-4: PB6125000 LD50/LC50:
CAS# 75-69-4: Inhalation, mouse: LC50 = 10 pph/30M; Inhalation, rabbit: LC50 = 25 pph/30M; Inhalation, rat: LC50 = 13 pph/15M.
Carcinogenicity:
Fluorotrichloromethane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
CAS# 75-69-4: PB6125000 LD50/LC50:
CAS# 75-69-4: Inhalation, mouse: LC50 = 10 pph/30M; Inhalation, rabbit: LC50 = 25 pph/30M; Inhalation, rat: LC50 = 13 pph/15M.
Carcinogenicity:
Fluorotrichloromethane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 75-69-4: 5000 lb final RQ; 2270 kg final RQ
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 15 Keep away from heat.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 75-69-4: 2
Canada
CAS# 75-69-4 is listed on Canadas DSL List.
CAS# 75-69-4 is listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-69-4 is listed on the TSCA inventory.
