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Name:
Gelatin Multicomponent Trace Element Reference Material (Teg-50-B)
Synonym:
CAS:
7429-90-5
Section 1 - Chemical Product
MSDS Name:Gelatin Multicomponent Trace Element Reference Material (Teg-50-B)
Synonym:
Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name emsds EINECS#
7429-90-5 Aluminum <1.0 231-072-3
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Particles embedded in the skin may cause "chemical gas gangrene" with symptoms of persistent lesions, inflammation and gas bubbles under the skin. Exposure to arsenic compounds may produce hyperpigmentation of the skin and hyperkeratoses of plantar and palmar surfaces as well as both primary irritation and sensitization types.
Ingestion:
May cause irritation of the digestive tract. May cause liver damage.
May cause allergic reaction. May cause blood abnormalities. Ingestion of arsenical compounds may cause burning of the lips, throat constriction, swallowing difficulties, severe abdominal pain, severe nausea, projectile vomiting, and profuse diarrhea. Ingestion of arsenic compounds can produce convulsions, coma, and possibly death within 24 hours.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. Inhalation of arsenic compounds may lead to irritation of the respiratory tract and to possible nasal perforation. Long-term exposure to arsenic compounds may produce impairment of peripheral circulation. May cause liver damage.
Chronic:
Prolonged inhalation may cause respiratory tract inflammation and lung damage. Chronic exposure to arsenical dust may cause shortness of breath, nausea, chest pains, and garlic odor.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Antidote: The use of Dimercaprol or BAL (British Anti-Lewisite) as a chelating agent should be determined by qualified medical personnel.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 7429-90-5: United Kingdom, WEL - TWA: 10 mg/m3 TWA (inhalable dust); 4 mg/m3 (respirable dust) United Kingdom, WEL - STEL: 30 mg/m3 STEL (inhalable dust); 12 mg STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 10 mg/m3 VLE (metal); 5 mg/m3 VLE (fume) France - VME: 10 mg/m3 VME (metal); 5 mg/m3 VME (dust) Japan: 0.5 mg/m3 OEL (respirable dust); 2 mg/m3 OEL (total dust) Malaysia: 10 mg/m3 TWA (metal dust) Netherlands: 10 mg/m3 MAC Russia: 2 mg/m3 TWA Spain: 10 mg/m3 VLA-ED (dust) CAS# 7439-92-1: United Kingdom, WEL - TWA: 0.15 mg/m3 TWA United Kingdom, WEL - STEL: 0.45 mg/m3 TWA United States OSHA: ; 50 ??g/m3 PEL (as Pb); 30 ??g/m3 Action Level Pb. Poison - see 29 CFR 1910.10 25) Belgium - TWA: (listed as lead, inorganic compounds): 0.15 mg/m3 (dust and fume) France - VME: 0.1 mg/m3 VME Germany: 0.1 mg/m3 TWA (inhalable fraction) Japan: 0.1 mg/m3 OEL Malaysia: 0.05 mg/m3 TWA Netherlands: 0.15 mg/m3 MAC Russia: 0.01 mg/m3 TWA Russia: 0.005 mg/m3 STEL Spain: 0.15 mg/m3 VLA-ED CAS# 7439-95-4: CAS# 7440-36-0: United Kingdom, WEL - TWA: 0.5 mg/m3 TWA United Kingdom, WEL - STEL: 1.5 mg/m3 STEL United States OSHA: 0.5 mg/m3 TWA Belgium - TWA: 0.5 mg/m3 VLE France - VME: 0.5 mg/m3 VME Germany: 0.5 mg/m3 TWA (inhalable fraction) Japan: 0.1 mg/m3 OEL Malaysia: 0.5 mg/m3 TWA Netherlands: 0.5 mg/m3 MAC Russia: 0.5 mg/m3 TWA Russia: 0.2 mg/m3 STEL Spain: 0.5 mg/m3 VLA-ED CAS# 7440-38-2: United Kingdom, WEL - TWA: 0.1 mg/m3 TWA United Kingdom, WEL - STEL: 0.3 mg/m3 STEL United States OSHA: 0.5 mg/m3 TWA Belgium - TWA: 0.01 mg/m3 VLE Japan: 3 ??g/m3 OEL (reference value) Malaysia: 0.01 mg/m3 TWA Netherlands: 0.050 mg/m3 MAC Spain: 0.1 mg/m3 VLA-ED CAS# 7440-39-3: United