Name:
Gallium(III) perchlorate hydrate 99%
Synonym:
None
CAS:
Section 1 - Chemical Product
MSDS Name:Gallium(III) perchlorate hydrate 99%
Synonym:None
Synonym:None
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
| CAS# | Chemical Name | emsds | EINECS# |
| Hazard Symbols: O Risk Phrases: |
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Contact with combustible material may cause fire.Oxidizer.
Potential Health Effects
Eye:
May cause conjunctivitis. May cause permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Effects may be delayed.
Contact with combustible material may cause fire.Oxidizer.
Potential Health Effects
Eye:
May cause conjunctivitis. May cause permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Effects may be delayed.
Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician:
Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Some oxidizers may react explosively with hydrocarbons(fuel). May accelerate burning if involved in a fire. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Contact professional fire-fighters immediately. For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires flood fire with water from a distance.
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Some oxidizers may react explosively with hydrocarbons(fuel). May accelerate burning if involved in a fire. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Contact professional fire-fighters immediately. For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires flood fire with water from a distance.
Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation. Do not use combustible materials such as paper towels to clean up spill.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation. Do not use combustible materials such as paper towels to clean up spill.
Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Keep containers tightly closed. Store in a cool, dry area away from incompatible substances.
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Keep containers tightly closed. Store in a cool, dry area away from incompatible substances.
Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# : United Kingdom, WEL - TWA: (listed as tellurium): 0.1 mg/m3 TWA United Kingdom, WEL - STEL: (listed as tellurium): 0.3 mg/m3 STEL United States OSHA: 0.1 mg/m3 TWA (listed under Tellurium).
Belgium - TWA: (listed as tellurium): 0.1 mg/m3 VLE France - VME: (listed as tellurium): 0.1 mg/m3 VME Germany: (listed as tellurium): 0.1 mg/m3 VME Malaysia: (listed as tellurium): 0.1 mg/m3 TWA Netherlands: (listed as tellurium): 0.1 mg/m3 MAC Russia: (listed as tellurium): 0.01 mg/m3 TWA Spain: (listed as tellurium): 0.1 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# : United Kingdom, WEL - TWA: (listed as tellurium): 0.1 mg/m3 TWA United Kingdom, WEL - STEL: (listed as tellurium): 0.3 mg/m3 STEL United States OSHA: 0.1 mg/m3 TWA (listed under Tellurium).
Belgium - TWA: (listed as tellurium): 0.1 mg/m3 VLE France - VME: (listed as tellurium): 0.1 mg/m3 VME Germany: (listed as tellurium): 0.1 mg/m3 VME Malaysia: (listed as tellurium): 0.1 mg/m3 TWA Netherlands: (listed as tellurium): 0.1 mg/m3 MAC Russia: (listed as tellurium): 0.01 mg/m3 TWA Spain: (listed as tellurium): 0.1 mg/m3 VLA-ED Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: white
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 175 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 175 deg C
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: Cl3GaO12.xH2O
Molecular Weight: 368.07
Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents, strong oxidants.
Incompatibilities with Other Materials:
Reducing agents, combustible materials.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents, strong oxidants.
Incompatibilities with Other Materials:
Reducing agents, combustible materials.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Gallium(III) perchlorate hydrate - Not listed by ACGIH, IARC, or NTP.
CAS# unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Gallium(III) perchlorate hydrate - Not listed by ACGIH, IARC, or NTP.
Section 12 - ECOLOGICAL INFORMATION
Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - TRANSPORT INFORMATION
IATA
Shipping Name: PERCHLORATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1481
Packing Group: II
IMO
Shipping Name: PERCHLORATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1481
Packing Group: II
RID/ADR
Shipping Name: PERCHLORATES, INORGANIC, N.O.S.
Hazard Class: 5.1
UN Number: 1481
Packing group: II
Section 15 - REGULATORY INFORMATION
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O
Risk Phrases:
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
WGK (Water Danger/Protection)
CAS# : No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# is not listed on the TSCA inventory.
It is for research and development use only.