States OSHA: 0.5 mg/m3 TWA Belgium - TWA: 0.5 mg/m3 VLE Malaysia: 0.5 mg/m3 TWA Netherlands: 0.5 mg/m3 MAC Spain: 0.5 mg/m3 VLA-ED CAS# 7440-47-3: United Kingdom, WEL - TWA: 0.5 mg/m3 TWA United Kingdom, WEL - STEL: 1.5 mg/m3 STEL United States OSHA: 1 mg/m3 TWA Belgium - TWA: 0.5 mg/m3 VLE France - VME: 0.5 mg/m3 VME Japan: 0.5 mg/m3 OEL Malaysia: 0.5 mg/m3 TWA Netherlands: (listed as chromium compounds): 0.01 mg/m3 STEL Netherlands: 0.5 mg/m3 MAC Spain: 0.5 mg/m3 VLA-ED CAS# 7440-48-4: United Kingdom, WEL - TWA: 0.1 mg/m3 TWA United Kingdom, WEL - STEL: 0.3 mg/m3 STEL United States OSHA: 0.1 mg/m3 TWA (dust and fume) Belgium - TWA: 0.02 mg/m3 VLE (dust and fume) Germany: 0.5 mg/m3 TWA (inhalable fraction, production of cobalt powder and catalysts, tu Japan: 0.05 mg/m3 OEL Malaysia: 0.02 mg/m3 TWA Netherlands: 0.02 mg/m3 MAC (dust and smoke, as Co) Russia: 0.5 mg/m3 TWA (dust and/or fumes) Spain: 0.02 mg/m3 VLA-ED CAS# 7440-50-8: United Kingdom, WEL - TWA: 0.2 mg/m3 TWA (fume); 1 mg/m3 TWA (dus and mist) United Kingdom, WEL - STEL: 0.6 mg/m3 STEL (fume); 2 mg/m3 STEL ( and mist) United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and mists) Belgium - TWA: 0.2 mg/m3 VLE (fume); 1 mg/m3 VLE (dust and mist) France - VME: 0.2 mg/m3 VME (fume); 1 mg/m3 VME (dust, as Cu) France - VLE: 2 mg/m3 VLE (dust, as Cu) Germany: 1 mg/m3 TWA (inhalable fraction); 0.1 mg/m3 TWA (respira fraction, smoke) Malaysia: 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m3 TWA (dust and mist Cu) Netherlands: 0.2 mg/m3 MAC (smoke); 1 mg/m3 MAC (dust) Russia: 1 mg/m3 TWA (dust) Russia: 0.5 mg/m3 STEL (dust) Spain: 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-ED (dust and mist, as CAS# 7440-69-9: Russia: 0.5 mg/m3 TWA CAS# 7440-70-2: CAS# 9000-70-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHAs eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: Mixture
Molecular Weight: 0

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, exposure to air, contact with water, acids, strong oxidants.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing, e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), amides (e.g. butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), caustics (e.g. ammonia, ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium hydroxide), nitriles (e.g. acetonitrile, methyl cyanide), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), epoxides (e.g. butyl glycidyl ether), explosives (e.g.
ammonium nitrate, hydrazoic acid, sodium azide), polymerizable compounds (e.g. butadiene, methyl acrylate, styrene, vinyl chloride), water and mixtures containing water (e.g. aqueous solutions, water), water reactive substa.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen gas, calcium oxide, calcium hydroxide, oxides of magnesium.
Hazardous Polymerization: Has not been reported
Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7429-90-5: BD0330000 BD1020000 CAS# 7439-92-1: OF7525000 CAS# 7439-95-4: FW6475100 CAS# 7440-36-0: CC4025000 CAS# 7440-38-2: CG0525000 CAS# 7440-39-3: CQ8370000 CAS# 7440-47-3: GB4200000 CAS# 7440-48-4: GF8750000 GF8850000 GG0375000 CAS# 7440-50-8: GL5325000 GL7440000 GL7590000 CAS# 7440-69-9: EB2600000 CAS# 7440-70-2: EV8500000 CAS# 9000-70-8: LX8580000 LD50/LC50:
Not available.
Not available.
Not available.
CAS# 7440-36-0: Oral, rat: LD50 = 7 gm/kg.
CAS# 7440-38-2: Oral, mouse: LD50 = 145 mg/kg; Oral, mouse: LD50 = 144 mg/kg; Oral, rat: LD50 = 763 mg/kg; Oral, rat: LD50 = 763 mg/kg.
CAS# 7440-39-3.
CAS# 7440-47-3.
CAS# 7440-48-4: Oral, rat: LD50 = 6171 mg/kg.
CAS# 7440-50-8.
CAS# 7440-69-9: Oral, mouse: LD50 = 10 gm/kg; Oral, rat: LD50 = 5000 mg/kg.
CAS# 7440-70-2.
CAS# 9000-70-8.
Carcinogenicity:
Aluminum - Not listed by ACGIH, IARC, or NTP.
Lead - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 10/1/92 NTP: Suspect carcinogen IARC: Group 2B carcinogen Magnesium - Not listed by ACGIH, IARC, or NTP.
Antimony - Not listed by ACGIH, IARC, or NTP.
Arsenic - ACGIH: A1 - Confirmed Human Carcinogen IARC: Group 1 carcinogen Barium - Not listed by ACGIH, IARC, or NTP.
Chromium - Not listed by ACGIH, IARC, or NTP.
Cobalt - ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to California: carcinogen, initial date 7/1/92 (powder) IARC: Group 2B carcinogen Copper - Not listed by ACGIH, IARC, or NTP.
Bismuth - Not listed by ACGIH, IARC, or NTP.
Calcium - Not listed by ACGIH, IARC, or NTP.
Gelatin - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 7439-92-1: 10 lb final RQ (no reporting of releases of this hazardo
USA RQ: CAS# 7440-36-0: 5000 lb final RQ (no reporting of releases of this hazar
USA RQ: CAS# 7440-38-2: 1 lb final RQ (no reporting of releases of this hazardou
USA RQ: CAS# 7440-47-3: 5000 lb final RQ (no reporting of releases of this hazar
USA RQ: CAS# 7440-50-8: 5000 lb final RQ (no reporting of releases of this hazar

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 8 Keep container dry.
S 24/25 Avoid contact with skin and eyes.
S 43 In case of fire, use ... (indicate in the space
the precise type of fire-fighting equipment. If water
increases the risk, add - never use water).
WGK (Water Danger/Protection)
CAS# 7429-90-5: 0
CAS# 7439-92-1: No information available.
CAS# 7439-95-4: No information available.
CAS# 7440-36-0: No information available.
CAS# 7440-38-2: No information available.
CAS# 7440-39-3: No information available.
CAS# 7440-47-3: No information available.
CAS# 7440-48-4: 1
CAS# 7440-50-8: 0
CAS# 7440-69-9: No information available.
CAS# 7440-70-2: 1
CAS# 9000-70-8: 0
Canada
CAS# 7429-90-5 is listed on Canadas DSL List.
CAS# 7439-92-1 is listed on Canadas DSL List.
CAS# 7439-95-4 is listed on Canadas DSL List.
CAS# 7440-36-0 is listed on Canadas DSL List.
CAS# 7440-38-2 is listed on Canadas DSL List.
CAS# 7440-39-3 is listed on Canadas DSL List.
CAS# 7440-47-3 is listed on Canadas DSL List.
CAS# 7440-48-4 is listed on Canadas DSL List.
CAS# 7440-50-8 is listed on Canadas DSL List.
CAS# 7440-69-9 is listed on Canadas DSL List.
CAS# 7440-70-2 is listed on Canadas DSL List.
CAS# 9000-70-8 is listed on Canadas DSL List.
CAS# 7429-90-5 is listed on Canadas Ingredient Disclosure List.
CAS# 7439-92-1 is listed on Canadas Ingredient Disclosure List.
CAS# 7439-95-4 is not listed on Canadas Ingredient Disclosure List.
CAS# 7440-36-0 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-38-2 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-39-3 is not listed on Canadas Ingredient Disclosure List.
CAS# 7440-47-3 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-48-4 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-50-8 is listed on Canadas Ingredient Disclosure List.
CAS# 7440-69-9 is not listed on Canadas Ingredient Disclosure List.
CAS# 7440-70-2 is not listed on Canadas Ingredient Disclosure List.
CAS# 9000-70-8 is not listed on Canadas Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7429-90-5 is listed on the TSCA inventory.
CAS# 7439-92-1 is listed on the TSCA inventory.
CAS# 7439-95-4 is listed on the TSCA inventory.
CAS# 7440-36-0 is listed on the TSCA inventory.
CAS# 7440-38-2 is listed on the TSCA inventory.
CAS# 7440-39-3 is listed on the TSCA inventory.
CAS# 7440-47-3 is listed on the TSCA inventory.
CAS# 7440-48-4 is listed on the TSCA inventory.
CAS# 7440-50-8 is listed on the TSCA inventory.
CAS# 7440-69-9 is listed on the TSCA inventory.
CAS# 7440-70-2 is listed on the TSCA inventory.
CAS# 9000-70-8 is listed on the TSCA inventory.